Synthesis, photochromism, and complexing ability of new derivatives of N-aminofulgimide View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2010-09

AUTHORS

L. D. Popov, I. N. Shcherbakov, V. A. Kogan, A. S. Burlov, S. I. Luiksaar, M. M. Krayushkin, O. I. Kobeleva, T. M. Valova, V. A. Barachevskii

ABSTRACT

On the basis of N-aminofulgimide two new photochromic compounds of the fulgimide class were synthesized. The performed spectral-kinetic studies have shown that the obtained fulgimide derivatives suffer thermally irreversible transformation similar to those observed for the starting N-aminofulgimide except for the absorption bands of the corresponding cyclic forms to undergo red shift. One of the obtained compounds is capable to form complexes with rare-earth metal ions. More... »

PAGES

1847-1852

References to SciGraph publications

  • 1992-06. Indole fulgides in CHEMISTRY OF HETEROCYCLIC COMPOUNDS
  • 1992. Fulgides and fulgimides — a promising class of photochrome for application in APPLIED PHOTOCHROMIC POLYMER SYSTEMS
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1134/s1070363210090227

    DOI

    http://dx.doi.org/10.1134/s1070363210090227

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1015854559


    Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
    Incoming Citations Browse incoming citations for this publication using opencitations.net

    JSON-LD is the canonical representation for SciGraph data.

    TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

    [
      {
        "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
        "about": [
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Chemical Sciences", 
            "type": "DefinedTerm"
          }, 
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Inorganic Chemistry", 
            "type": "DefinedTerm"
          }
        ], 
        "author": [
          {
            "affiliation": {
              "alternateName": "Southern Federal University, ul. B. Sadovaya 105, 344104, Rostov-on-Don, Russia", 
              "id": "http://www.grid.ac/institutes/grid.182798.d", 
              "name": [
                "Southern Federal University, ul. B. Sadovaya 105, 344104, Rostov-on-Don, Russia"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Popov", 
            "givenName": "L. D.", 
            "id": "sg:person.0721047070.68", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0721047070.68"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Southern Federal University, ul. B. Sadovaya 105, 344104, Rostov-on-Don, Russia", 
              "id": "http://www.grid.ac/institutes/grid.182798.d", 
              "name": [
                "Southern Federal University, ul. B. Sadovaya 105, 344104, Rostov-on-Don, Russia"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Shcherbakov", 
            "givenName": "I. N.", 
            "id": "sg:person.011547725721.73", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011547725721.73"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Southern Federal University, ul. B. Sadovaya 105, 344104, Rostov-on-Don, Russia", 
              "id": "http://www.grid.ac/institutes/grid.182798.d", 
              "name": [
                "Southern Federal University, ul. B. Sadovaya 105, 344104, Rostov-on-Don, Russia"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Kogan", 
            "givenName": "V. A.", 
            "id": "sg:person.01147254073.80", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01147254073.80"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Institute of Physical and Organic Chemistry of Southern Federal University, Rostov-on-Don, Russia", 
              "id": "http://www.grid.ac/institutes/grid.182798.d", 
              "name": [
                "Institute of Physical and Organic Chemistry of Southern Federal University, Rostov-on-Don, Russia"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Burlov", 
            "givenName": "A. S.", 
            "id": "sg:person.011000206727.62", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011000206727.62"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Zelinskii Institute of Organic Chemistry of Russian Academy of Sciences, Moscow, Russia", 
              "id": "http://www.grid.ac/institutes/grid.439283.7", 
              "name": [
                "Zelinskii Institute of Organic Chemistry of Russian Academy of Sciences, Moscow, Russia"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Luiksaar", 
            "givenName": "S. I.", 
            "id": "sg:person.014424452151.41", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014424452151.41"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Zelinskii Institute of Organic Chemistry of Russian Academy of Sciences, Moscow, Russia", 
              "id": "http://www.grid.ac/institutes/grid.439283.7", 
              "name": [
                "Zelinskii Institute of Organic Chemistry of Russian Academy of Sciences, Moscow, Russia"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Krayushkin", 
            "givenName": "M. M.", 
            "id": "sg:person.011757735436.71", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011757735436.71"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Photochemistry Center of Russian Academy of Sciences, Moscow, Russia", 
              "id": "http://www.grid.ac/institutes/grid.465313.6", 
              "name": [
                "Photochemistry Center of Russian Academy of Sciences, Moscow, Russia"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Kobeleva", 
            "givenName": "O. I.", 
            "id": "sg:person.013722645212.67", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013722645212.67"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Photochemistry Center of Russian Academy of Sciences, Moscow, Russia", 
              "id": "http://www.grid.ac/institutes/grid.465313.6", 
              "name": [
                "Photochemistry Center of Russian Academy of Sciences, Moscow, Russia"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Valova", 
            "givenName": "T. M.", 
            "id": "sg:person.014501760523.50", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014501760523.50"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Photochemistry Center of Russian Academy of Sciences, Moscow, Russia", 
              "id": "http://www.grid.ac/institutes/grid.465313.6", 
              "name": [
                "Photochemistry Center of Russian Academy of Sciences, Moscow, Russia"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Barachevskii", 
            "givenName": "V. A.", 
            "id": "sg:person.012536532251.79", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012536532251.79"
            ], 
            "type": "Person"
          }
        ], 
        "citation": [
          {
            "id": "sg:pub.10.1007/978-94-011-3050-9_3", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1089517111", 
              "https://doi.org/10.1007/978-94-011-3050-9_3"
            ], 
            "type": "CreativeWork"
          }, 
          {
            "id": "sg:pub.10.1007/bf00529332", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1010978939", 
              "https://doi.org/10.1007/bf00529332"
            ], 
            "type": "CreativeWork"
          }
        ], 
        "datePublished": "2010-09", 
        "datePublishedReg": "2010-09-01", 
        "description": "On the basis of N-aminofulgimide two new photochromic compounds of the fulgimide class were synthesized. The performed spectral-kinetic studies have shown that the obtained fulgimide derivatives suffer thermally irreversible transformation similar to those observed for the starting N-aminofulgimide except for the absorption bands of the corresponding cyclic forms to undergo red shift. One of the obtained compounds is capable to form complexes with rare-earth metal ions.", 
        "genre": "article", 
        "id": "sg:pub.10.1134/s1070363210090227", 
        "inLanguage": "en", 
        "isAccessibleForFree": false, 
        "isPartOf": [
          {
            "id": "sg:journal.1109093", 
            "issn": [
              "1070-3632", 
              "1608-3350"
            ], 
            "name": "Russian Journal of General Chemistry", 
            "publisher": "Pleiades Publishing", 
            "type": "Periodical"
          }, 
          {
            "issueNumber": "9", 
            "type": "PublicationIssue"
          }, 
          {
            "type": "PublicationVolume", 
            "volumeNumber": "80"
          }
        ], 
        "keywords": [
          "rare-earth metal ions", 
          "spectral-kinetic study", 
          "new photochromic compound", 
          "metal ions", 
          "photochromic compounds", 
          "red shift", 
          "absorption bands", 
          "cyclic form", 
          "new derivatives", 
          "irreversible transformation", 
          "compounds", 
          "derivatives", 
          "photochromism", 
          "ions", 
          "synthesis", 
          "complexes", 
          "band", 
          "shift", 
          "transformation", 
          "form", 
          "ability", 
          "basis", 
          "class", 
          "study", 
          "aminofulgimide two new photochromic compounds", 
          "two new photochromic compounds", 
          "fulgimide class", 
          "fulgimide derivatives", 
          "aminofulgimide", 
          "corresponding cyclic forms"
        ], 
        "name": "Synthesis, photochromism, and complexing ability of new derivatives of N-aminofulgimide", 
        "pagination": "1847-1852", 
        "productId": [
          {
            "name": "dimensions_id", 
            "type": "PropertyValue", 
            "value": [
              "pub.1015854559"
            ]
          }, 
          {
            "name": "doi", 
            "type": "PropertyValue", 
            "value": [
              "10.1134/s1070363210090227"
            ]
          }
        ], 
        "sameAs": [
          "https://doi.org/10.1134/s1070363210090227", 
          "https://app.dimensions.ai/details/publication/pub.1015854559"
        ], 
        "sdDataset": "articles", 
        "sdDatePublished": "2022-01-01T18:22", 
        "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
        "sdPublisher": {
          "name": "Springer Nature - SN SciGraph project", 
          "type": "Organization"
        }, 
        "sdSource": "s3://com-springernature-scigraph/baseset/20220101/entities/gbq_results/article/article_512.jsonl", 
        "type": "ScholarlyArticle", 
        "url": "https://doi.org/10.1134/s1070363210090227"
      }
    ]
     

    Download the RDF metadata as:  json-ld nt turtle xml License info

    HOW TO GET THIS DATA PROGRAMMATICALLY:

    JSON-LD is a popular format for linked data which is fully compatible with JSON.

    curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s1070363210090227'

    N-Triples is a line-based linked data format ideal for batch operations.

    curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s1070363210090227'

    Turtle is a human-readable linked data format.

    curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s1070363210090227'

    RDF/XML is a standard XML format for linked data.

    curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s1070363210090227'


     

    This table displays all metadata directly associated to this object as RDF triples.

