O-vinylacetoxime as a hydrogen bond acceptor View Full Text


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Article Info

DATE

2009-03

AUTHORS

T. N. Aksamentova, N. N. Chipanina, A. I. Mikhaleva, B. A. Trofimov

ABSTRACT

According to quantum chemical calculations (B3LYP/6-311G*) and IR spectroscopy the basicity of oxygen atom of O-vinylacetoxime is substantially lower than that of O-ethylacetoxime and is comparable to the basicity of phenyl vinyl and diphenyl ethers. In CCl4 solution, O-vinylacetoxime gives H-complexes wit methanol by formation of N···HO bonds. With phenol and trifluoroacetic acid under these conditions it enters in the reaction of electrophilic addition. O-Ethylacetoxime in inert media forms with methanol and phenol two types of H-complexes with the N···HO or O···HO bonds. More... »

PAGES

390-397

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070363209030104

DOI

http://dx.doi.org/10.1134/s1070363209030104

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1031705329


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