Synthesis and structure of (C=O→Si←O′=C′)bis(2-methyl-4-oxopyran-3-yloxy)difluoro-(λ6)siliconium View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2009-01

AUTHORS

T. N. Aksamentova, N. N. Chipanina, M. G. Voronkov, E. A. Grebneva, A. I. Albanov, O. M. Trofimova, S. A. Mukha, B. G. Sukhov

ABSTRACT

A new six-coordinate silicon compound, (C=O→Si←O′=C′)bis(2-methyl-4-oxopyran-3-yloxy)-difluoro(λ6)siliconium, containing two five-membered rings closed by C=O→Si coordination bonds, forms o protodesilylation trifluoro(phenyl)silane with 3-hydroxy-2-methylpyran-4-one (maltol). According to multinuclear NMR and IR spectral data and quantum-chemical calculations, the silicon atom in this compound has an octahedral environment with two cis-arranged C=O→Si bonds

PAGES

98-103

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070363209010150

DOI

http://dx.doi.org/10.1134/s1070363209010150

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1031146481


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