Solvatochromism of heteroaromatic compounds: XXXI. Energetics of hydrogen bonding between N-methyltrifluoromethanesulfonamide and ethers View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2007-02

AUTHORS

I. V. Sterkhova, A. I. Vokin, L. P. Oznobikhina, N. N. Chipanina, B. A. Shainyan, V. K. Turchaninov

ABSTRACT

For a series of H-complexes of ethers with N-methyltrifluoromethanesulfonamide CF3SO2NHMe, a proportionality between the spectral shift (ΔvNH) and the enthalpy of complex formation (ΔH) was found. Comparison with hydroxyl-containing H-bond donors revealed the following contradiction: ΔH increases in the order CF3SO2NHMe < MeOH < PhOH, whereas ΔvXH increases in the order MeOH < CF3SO2NHMe ∼ PhOH. The absence of a single Badger-Bauer relationship ΔvXH ∼ f(ΔH) is due to the contribution of universal interactions into the enthalpy of H-complex formation. The account for these interactions allowed calculation of the energy of an intermolecular hydrogen bond, which varies in parallel with the spectral shift: MeOH < CF3SO2NHMe ∼ PhOH. More... »

PAGES

264-273

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070363207020120

DOI

http://dx.doi.org/10.1134/s1070363207020120

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1002403592


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