Reactions of 1-nitrocyclohexene with N,N-binucleophiles View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2010-11

AUTHORS

I. E. Efremova, M. I. Vakulenko, K. A. Lysenko, I. S. Bushmarinov, L. V. Lapshina, G. A. Berkova, V. M. Berestovitskaya

ABSTRACT

A modification of 1-nitrocyclohexene synthesis is proposed; its reaction with phenylhydrazine and benzoic acid hydrazide is shown to afford monoadducts, and with hydrazine hydrate, bisaduct. With diphenylguanidine occurs heterocyclization to 1-phenyl-2-N-phenylamino-4,5,6,7-tetrahydrobenzimidazole, whose structure is confirmed by the X-ray diffraction data. The analysis performed for this compound of the electron density distribution function in the crystal made it possible to estimate the charge distribution, π-electrons delocalization nature, and the role of N-H…N, C-H…H-C and C-H…C interactions in the formation of the crystal packing. More... »

PAGES

2298-2305

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070363210110113

DOI

http://dx.doi.org/10.1134/s1070363210110113

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1051195408


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Herzen University", 
          "id": "https://www.grid.ac/institutes/grid.440630.5", 
          "name": [
            "Herzen Russian State Pedagogical University, nab. r. Moiki 48, 191186, St. Petersburg, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Efremova", 
        "givenName": "I. E.", 
        "id": "sg:person.0717604100.39", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0717604100.39"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Herzen University", 
          "id": "https://www.grid.ac/institutes/grid.440630.5", 
          "name": [
            "Herzen Russian State Pedagogical University, nab. r. Moiki 48, 191186, St. Petersburg, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Vakulenko", 
        "givenName": "M. I.", 
        "id": "sg:person.07574057777.75", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07574057777.75"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "A. N. Nesmeyanov Institute of Organoelement Compounds", 
          "id": "https://www.grid.ac/institutes/grid.431939.5", 
          "name": [
            "Nesmeyanov Institute of Organoelemental Compounds, Russian Academy of Sciences, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Lysenko", 
        "givenName": "K. A.", 
        "id": "sg:person.016065625305.54", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016065625305.54"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "A. N. Nesmeyanov Institute of Organoelement Compounds", 
          "id": "https://www.grid.ac/institutes/grid.431939.5", 
          "name": [
            "Nesmeyanov Institute of Organoelemental Compounds, Russian Academy of Sciences, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Bushmarinov", 
        "givenName": "I. S.", 
        "id": "sg:person.01335445233.59", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01335445233.59"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Herzen University", 
          "id": "https://www.grid.ac/institutes/grid.440630.5", 
          "name": [
            "Herzen Russian State Pedagogical University, nab. r. Moiki 48, 191186, St. Petersburg, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Lapshina", 
        "givenName": "L. V.", 
        "id": "sg:person.014545751573.03", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014545751573.03"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Herzen University", 
          "id": "https://www.grid.ac/institutes/grid.440630.5", 
          "name": [
            "Herzen Russian State Pedagogical University, nab. r. Moiki 48, 191186, St. Petersburg, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Berkova", 
        "givenName": "G. A.", 
        "id": "sg:person.016603144075.56", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016603144075.56"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Herzen University", 
          "id": "https://www.grid.ac/institutes/grid.440630.5", 
          "name": [
            "Herzen Russian State Pedagogical University, nab. r. Moiki 48, 191186, St. Petersburg, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Berestovitskaya", 
        "givenName": "V. M.", 
        "id": "sg:person.01051275354.69", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01051275354.69"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1039/c39900000420", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1006115343"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1107/s0567739478001886", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1007167880"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0040-4020(01)81002-4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1020857251"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/hlca.19810640518", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1026501508"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1246/cl.1986.1747", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1031645005"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0040-4039(00)85920-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1046583965"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0040-4039(00)79668-7", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1049186504"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0009-2614(01)00178-6", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050812946"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja00487a088", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055736615"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jo048776w", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056020354"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jo048776w", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056020354"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp057516v", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056064553"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jp057516v", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056064553"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2010-11", 
    "datePublishedReg": "2010-11-01", 
    "description": "A modification of 1-nitrocyclohexene synthesis is proposed; its reaction with phenylhydrazine and benzoic acid hydrazide is shown to afford monoadducts, and with hydrazine hydrate, bisaduct. With diphenylguanidine occurs heterocyclization to 1-phenyl-2-N-phenylamino-4,5,6,7-tetrahydrobenzimidazole, whose structure is confirmed by the X-ray diffraction data. The analysis performed for this compound of the electron density distribution function in the crystal made it possible to estimate the charge distribution, \u03c0-electrons delocalization nature, and the role of N-H\u2026N, C-H\u2026H-C and C-H\u2026C interactions in the formation of the crystal packing.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1134/s1070363210110113", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1109093", 
        "issn": [
          "0022-1279", 
          "0044-460X"
        ], 
        "name": "Russian Journal of General Chemistry", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "11", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "80"
      }
    ], 
    "name": "Reactions of 1-nitrocyclohexene with N,N-binucleophiles", 
    "pagination": "2298-2305", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "f3e01875119dd928b04b06049067c8afe8423d8a0b99040915f4f17c8be465dc"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s1070363210110113"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1051195408"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s1070363210110113", 
      "https://app.dimensions.ai/details/publication/pub.1051195408"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T22:30", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8690_00000508.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1134%2FS1070363210110113"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s1070363210110113'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s1070363210110113'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s1070363210110113'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s1070363210110113'


 

This table displays all metadata directly associated to this object as RDF triples.

