Solvatochromism of heteroaromatic compounds: XXX. N-Methyltrifluoromethanesulfonamide as hydrogen-bond donor View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2007-01

AUTHORS

I. V. Sterkhova, N. N. Chipanina, B. A. Shainyan, V. K. Turchaninov

ABSTRACT

In two-centered H-complexes with protophilic solvents, the monomer of N-methyltrifluoromethanesulfonamide I behaves as a strong H-bond donor, stronger than 4-fluorophenol and ranking second after 4-nitrophenol. In protophilic media, amide I exists as monomeric H-complexes with a two-centered H-bond and 1:2 H-complexes of the open-chair dimer with a bifurcated (three-centered) hydrogen bond. The formation of a strong bifurcated H-bond weaken the bridging N-H.‥O=S bond. More... »

PAGES

84-89

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070363207010112

DOI

http://dx.doi.org/10.1134/s1070363207010112

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1045944104


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