    160 TRIPLES      22 PREDICATES      58 URIs      48 LITERALS      6 BLANK NODES

    Subject Predicate Object
    1 sg:pub.10.1134/s1070363210090227 schema:about anzsrc-for:03
    2 anzsrc-for:0302
    3 schema:author N054bf1bf56094b579fba080e8423159c
    4 schema:citation sg:pub.10.1007/978-94-011-3050-9_3
    5 sg:pub.10.1007/bf00529332
    6 schema:datePublished 2010-09
    7 schema:datePublishedReg 2010-09-01
    8 schema:description On the basis of N-aminofulgimide two new photochromic compounds of the fulgimide class were synthesized. The performed spectral-kinetic studies have shown that the obtained fulgimide derivatives suffer thermally irreversible transformation similar to those observed for the starting N-aminofulgimide except for the absorption bands of the corresponding cyclic forms to undergo red shift. One of the obtained compounds is capable to form complexes with rare-earth metal ions.
    9 schema:genre article
    10 schema:inLanguage en
    11 schema:isAccessibleForFree false
    12 schema:isPartOf N9c354260cbe042af8b36e53ef45c9048
    13 Nb1b77bd9c9ac4cac9cb007513f5bf8ce
    14 sg:journal.1109093
    15 schema:keywords ability
    16 absorption bands
    17 aminofulgimide
    18 aminofulgimide two new photochromic compounds
    19 band
    20 basis
    21 class
    22 complexes
    23 compounds
    24 corresponding cyclic forms
    25 cyclic form
    26 derivatives
    27 form
    28 fulgimide class
    29 fulgimide derivatives
    30 ions
    31 irreversible transformation
    32 metal ions
    33 new derivatives
    34 new photochromic compound
    35 photochromic compounds
    36 photochromism
    37 rare-earth metal ions
    38 red shift
    39 shift
    40 spectral-kinetic study
    41 study
    42 synthesis
    43 transformation
    44 two new photochromic compounds
    45 schema:name Synthesis, photochromism, and complexing ability of new derivatives of N-aminofulgimide
    46 schema:pagination 1847-1852
    47 schema:productId N2aeca705e0ed438c973b65f4c5a9ee49
    48 N84a1e1edf2cd450e88f941108116dd32
    49 schema:sameAs https://app.dimensions.ai/details/publication/pub.1015854559
    50 https://doi.org/10.1134/s1070363210090227
    51 schema:sdDatePublished 2022-01-01T18:22
    52 schema:sdLicense https://scigraph.springernature.com/explorer/license/
    53 schema:sdPublisher Ne51cda47d5fa4ecf8ecfd2dfd4353c48
    54 schema:url https://doi.org/10.1134/s1070363210090227
    55 sgo:license sg:explorer/license/
    56 sgo:sdDataset articles
    57 rdf:type schema:ScholarlyArticle
    58 N054bf1bf56094b579fba080e8423159c rdf:first sg:person.0721047070.68
    59 rdf:rest Nba888b8b9d734e8da00042dd8e16fb9a
    60 N11d9ce13171645a4aac3469ef63a982c rdf:first sg:person.011000206727.62
    61 rdf:rest Nf8995ced3c4a4d80801238593c53b88a
    62 N2aeca705e0ed438c973b65f4c5a9ee49 schema:name dimensions_id
    63 schema:value pub.1015854559
    64 rdf:type schema:PropertyValue
    65 N3ad3d453b64d4d33a0bbe141b42fe41d rdf:first sg:person.013722645212.67
    66 rdf:rest N5b0bfe4f8db24b6eafabb07ff708bd2a
    67 N5b0bfe4f8db24b6eafabb07ff708bd2a rdf:first sg:person.014501760523.50
    68 rdf:rest Nc62243917e87489eb59730052024d9a7
    69 N6e39b13119174afb88b516b45486bb55 rdf:first sg:person.01147254073.80
    70 rdf:rest N11d9ce13171645a4aac3469ef63a982c
    71 N84a1e1edf2cd450e88f941108116dd32 schema:name doi
    72 schema:value 10.1134/s1070363210090227
    73 rdf:type schema:PropertyValue
    74 N9c354260cbe042af8b36e53ef45c9048 schema:issueNumber 9
    75 rdf:type schema:PublicationIssue
    76 Nb1b77bd9c9ac4cac9cb007513f5bf8ce schema:volumeNumber 80
    77 rdf:type schema:PublicationVolume
    78 Nba888b8b9d734e8da00042dd8e16fb9a rdf:first sg:person.011547725721.73
    79 rdf:rest N6e39b13119174afb88b516b45486bb55
    80 Nc62243917e87489eb59730052024d9a7 rdf:first sg:person.012536532251.79
    81 rdf:rest rdf:nil
    82 Nd5390f791a8d47a98d1f7140556dd64a rdf:first sg:person.011757735436.71
    83 rdf:rest N3ad3d453b64d4d33a0bbe141b42fe41d
    84 Ne51cda47d5fa4ecf8ecfd2dfd4353c48 schema:name Springer Nature - SN SciGraph project
    85 rdf:type schema:Organization
    86 Nf8995ced3c4a4d80801238593c53b88a rdf:first sg:person.014424452151.41
    87 rdf:rest Nd5390f791a8d47a98d1f7140556dd64a
