New route to 1,1-difluoro-5-methylquasisilatrane View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2011-12

AUTHORS

A. S. Soldatenko, E. A. Grebneva, N. F. Chernov, A. I. Albanov, O. M. Trofimova, M. G. Voronkov

ABSTRACT

A new route to 1,1-difluoro-5-methylquasisilatrane (N→Si) F2Si(OCH2CH2)2NMe is elaborated: the reaction of chlorinated methyltrifluorosilanes F3SiCH3−nCln (n = 1–3) as well as trifluoro(3-chloropropyl) silane and trifluoro(propenyl)silane with N-methyl-bis(2-hydroxyethyl)amine. The reactivity of the silanes F3SiCH3−nCln increases with the number of chlorine atoms, that is, with the electronegativity of the CH3−nCln group.

PAGES

2490-2492

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070363211120115

DOI

http://dx.doi.org/10.1134/s1070363211120115

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1004232099


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