Synthesis and structure of N-(2-silatranylethyl)imidazoles View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2011-12

AUTHORS

V. D. Sheludyakov, N. E. Kuz’mina, A. M. Abramkin, A. A. Korlyukov, D. E. Arkhipov, S. V. Loginov, D. A. Cheshkov, P. A. Storozhenko

ABSTRACT

Organosilicon imidazole derivatives containing a 2-silatranylethyl [N(CH2CH2O)3Si(CH2)2] group on the nitrogen atom were synthesized, and their steric and electronic structures, including the nature of interaction between the imidazole and silatrane fragments, were studied by X-ray analysis and 1H, 13C, and 29Si NMR spectroscopy.

PAGES

2468-2477

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070363211120085

DOI

http://dx.doi.org/10.1134/s1070363211120085

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1009467295


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "State Research Institute of Chemistry and Technology of Organometallic Compounds, sh. Entuziastov 38, 105118, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/None", 
          "name": [
            "State Research Institute of Chemistry and Technology of Organometallic Compounds, sh. Entuziastov 38, 105118, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Sheludyakov", 
        "givenName": "V. D.", 
        "id": "sg:person.015057567143.55", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015057567143.55"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Medical Equipment Scientific Appraisal Center, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/None", 
          "name": [
            "Medical Equipment Scientific Appraisal Center, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kuz\u2019mina", 
        "givenName": "N. E.", 
        "id": "sg:person.011272267131.49", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011272267131.49"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "State Research Institute of Chemistry and Technology of Organometallic Compounds, sh. Entuziastov 38, 105118, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/None", 
          "name": [
            "State Research Institute of Chemistry and Technology of Organometallic Compounds, sh. Entuziastov 38, 105118, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Abramkin", 
        "givenName": "A. M.", 
        "id": "sg:person.011120621425.25", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011120621425.25"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Nesmeyanov Institute of Organometallic Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Nesmeyanov Institute of Organometallic Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Korlyukov", 
        "givenName": "A. A.", 
        "id": "sg:person.01050521013.60", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01050521013.60"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Nesmeyanov Institute of Organometallic Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Nesmeyanov Institute of Organometallic Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Arkhipov", 
        "givenName": "D. E.", 
        "id": "sg:person.014441433661.39", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014441433661.39"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "State Research Institute of Chemistry and Technology of Organometallic Compounds, sh. Entuziastov 38, 105118, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/None", 
          "name": [
            "State Research Institute of Chemistry and Technology of Organometallic Compounds, sh. Entuziastov 38, 105118, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Loginov", 
        "givenName": "S. V.", 
        "id": "sg:person.013037424642.28", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013037424642.28"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "State Research Institute of Chemistry and Technology of Organometallic Compounds, sh. Entuziastov 38, 105118, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/None", 
          "name": [
            "State Research Institute of Chemistry and Technology of Organometallic Compounds, sh. Entuziastov 38, 105118, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Cheshkov", 
        "givenName": "D. A.", 
        "id": "sg:person.0732162157.42", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0732162157.42"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "State Research Institute of Chemistry and Technology of Organometallic Compounds, sh. Entuziastov 38, 105118, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/None", 
          "name": [
            "State Research Institute of Chemistry and Technology of Organometallic Compounds, sh. Entuziastov 38, 105118, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Storozhenko", 
        "givenName": "P. A.", 
        "id": "sg:person.01166103634.96", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01166103634.96"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "2011-12", 
    "datePublishedReg": "2011-12-01", 
    "description": "Organosilicon imidazole derivatives containing a 2-silatranylethyl [N(CH2CH2O)3Si(CH2)2] group on the nitrogen atom were synthesized, and their steric and electronic structures, including the nature of interaction between the imidazole and silatrane fragments, were studied by X-ray analysis and 1H, 13C, and 29Si NMR spectroscopy.", 
    "genre": "article", 
    "id": "sg:pub.10.1134/s1070363211120085", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1446214", 
        "issn": [
          "1070-3632", 
          "1608-3350"
        ], 
        "name": "Russian Journal of General Chemistry", 
        "publisher": "Pleiades Publishing", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "12", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "81"
      }
    ], 
    "keywords": [
      "X-ray analysis", 
      "NMR spectroscopy", 
      "nitrogen atoms", 
      "nature of interactions", 
      "imidazole derivatives", 
      "electronic structure", 
      "imidazole", 
      "spectroscopy", 
      "synthesis", 
      "atoms", 
      "structure", 
      "derivatives", 
      "interaction", 
      "fragments", 
      "nature", 
      "group", 
      "analysis"
    ], 
    "name": "Synthesis and structure of N-(2-silatranylethyl)imidazoles", 
    "pagination": "2468-2477", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1009467295"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s1070363211120085"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s1070363211120085", 
      "https://app.dimensions.ai/details/publication/pub.1009467295"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-09-02T15:54", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20220902/entities/gbq_results/article/article_535.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1134/s1070363211120085"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s1070363211120085'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s1070363211120085'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s1070363211120085'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s1070363211120085'


