Reaction of tetrafluorosilane with tris(2-hydroxyethyl)amine, tris(2-trimethylsiloxyethyl)amine and bis(2-trimethylsiloxyethyl)amine and its N-methyl derivative. 1,1-difluoroquasisilatranes View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2006-12

AUTHORS

M. G. Voronkov, E. A. Grebneva, O. M. Trofimova, A. I. Albanov, N. F. Chernov, N. N. Chipanina

ABSTRACT

Reaction of tetrafluorosilane with tris(2-hydroxyethyl)-and tris(2-trimethylsiloxyethyl)amine results in formation of 1-fluorosilatrane and fluorosilatrane in 75 and 53% yield, respectively. Reaction of tetrafluorosilane with bis(2-trimethylsiloxyethyl)amine and its N-methyl derivative leads to the hitherto unknown 1,1-difluoroquasisilatranes (N → Si) F2Si(OCH2CH2)2NR (R = H, Me) containing donor-acceptor bond N → Si and pentacoordinate silicon atom. The structure of the synthesized compounds was proved by 1H, 13C, 15N, 19F, 29Si NMR and IR spectroscopy. More... »

PAGES

1851-1853

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070363206120012

DOI

http://dx.doi.org/10.1134/s1070363206120012

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1029333622


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