Relation between the N-NO2 bond length and stability of the secondary nitramines View Full Text


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Article Info

DATE

2013-06

AUTHORS

G. M. Nazin, V. G. Prokudin, V. V. Dubikhin, Z. G. Aliev, V. L. Zbarskii, N. V. Yudin, A. V. Shastin

ABSTRACT

The fact of the constancy of activation entropy of N-NO2 bond homolysis in a series of secondary nitramines was utilized for correction of the experimental values of activation energy E of this process proceeding from the reliable data for the rate constants of the nitramines decomposition in solutions. When comparing the refined values of E (kJ mol−1) with the N-N bond length dN-N (Å) the following correlations were obtained: for cyclic and framework nitramines E = 663 − 356dN-N, and for the aromatic nitramines E = 1810 − 1227dN-N. A linear relationship between E and d is observed in the series of similar compounds. It depends on the electronic and steric effects of substituents. More... »

PAGES

1071-1076

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s107036321306011x

DOI

http://dx.doi.org/10.1134/s107036321306011x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1033103404


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