Considering the polynuclear complexes in the ionic equilibria of the Pb2+-H2O system View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2012-04

AUTHORS

N. S. Kozhevnikova, S. I. Sadovnikov, A. A. Uritskaya, A. I. Gusev

ABSTRACT

Analysis of conditions of the lead hydroxide and sulfide formation in the Pb2+-H2O system was carried out with accounting for the formation of polynuclear hydroxo-complexes. This allows predicting a possibility of the lead hydroxide formation in the solution before the beginning of the synthesis of lead sulfide. The domains of the stable formation of Pb(OH)2 and PbS were calculated for the systems containing lead citrate complexes and hydroxo-complexes. The proposed calculation method can be used for the quantitative determination of the reaction mixture composition and development of the chemical deposition technology of lead chalcogenides in different morphological forms: nanocrystalline powders (hydrophobic sol), quantum dots, heterostructures of the core@shell type or films. The proposed calculation method is applicable to other chalcogenide systems containing metal ions forming mononuclear and polynuclear hydroxo-complexes. More... »

PAGES

626-634

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070363212040020

DOI

http://dx.doi.org/10.1134/s1070363212040020

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1025680762


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Inorganic Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, ul. Pervomayskaya 91, 620990, Yekaterinburg, Russia", 
          "id": "http://www.grid.ac/institutes/grid.426536.0", 
          "name": [
            "Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, ul. Pervomayskaya 91, 620990, Yekaterinburg, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kozhevnikova", 
        "givenName": "N. S.", 
        "id": "sg:person.016411456366.94", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016411456366.94"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Ural Federal University named after First President of Russia B.N. Yeltsin, 620002, Yekaterinburg, Russia", 
          "id": "http://www.grid.ac/institutes/grid.412761.7", 
          "name": [
            "Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, ul. Pervomayskaya 91, 620990, Yekaterinburg, Russia", 
            "Ural Federal University named after First President of Russia B.N. Yeltsin, 620002, Yekaterinburg, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Sadovnikov", 
        "givenName": "S. I.", 
        "id": "sg:person.0772404233.53", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0772404233.53"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Ural Federal University named after First President of Russia B.N. Yeltsin, 620002, Yekaterinburg, Russia", 
          "id": "http://www.grid.ac/institutes/grid.412761.7", 
          "name": [
            "Ural Federal University named after First President of Russia B.N. Yeltsin, 620002, Yekaterinburg, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Uritskaya", 
        "givenName": "A. A.", 
        "id": "sg:person.015675162237.11", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015675162237.11"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, ul. Pervomayskaya 91, 620990, Yekaterinburg, Russia", 
          "id": "http://www.grid.ac/institutes/grid.426536.0", 
          "name": [
            "Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, ul. Pervomayskaya 91, 620990, Yekaterinburg, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Gusev", 
        "givenName": "A. I.", 
        "id": "sg:person.015476063503.77", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015476063503.77"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "2012-04", 
    "datePublishedReg": "2012-04-01", 
    "description": "Analysis of conditions of the lead hydroxide and sulfide formation in the Pb2+-H2O system was carried out with accounting for the formation of polynuclear hydroxo-complexes. This allows predicting a possibility of the lead hydroxide formation in the solution before the beginning of the synthesis of lead sulfide. The domains of the stable formation of Pb(OH)2 and PbS were calculated for the systems containing lead citrate complexes and hydroxo-complexes. The proposed calculation method can be used for the quantitative determination of the reaction mixture composition and development of the chemical deposition technology of lead chalcogenides in different morphological forms: nanocrystalline powders (hydrophobic sol), quantum dots, heterostructures of the core@shell type or films. The proposed calculation method is applicable to other chalcogenide systems containing metal ions forming mononuclear and polynuclear hydroxo-complexes.", 
    "genre": "article", 
    "id": "sg:pub.10.1134/s1070363212040020", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1109093", 
        "issn": [
          "1070-3632", 
          "1608-3350"
        ], 
        "name": "Russian Journal of General Chemistry", 
        "publisher": "Pleiades Publishing", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "4", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "82"
      }
    ], 
    "keywords": [
      "chemical deposition technology", 
      "reaction mixture composition", 
      "formation of polynuclear", 
      "polynuclear complexes", 
      "metal ions", 
      "citrate complexes", 
      "hydroxide formation", 
      "lead hydroxide", 
      "lead sulfide", 
      "quantitative determination", 
      "deposition technology", 
      "quantum dots", 
      "ionic equilibria", 
      "sulfide formation", 
      "nanocrystalline powders", 
      "Pb2", 
      "mixture composition", 
      "lead chalcogenides", 
      "chalcogenide systems", 
      "complexes", 
      "stable formation", 
      "polynuclear", 
      "formation", 
      "mononuclear", 
      "different morphological forms", 
      "hydroxide", 
      "ions", 
      "chalcogenides", 
      "synthesis", 
      "sulfide", 
      "films", 
      "dots", 
      "powder", 
      "determination", 
      "solution", 
      "heterostructures", 
      "composition", 
      "Pb", 
      "equilibrium", 
      "method", 
      "calculation method", 
      "morphological forms", 
      "system", 
      "conditions", 
      "form", 
      "analysis", 
      "possibility", 
      "technology", 
      "types", 
      "development", 
      "analysis of conditions", 
      "domain", 
      "beginning", 
      "accounting", 
      "lead hydroxide formation", 
      "lead citrate complexes"
    ], 
    "name": "Considering the polynuclear complexes in the ionic equilibria of the Pb2+-H2O system", 
    "pagination": "626-634", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1025680762"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s1070363212040020"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s1070363212040020", 
      "https://app.dimensions.ai/details/publication/pub.1025680762"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-01-01T18:27", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20220101/entities/gbq_results/article/article_565.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1134/s1070363212040020"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s1070363212040020'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s1070363212040020'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s1070363212040020'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s1070363212040020'


