Directivity of the intramolecular O→Si bond in pentacoordinate organosilicone compounds View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2009-11

AUTHORS

T. N. Aksamentova, N. N. Chipanina, M. G. Voronkov, O. M. Trofimova, E. A. Zelbst, V. K. Turchaninov

ABSTRACT

According to the data of X-ray diffraction analysis and quantum chemical calculations, in the hypervalent silicon compounds where the coordination cycle is closed by the C=O→Si-F fragment, the O→Si interatomic distance is governed by the orientation of the silicon atom determined by the C=O→Si angle. This is an indication of a directivity of the coordination bond O→Si; a regular variation in the nature of the latter is reflected in the observed dependence of the O→Si distance on the C=O→Si angle. More... »

PAGES

2328-2338

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070363209110085

DOI

http://dx.doi.org/10.1134/s1070363209110085

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1041647361


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