Effect of ortho-methyl groups in the benzene rings of the macrocyclic frame on the chemistry of phosphacavitands View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2008-02

AUTHORS

V. I. Maslennikova, T. V. Guzeeva, O. S. Serkova, L. K. Vasyanina, K. A. Lysenko, E. E. Nifant’ev

ABSTRACT

Effect of ortho-methyl groups in the benzene rings of the macrocyclic matrix on the chemistry of cavitands with phosphorous amide bridges in the upper rim is studied. The presence of ortho-methyl groups is shown to prevent formation of phosphacavitands of C4v symmetry and favor formation of macrocyclic systems of C2v symmetry, enhance solubility of phosphacavitands in organic solvents, hinder oxidation of phospha(III)cavitands and decrease the yield of phospha(V)cavitands, prevent formation of binuclear molybdenum complexes of phosphorous amide cavitands, and favor formation of their tetranuclear analogs. More... »

PAGES

175

References to SciGraph publications

  • 1992-03. Molecular container compounds in NATURE
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1134/s1070363208020047

    DOI

    http://dx.doi.org/10.1134/s1070363208020047

    DIMENSIONS

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