 

This table displays all metadata directly associated to this object as RDF triples.

143 TRIPLES      21 PREDICATES      83 URIs      74 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s1070363212040020 schema:about anzsrc-for:03
2 anzsrc-for:0302
3 anzsrc-for:0306
4 schema:author Nfcd825d3c92c4d67a605da26df73f995
5 schema:datePublished 2012-04
6 schema:datePublishedReg 2012-04-01
7 schema:description Analysis of conditions of the lead hydroxide and sulfide formation in the Pb2+-H2O system was carried out with accounting for the formation of polynuclear hydroxo-complexes. This allows predicting a possibility of the lead hydroxide formation in the solution before the beginning of the synthesis of lead sulfide. The domains of the stable formation of Pb(OH)2 and PbS were calculated for the systems containing lead citrate complexes and hydroxo-complexes. The proposed calculation method can be used for the quantitative determination of the reaction mixture composition and development of the chemical deposition technology of lead chalcogenides in different morphological forms: nanocrystalline powders (hydrophobic sol), quantum dots, heterostructures of the core@shell type or films. The proposed calculation method is applicable to other chalcogenide systems containing metal ions forming mononuclear and polynuclear hydroxo-complexes.
8 schema:genre article
9 schema:inLanguage en
10 schema:isAccessibleForFree false
11 schema:isPartOf N107e331c451346579b68f608f67ea669
12 Nb32a5276e07844ef8decb16916add8ec
13 sg:journal.1109093
14 schema:keywords Pb
15 Pb2
16 accounting
17 analysis
18 analysis of conditions
19 beginning
20 calculation method
21 chalcogenide systems
22 chalcogenides
23 chemical deposition technology
24 citrate complexes
25 complexes
26 composition
27 conditions
28 deposition technology
29 determination
30 development
31 different morphological forms
32 domain
33 dots
34 equilibrium
35 films
36 form
37 formation
38 formation of polynuclear
39 heterostructures
40 hydroxide
41 hydroxide formation
42 ionic equilibria
43 ions
44 lead chalcogenides
45 lead citrate complexes
46 lead hydroxide
47 lead hydroxide formation
48 lead sulfide
49 metal ions
50 method
51 mixture composition
52 mononuclear
53 morphological forms
54 nanocrystalline powders
55 polynuclear
56 polynuclear complexes
57 possibility
58 powder
59 quantitative determination
60 quantum dots
61 reaction mixture composition
62 solution
63 stable formation
64 sulfide
65 sulfide formation
66 synthesis
67 system
68 technology
69 types
70 schema:name Considering the polynuclear complexes in the ionic equilibria of the Pb2+-H2O system
71 schema:pagination 626-634
72 schema:productId Nfaae58527da7473389cd6cf460773ad0
73 Nffc32516bb1d445f980b92fc69b2926f
74 schema:sameAs https://app.dimensions.ai/details/publication/pub.1025680762
75 https://doi.org/10.1134/s1070363212040020
76 schema:sdDatePublished 2022-01-01T18:27
77 schema:sdLicense https://scigraph.springernature.com/explorer/license/
78 schema:sdPublisher Ncadce97567424909b0ebfcfb56e02b82
79 schema:url https://doi.org/10.1134/s1070363212040020
80 sgo:license sg:explorer/license/
81 sgo:sdDataset articles
82 rdf:type schema:ScholarlyArticle
83 N107e331c451346579b68f608f67ea669 schema:volumeNumber 82
