5s5p element dopant cations: Møssbauer probes for studying chemical reactions at the solid-gas interface View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2008-05

AUTHORS

P. B. Fabrichnyi, M. I. Afanasov, M. Danot

ABSTRACT

Annealing in reducing atmosphere allows stabilization of the Sn4+, Sb5+, or Te6+ dopant cations in a lower oxidation state. Due to its stereochemical activity, the lone electron pair of the resulting Sn2+, Sb3+, or Te4+ favors the location of these species in low-coordination sites, immediately on the surface of the substrate-compound crystallites. This allows 119Sn, 121Sb, or 125Te Møssbauer spectroscopy to be applied for studying the processes occurring at the solid-gas interface. Results of such studies, mainly devoted to the Cr2O3 antiferromagnetic substrate, were discussed, along with the prospects of searching appropriate substrate-compounds of other types. More... »

PAGES

1060-1069

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070363208050393

DOI

http://dx.doi.org/10.1134/s1070363208050393

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1012304856


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