Preparation and luminescent properties of coordination polymers of terbium and europium with 1,4-bis-(4-methoxycarbonyl-3-hydroxyphenoxycarbonyl)butane View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2014-10

AUTHORS

I. I. Zseltvay, S. B. Meshkova, N. S. Novikova, R. V. Kondrat’eva, V. I. Nedostup, P. G. Doga, Yu. V. Skripinets, E. A. Zhikhareva

ABSTRACT

Physicochemical properties of new isostructural homo- and heteronuclear coordination polymers of terbium and europium with 1,4-bis-(4-methoxycarbonyl-3-hydroxyphenoxycarbonyl)butane (H2L) differing in the composition have been studied. The Tb2L3·H2O compound has exhibited efficient sensibilized green luminescence, whereas the corresponding europium-containing polymer EuL3·H2O has shown practically no luminescence due to mismatch of energies of the ligand triplet level and the Eu3+ ion emitting level. Heteronuclear terbium-europium polymers (Tb1.5Eu0.5L3·H2O, TbEuL3·H2O, and Tb0.5Eu1.5L3·H2O) show luminescence via the intramolecular transfer of the exiting energy from Tb3+ emitting level to Eu3+. More... »

PAGES

1994-2000

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070363214100223

DOI

http://dx.doi.org/10.1134/s1070363214100223

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1022816445


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