84 rdf:type schema:PublicationVolume
85 N97053f97a14a43e489579e51a3a53ffc rdf:first sg:person.015675162237.11
86 rdf:rest Nd260699913084a3d8de1a4a6a62648d7
87 Nb32a5276e07844ef8decb16916add8ec schema:issueNumber 4
88 rdf:type schema:PublicationIssue
89 Ncadce97567424909b0ebfcfb56e02b82 schema:name Springer Nature - SN SciGraph project
90 rdf:type schema:Organization
91 Nd260699913084a3d8de1a4a6a62648d7 rdf:first sg:person.015476063503.77
92 rdf:rest rdf:nil
93 Nf2383594d049438c82a3f0f8eb82c78e rdf:first sg:person.0772404233.53
94 rdf:rest N97053f97a14a43e489579e51a3a53ffc
95 Nfaae58527da7473389cd6cf460773ad0 schema:name dimensions_id
96 schema:value pub.1025680762
97 rdf:type schema:PropertyValue
98 Nfcd825d3c92c4d67a605da26df73f995 rdf:first sg:person.016411456366.94
99 rdf:rest Nf2383594d049438c82a3f0f8eb82c78e
100 Nffc32516bb1d445f980b92fc69b2926f schema:name doi
101 schema:value 10.1134/s1070363212040020
102 rdf:type schema:PropertyValue
103 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
104 schema:name Chemical Sciences
105 rdf:type schema:DefinedTerm
106 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
107 schema:name Inorganic Chemistry
108 rdf:type schema:DefinedTerm
109 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
110 schema:name Physical Chemistry (incl. Structural)
111 rdf:type schema:DefinedTerm
112 sg:journal.1109093 schema:issn 1070-3632
113 1608-3350
114 schema:name Russian Journal of General Chemistry
115 schema:publisher Pleiades Publishing
116 rdf:type schema:Periodical
117 sg:person.015476063503.77 schema:affiliation grid-institutes:grid.426536.0
118 schema:familyName Gusev
119 schema:givenName A. I.
120 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015476063503.77
121 rdf:type schema:Person
122 sg:person.015675162237.11 schema:affiliation grid-institutes:grid.412761.7
123 schema:familyName Uritskaya
124 schema:givenName A. A.
125 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015675162237.11
126 rdf:type schema:Person
127 sg:person.016411456366.94 schema:affiliation grid-institutes:grid.426536.0
128 schema:familyName Kozhevnikova
129 schema:givenName N. S.
130 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016411456366.94
131 rdf:type schema:Person
132 sg:person.0772404233.53 schema:affiliation grid-institutes:grid.412761.7
133 schema:familyName Sadovnikov
134 schema:givenName S. I.
135 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0772404233.53
136 rdf:type schema:Person
137 grid-institutes:grid.412761.7 schema:alternateName Ural Federal University named after First President of Russia B.N. Yeltsin, 620002, Yekaterinburg, Russia
138 schema:name Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, ul. Pervomayskaya 91, 620990, Yekaterinburg, Russia
139 Ural Federal University named after First President of Russia B.N. Yeltsin, 620002, Yekaterinburg, Russia
140 rdf:type schema:Organization
141 grid-institutes:grid.426536.0 schema:alternateName Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, ul. Pervomayskaya 91, 620990, Yekaterinburg, Russia
142 schema:name Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, ul. Pervomayskaya 91, 620990, Yekaterinburg, Russia
143 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...