Reaction of 2-acylamino-3,3-dichloroacrylonitriles with 2-aminothiophenol View Full Text


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Article Info

DATE

2010-09

AUTHORS

O. V. Shablykin, S. A. Chumachenko, V. S. Brovarets

ABSTRACT

Reactions of 2-acylamino-3,3-dichloroacrylonitriles with 2-aminothiophenol in the presence of triethylamine was shown to lead to 2-aryl-3,3-bis(2-aminophenylsulfanyl)acrylonitrile, which suffered a transformation into 5-amino-4-(benzothiazol-2-yl)oxazole derivatives at heating without solvent. The formation of the same compounds from these reagents proceeded in one step in the presence of N,N-dimethylaniline. The presence of primary amino groups in the derivatives of 5-aminooxazole was confirmed by acylation and further transformation, which was used also for indroduction of various biophoric sites in 5 position of the oxazole ring. More... »

PAGES

1795-1799

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070363210090136

DOI

http://dx.doi.org/10.1134/s1070363210090136

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1034983651


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