 

This table displays all metadata directly associated to this object as RDF triples.

124 TRIPLES      20 PREDICATES      41 URIs      34 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s1070363211120085 schema:about anzsrc-for:03
2 schema:author Na971f73ec4654bfa83c5223394a18952
3 schema:datePublished 2011-12
4 schema:datePublishedReg 2011-12-01
5 schema:description Organosilicon imidazole derivatives containing a 2-silatranylethyl [N(CH2CH2O)3Si(CH2)2] group on the nitrogen atom were synthesized, and their steric and electronic structures, including the nature of interaction between the imidazole and silatrane fragments, were studied by X-ray analysis and 1H, 13C, and 29Si NMR spectroscopy.
6 schema:genre article
7 schema:isAccessibleForFree false
8 schema:isPartOf N1f2904be55004007a26574e1e7cfb1c3
9 N45e1d3179cc24fd9828d7639ba14b3d4
10 sg:journal.1446214
11 schema:keywords NMR spectroscopy
12 X-ray analysis
13 analysis
14 atoms
15 derivatives
16 electronic structure
17 fragments
18 group
19 imidazole
20 imidazole derivatives
21 interaction
22 nature
23 nature of interactions
24 nitrogen atoms
25 spectroscopy
26 structure
27 synthesis
28 schema:name Synthesis and structure of N-(2-silatranylethyl)imidazoles
29 schema:pagination 2468-2477
30 schema:productId N975e54f5a7564768a80361d7bc5dd6cf
31 Na29f3eab74de4cf48410d0fe44e001e7
32 schema:sameAs https://app.dimensions.ai/details/publication/pub.1009467295
33 https://doi.org/10.1134/s1070363211120085
34 schema:sdDatePublished 2022-09-02T15:54
35 schema:sdLicense https://scigraph.springernature.com/explorer/license/
36 schema:sdPublisher N4b52b0ad16af4e45bfeb7b0488f23023
37 schema:url https://doi.org/10.1134/s1070363211120085
38 sgo:license sg:explorer/license/
39 sgo:sdDataset articles
40 rdf:type schema:ScholarlyArticle
41 N151e32dae254483ca67e191fea4a2088 rdf:first sg:person.01050521013.60
42 rdf:rest Ne9f80876d5e34d91bce29eca34f20460
43 N1f2904be55004007a26574e1e7cfb1c3 schema:volumeNumber 81
44 rdf:type schema:PublicationVolume
45 N45e1d3179cc24fd9828d7639ba14b3d4 schema:issueNumber 12
46 rdf:type schema:PublicationIssue
47 N4b52b0ad16af4e45bfeb7b0488f23023 schema:name Springer Nature - SN SciGraph project
48 rdf:type schema:Organization
49 N5d30c7fd24044334a3cc5fbab9419ba6 rdf:first sg:person.01166103634.96
50 rdf:rest rdf:nil
51 N6f29a09776c44bd3be3959dd6fe168c3 rdf:first sg:person.013037424642.28
52 rdf:rest Nca3762aae2ee48b2bd72250dd91db66b
53 N7ad70a1caae14b9bba71f614b903f0a4 rdf:first sg:person.011120621425.25
54 rdf:rest N151e32dae254483ca67e191fea4a2088
55 N7b593e8bfeb641868d8b11776975c597 rdf:first sg:person.011272267131.49
56 rdf:rest N7ad70a1caae14b9bba71f614b903f0a4
57 N975e54f5a7564768a80361d7bc5dd6cf schema:name dimensions_id
58 schema:value pub.1009467295
59 rdf:type schema:PropertyValue
60 Na29f3eab74de4cf48410d0fe44e001e7 schema:name doi
61 schema:value 10.1134/s1070363211120085
62 rdf:type schema:PropertyValue
63 Na971f73ec4654bfa83c5223394a18952 rdf:first sg:person.015057567143.55
64 rdf:rest N7b593e8bfeb641868d8b11776975c597
65 Nca3762aae2ee48b2bd72250dd91db66b rdf:first sg:person.0732162157.42