139 TRIPLES      21 PREDICATES      38 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s1070363210110113 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N54ecb2ef824a4f0dbe81e9e6e139823e
4 schema:citation https://doi.org/10.1002/hlca.19810640518
5 https://doi.org/10.1016/s0009-2614(01)00178-6
6 https://doi.org/10.1016/s0040-4020(01)81002-4
7 https://doi.org/10.1016/s0040-4039(00)79668-7
8 https://doi.org/10.1016/s0040-4039(00)85920-1
9 https://doi.org/10.1021/ja00487a088
10 https://doi.org/10.1021/jo048776w
11 https://doi.org/10.1021/jp057516v
12 https://doi.org/10.1039/c39900000420
13 https://doi.org/10.1107/s0567739478001886
14 https://doi.org/10.1246/cl.1986.1747
15 schema:datePublished 2010-11
16 schema:datePublishedReg 2010-11-01
17 schema:description A modification of 1-nitrocyclohexene synthesis is proposed; its reaction with phenylhydrazine and benzoic acid hydrazide is shown to afford monoadducts, and with hydrazine hydrate, bisaduct. With diphenylguanidine occurs heterocyclization to 1-phenyl-2-N-phenylamino-4,5,6,7-tetrahydrobenzimidazole, whose structure is confirmed by the X-ray diffraction data. The analysis performed for this compound of the electron density distribution function in the crystal made it possible to estimate the charge distribution, π-electrons delocalization nature, and the role of N-H…N, C-H…H-C and C-H…C interactions in the formation of the crystal packing.
18 schema:genre research_article
19 schema:inLanguage en
20 schema:isAccessibleForFree false
21 schema:isPartOf Na2557f77bc0c4acf82869c7d58cb5c4c
22 Nfdb7c59a34994bf596b8cf06f1747051
23 sg:journal.1109093
24 schema:name Reactions of 1-nitrocyclohexene with N,N-binucleophiles
25 schema:pagination 2298-2305
26 schema:productId N438f0ff00857495c8f18e192ef4ba978
27 N5d5af381efa041f4b5ffb6402034b6cc
28 Ne8ae6fe1c9dd4565b46bec3881be1046
29 schema:sameAs https://app.dimensions.ai/details/publication/pub.1051195408
30 https://doi.org/10.1134/s1070363210110113
31 schema:sdDatePublished 2019-04-10T22:30
32 schema:sdLicense https://scigraph.springernature.com/explorer/license/
33 schema:sdPublisher N660d7339bf734ea7a89d69e54f3fb77f
34 schema:url http://link.springer.com/10.1134%2FS1070363210110113
35 sgo:license sg:explorer/license/
36 sgo:sdDataset articles
37 rdf:type schema:ScholarlyArticle
38 N438f0ff00857495c8f18e192ef4ba978 schema:name doi
39 schema:value 10.1134/s1070363210110113
40 rdf:type schema:PropertyValue
41 N4ebaad5c287e432ab3281bafe056ef10 rdf:first sg:person.014545751573.03
42 rdf:rest Ncd76a0cb57cb44f4963eef77cd804287
43 N54ecb2ef824a4f0dbe81e9e6e139823e rdf:first sg:person.0717604100.39
44 rdf:rest N7e08b5a26b074d92938234343a48ccfb
45 N5d5af381efa041f4b5ffb6402034b6cc schema:name dimensions_id
46 schema:value pub.1051195408
47 rdf:type schema:PropertyValue
48 N61e39282e0c343089f75cc342eaafe54 rdf:first sg:person.01335445233.59
49 rdf:rest N4ebaad5c287e432ab3281bafe056ef10
50 N660d7339bf734ea7a89d69e54f3fb77f schema:name Springer Nature - SN SciGraph project
51 rdf:type schema:Organization
52 N7a1a0a4571d64aa5ae8011e1054c845d rdf:first sg:person.01051275354.69
53 rdf:rest rdf:nil
54 N7e08b5a26b074d92938234343a48ccfb rdf:first sg:person.07574057777.75
55 rdf:rest N80f63437b4b6461081028ffb996a37f4
56 N80f63437b4b6461081028ffb996a37f4 rdf:first sg:person.016065625305.54
57 rdf:rest N61e39282e0c343089f75cc342eaafe54
58 Na2557f77bc0c4acf82869c7d58cb5c4c schema:issueNumber 11
59 rdf:type schema:PublicationIssue
60 Ncd76a0cb57cb44f4963eef77cd804287 rdf:first sg:person.016603144075.56
61 rdf:rest N7a1a0a4571d64aa5ae8011e1054c845d
62 Ne8ae6fe1c9dd4565b46bec3881be1046 schema:name readcube_id
63 schema:value f3e01875119dd928b04b06049067c8afe8423d8a0b99040915f4f17c8be465dc
64 rdf:type schema:PropertyValue
65 Nfdb7c59a34994bf596b8cf06f1747051 schema:volumeNumber 80
66 rdf:type schema:PublicationVolume
67 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
68 schema:name Chemical Sciences
69 rdf:type schema:DefinedTerm
70 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
71 schema:name Physical Chemistry (incl. Structural)
