New heterosilocanes, 1,1-difluoroand 1-phenyl-1-fluoro-2,8-dioxa-5-chalcogenosilocanes View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2010-07

AUTHORS

M. G. Voronkov, O. M. Trofimova, E. A. Grebneva, A. I. Albanov, T. N. Aksamentova, N. N. Chipanina, A. S. Soldatenko

ABSTRACT

The earlier unknown Si-fluorinated 2,8-dioxa-5-chalcogenosilocanes RFSi(OCH2CH2)2Y (R = Ph, F; Y = O, S) were synthesized. According to calculations, there is a weak transannular coordinate interaction Y→Si (Y = O, S), which is much weaker than that in the isostructural quasisilatranes (Y = N). At low temperatures, 1,1-difluoro-2,5,8-trioxasilocane forms a dimer, in which two molecules of the monomer are linked by four fluorine bridges Si-F→Si located in pairs in the two orthogonal planes SiF2Si. More... »

PAGES

1276-1282

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070363210070108

DOI

http://dx.doi.org/10.1134/s1070363210070108

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1039508423


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