Molecular structure of complexes with bifurcated hydrogen bond: IV. Solvate H-complexes of N-methyltrifluoromethanesulfonamide in aprotic protophilic media View Full Text


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Article Info

DATE

2007-01

AUTHORS

I. V. Sterkhova, N. N. Chipanina, B. A. Shainyan, V. K. Turchaninov

ABSTRACT

Analysis of the IR spectra of N-methyltrifluoromethanesulfonamide, as well as quantum-chemical calculations of solvate complexes of its monomer and open-chain dimer have demonstrated inadequacy of the model assuming the presence in protophilic solvents of a 1:1 monomer H-complex only. A model is suggested, which is based on an equilibrium between the 1:1 monomer H-complexes and open-chain dimer complexes of variable composition. The proposed model is much better consistent with experimental data. More... »

PAGES

73-83

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070363207010100

DOI

http://dx.doi.org/10.1134/s1070363207010100

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1000075483


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