72 rdf:type schema:DefinedTerm
73 sg:journal.1109093 schema:issn 0022-1279
74 0044-460X
75 schema:name Russian Journal of General Chemistry
76 rdf:type schema:Periodical
77 sg:person.01051275354.69 schema:affiliation https://www.grid.ac/institutes/grid.440630.5
78 schema:familyName Berestovitskaya
79 schema:givenName V. M.
80 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01051275354.69
81 rdf:type schema:Person
82 sg:person.01335445233.59 schema:affiliation https://www.grid.ac/institutes/grid.431939.5
83 schema:familyName Bushmarinov
84 schema:givenName I. S.
85 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01335445233.59
86 rdf:type schema:Person
87 sg:person.014545751573.03 schema:affiliation https://www.grid.ac/institutes/grid.440630.5
88 schema:familyName Lapshina
89 schema:givenName L. V.
90 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014545751573.03
91 rdf:type schema:Person
92 sg:person.016065625305.54 schema:affiliation https://www.grid.ac/institutes/grid.431939.5
93 schema:familyName Lysenko
94 schema:givenName K. A.
95 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016065625305.54
96 rdf:type schema:Person
97 sg:person.016603144075.56 schema:affiliation https://www.grid.ac/institutes/grid.440630.5
98 schema:familyName Berkova
99 schema:givenName G. A.
100 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016603144075.56
101 rdf:type schema:Person
102 sg:person.0717604100.39 schema:affiliation https://www.grid.ac/institutes/grid.440630.5
103 schema:familyName Efremova
104 schema:givenName I. E.
105 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0717604100.39
106 rdf:type schema:Person
107 sg:person.07574057777.75 schema:affiliation https://www.grid.ac/institutes/grid.440630.5
108 schema:familyName Vakulenko
109 schema:givenName M. I.
110 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07574057777.75
111 rdf:type schema:Person
112 https://doi.org/10.1002/hlca.19810640518 schema:sameAs https://app.dimensions.ai/details/publication/pub.1026501508
113 rdf:type schema:CreativeWork
114 https://doi.org/10.1016/s0009-2614(01)00178-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050812946
115 rdf:type schema:CreativeWork
116 https://doi.org/10.1016/s0040-4020(01)81002-4 schema:sameAs https://app.dimensions.ai/details/publication/pub.1020857251
117 rdf:type schema:CreativeWork
118 https://doi.org/10.1016/s0040-4039(00)79668-7 schema:sameAs https://app.dimensions.ai/details/publication/pub.1049186504
119 rdf:type schema:CreativeWork
120 https://doi.org/10.1016/s0040-4039(00)85920-1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1046583965
121 rdf:type schema:CreativeWork
122 https://doi.org/10.1021/ja00487a088 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055736615
123 rdf:type schema:CreativeWork
124 https://doi.org/10.1021/jo048776w schema:sameAs https://app.dimensions.ai/details/publication/pub.1056020354
125 rdf:type schema:CreativeWork
126 https://doi.org/10.1021/jp057516v schema:sameAs https://app.dimensions.ai/details/publication/pub.1056064553
127 rdf:type schema:CreativeWork
128 https://doi.org/10.1039/c39900000420 schema:sameAs https://app.dimensions.ai/details/publication/pub.1006115343
129 rdf:type schema:CreativeWork
130 https://doi.org/10.1107/s0567739478001886 schema:sameAs https://app.dimensions.ai/details/publication/pub.1007167880
131 rdf:type schema:CreativeWork
132 https://doi.org/10.1246/cl.1986.1747 schema:sameAs https://app.dimensions.ai/details/publication/pub.1031645005
133 rdf:type schema:CreativeWork
134 https://www.grid.ac/institutes/grid.431939.5 schema:alternateName A. N. Nesmeyanov Institute of Organoelement Compounds
135 schema:name Nesmeyanov Institute of Organoelemental Compounds, Russian Academy of Sciences, Moscow, Russia
136 rdf:type schema:Organization
137 https://www.grid.ac/institutes/grid.440630.5 schema:alternateName Herzen University
138 schema:name Herzen Russian State Pedagogical University, nab. r. Moiki 48, 191186, St. Petersburg, Russia
139 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...