    88 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
    89 schema:name Chemical Sciences
    90 rdf:type schema:DefinedTerm
    91 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
    92 schema:name Inorganic Chemistry
    93 rdf:type schema:DefinedTerm
    94 sg:journal.1109093 schema:issn 1070-3632
    95 1608-3350
    96 schema:name Russian Journal of General Chemistry
    97 schema:publisher Pleiades Publishing
    98 rdf:type schema:Periodical
    99 sg:person.011000206727.62 schema:affiliation grid-institutes:grid.182798.d
    100 schema:familyName Burlov
    101 schema:givenName A. S.
    102 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011000206727.62
    103 rdf:type schema:Person
    104 sg:person.01147254073.80 schema:affiliation grid-institutes:grid.182798.d
    105 schema:familyName Kogan
    106 schema:givenName V. A.
    107 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01147254073.80
    108 rdf:type schema:Person
    109 sg:person.011547725721.73 schema:affiliation grid-institutes:grid.182798.d
    110 schema:familyName Shcherbakov
    111 schema:givenName I. N.
    112 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011547725721.73
    113 rdf:type schema:Person
    114 sg:person.011757735436.71 schema:affiliation grid-institutes:grid.439283.7
    115 schema:familyName Krayushkin
    116 schema:givenName M. M.
    117 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011757735436.71
    118 rdf:type schema:Person
    119 sg:person.012536532251.79 schema:affiliation grid-institutes:grid.465313.6
    120 schema:familyName Barachevskii
    121 schema:givenName V. A.
    122 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012536532251.79
    123 rdf:type schema:Person
    124 sg:person.013722645212.67 schema:affiliation grid-institutes:grid.465313.6
    125 schema:familyName Kobeleva
    126 schema:givenName O. I.
    127 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013722645212.67
    128 rdf:type schema:Person
    129 sg:person.014424452151.41 schema:affiliation grid-institutes:grid.439283.7
    130 schema:familyName Luiksaar
    131 schema:givenName S. I.
    132 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014424452151.41
    133 rdf:type schema:Person
    134 sg:person.014501760523.50 schema:affiliation grid-institutes:grid.465313.6
    135 schema:familyName Valova
    136 schema:givenName T. M.
    137 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014501760523.50
    138 rdf:type schema:Person
    139 sg:person.0721047070.68 schema:affiliation grid-institutes:grid.182798.d
    140 schema:familyName Popov
    141 schema:givenName L. D.
    142 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0721047070.68
    143 rdf:type schema:Person
    144 sg:pub.10.1007/978-94-011-3050-9_3 schema:sameAs https://app.dimensions.ai/details/publication/pub.1089517111
    145 https://doi.org/10.1007/978-94-011-3050-9_3
    146 rdf:type schema:CreativeWork
    147 sg:pub.10.1007/bf00529332 schema:sameAs https://app.dimensions.ai/details/publication/pub.1010978939
    148 https://doi.org/10.1007/bf00529332
    149 rdf:type schema:CreativeWork
    150 grid-institutes:grid.182798.d schema:alternateName Institute of Physical and Organic Chemistry of Southern Federal University, Rostov-on-Don, Russia
    151 Southern Federal University, ul. B. Sadovaya 105, 344104, Rostov-on-Don, Russia
    152 schema:name Institute of Physical and Organic Chemistry of Southern Federal University, Rostov-on-Don, Russia
    153 Southern Federal University, ul. B. Sadovaya 105, 344104, Rostov-on-Don, Russia
    154 rdf:type schema:Organization
    155 grid-institutes:grid.439283.7 schema:alternateName Zelinskii Institute of Organic Chemistry of Russian Academy of Sciences, Moscow, Russia
    156 schema:name Zelinskii Institute of Organic Chemistry of Russian Academy of Sciences, Moscow, Russia
    157 rdf:type schema:Organization
    158 grid-institutes:grid.465313.6 schema:alternateName Photochemistry Center of Russian Academy of Sciences, Moscow, Russia
    159 schema:name Photochemistry Center of Russian Academy of Sciences, Moscow, Russia
    160 rdf:type schema:Organization
     




    Preview window. Press ESC to close (or click here)


    ...