Molecular design of new magnetically active copper complexes with heteroaromatic schiff bases and azo compounds View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2008-06

AUTHORS

A. S. Burlov, A. I. Uraev, V. N. Ikorskii, S. A. Nikolaevskii, Yu. V. Koshchienko, I. S. Vasil’chenko, D. A. Garnovskii, V. G. Vlasenko, Ya. V. Zubavichus, L. N. Divaeva, G. S. Borodkin, A. D. Garnovskii

ABSTRACT

Copper chelates with tridentate ligands containing pyridine or pyrazole ring at the azomethine or azo fragment were synthesized by chemical electrochemical methods, and their structure was characterized by the EXAFS spectra. Thermal magnetochemical analysis of the complexes revealed antiferromagnetic exchange interaction in all complexes. The exchange interaction parameter of the complex containing an N-tosylamino group in the ortho position with respect to the azomethine group is much lesser than that of the corresponding complex having an oxygen atom in the same position. The copper chelate derived from azopyrazole ligand shows low-temperature ferromagnetic phase transition. More... »

PAGES

1230-1235

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070363208060224

DOI

http://dx.doi.org/10.1134/s1070363208060224

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1002614484


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