Stoichiometry of the reaction of diphenylchlorophosphine with dimethylformamide in the presence of NaI View Full Text


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Article Info

DATE

2010-01

AUTHORS

V. P. Morgalyuk, P. V. Petrovskii, K. A. Lysenko, E. E. Nifant’ev

ABSTRACT

Stoichiometric relations of initial compounds and reaction products in the synthesis of N,N-dialkyl-(diphenylphosphinomethylene)iminium are established; the second reaction product is diphenylphosphinic iodide. Bringing triphenylphosphine into the reaction increases the N,N-dialkyl(diphenylphosphinomethylene)-iminium yield approximately twice. One of the reaction intermediates is shown to be iododiphenylphosphine. The reaction can be regarded as disproportionation.

PAGES

100-105

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070363210010123

DOI

http://dx.doi.org/10.1134/s1070363210010123

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1019083963


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