66 rdf:rest N5d30c7fd24044334a3cc5fbab9419ba6
67 Ne9f80876d5e34d91bce29eca34f20460 rdf:first sg:person.014441433661.39
68 rdf:rest N6f29a09776c44bd3be3959dd6fe168c3
69 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
70 schema:name Chemical Sciences
71 rdf:type schema:DefinedTerm
72 sg:journal.1446214 schema:issn 1070-3632
73 1608-3350
74 schema:name Russian Journal of General Chemistry
75 schema:publisher Pleiades Publishing
76 rdf:type schema:Periodical
77 sg:person.01050521013.60 schema:affiliation grid-institutes:grid.4886.2
78 schema:familyName Korlyukov
79 schema:givenName A. A.
80 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01050521013.60
81 rdf:type schema:Person
82 sg:person.011120621425.25 schema:affiliation grid-institutes:None
83 schema:familyName Abramkin
84 schema:givenName A. M.
85 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011120621425.25
86 rdf:type schema:Person
87 sg:person.011272267131.49 schema:affiliation grid-institutes:None
88 schema:familyName Kuz’mina
89 schema:givenName N. E.
90 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011272267131.49
91 rdf:type schema:Person
92 sg:person.01166103634.96 schema:affiliation grid-institutes:None
93 schema:familyName Storozhenko
94 schema:givenName P. A.
95 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01166103634.96
96 rdf:type schema:Person
97 sg:person.013037424642.28 schema:affiliation grid-institutes:None
98 schema:familyName Loginov
99 schema:givenName S. V.
100 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013037424642.28
101 rdf:type schema:Person
102 sg:person.014441433661.39 schema:affiliation grid-institutes:grid.4886.2
103 schema:familyName Arkhipov
104 schema:givenName D. E.
105 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014441433661.39
106 rdf:type schema:Person
107 sg:person.015057567143.55 schema:affiliation grid-institutes:None
108 schema:familyName Sheludyakov
109 schema:givenName V. D.
110 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015057567143.55
111 rdf:type schema:Person
112 sg:person.0732162157.42 schema:affiliation grid-institutes:None
113 schema:familyName Cheshkov
114 schema:givenName D. A.
115 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0732162157.42
116 rdf:type schema:Person
117 grid-institutes:None schema:alternateName Medical Equipment Scientific Appraisal Center, Moscow, Russia
118 State Research Institute of Chemistry and Technology of Organometallic Compounds, sh. Entuziastov 38, 105118, Moscow, Russia
119 schema:name Medical Equipment Scientific Appraisal Center, Moscow, Russia
120 State Research Institute of Chemistry and Technology of Organometallic Compounds, sh. Entuziastov 38, 105118, Moscow, Russia
121 rdf:type schema:Organization
122 grid-institutes:grid.4886.2 schema:alternateName Nesmeyanov Institute of Organometallic Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia
123 schema:name Nesmeyanov Institute of Organometallic Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia
124 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...