Transformation of substituted 5-amino-1,3-oxazole-4-carbonitriles into new 3,4,5-triaminopyrazole derivatives View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2010-01

AUTHORS

A. P. Kozachenko, O. V. Shablykin, A. N. Vasilenko, V. S. Brovarets

ABSTRACT

Reactions of accessible 5-alkylamino- and 5-arylamino-1,3-oxazole-4-carbonitriles with hydrazine hydrate on heating involved a complex transformation sequence resulting in the formation of 3,4,5-triaminopyrazole derivatives. The structure of the products was confirmed by their cyclocondensation with acetylacetone, leading to 2-alkyl(aryl)amino-3-acylamino-5,7-dimethylpyrazolo[1,5-a]pyrimidines which were identified by NMR spectroscopy using COSY, NOESY, HMQC, and HMBC techniques. More... »

PAGES

127-132

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070363210010172

DOI

http://dx.doi.org/10.1134/s1070363210010172

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1047243359


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