Reaction of tetrafluorosilane with tris(2-hydroxyethyl)amine, tris(2-trimethylsiloxyethyl)amine and bis(2-trimethylsiloxyethyl)amine and its N-methyl derivative. 1,1-difluoroquasisilatranes View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2006-12

AUTHORS

M. G. Voronkov, E. A. Grebneva, O. M. Trofimova, A. I. Albanov, N. F. Chernov, N. N. Chipanina

ABSTRACT

Reaction of tetrafluorosilane with tris(2-hydroxyethyl)-and tris(2-trimethylsiloxyethyl)amine results in formation of 1-fluorosilatrane and fluorosilatrane in 75 and 53% yield, respectively. Reaction of tetrafluorosilane with bis(2-trimethylsiloxyethyl)amine and its N-methyl derivative leads to the hitherto unknown 1,1-difluoroquasisilatranes (N → Si) F2Si(OCH2CH2)2NR (R = H, Me) containing donor-acceptor bond N → Si and pentacoordinate silicon atom. The structure of the synthesized compounds was proved by 1H, 13C, 15N, 19F, 29Si NMR and IR spectroscopy. More... »

PAGES

1851-1853

References to SciGraph publications

  • 1965-01. Atranes. II. Dipole moments and structure of silatranes in CHEMISTRY OF HETEROCYCLIC COMPOUNDS
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1134/s1070363206120012

    DOI

    http://dx.doi.org/10.1134/s1070363206120012

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1029333622


    Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
    Incoming Citations Browse incoming citations for this publication using opencitations.net

    JSON-LD is the canonical representation for SciGraph data.

    TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

    [
      {
        "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
        "about": [
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Chemical Sciences", 
            "type": "DefinedTerm"
          }, 
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Physical Chemistry (incl. Structural)", 
            "type": "DefinedTerm"
          }
        ], 
        "author": [
          {
            "affiliation": {
              "alternateName": "Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia", 
              "id": "http://www.grid.ac/institutes/grid.415877.8", 
              "name": [
                "Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Voronkov", 
            "givenName": "M. G.", 
            "id": "sg:person.016410733065.70", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016410733065.70"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia", 
              "id": "http://www.grid.ac/institutes/grid.415877.8", 
              "name": [
                "Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Grebneva", 
            "givenName": "E. A.", 
            "id": "sg:person.010114234171.52", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010114234171.52"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia", 
              "id": "http://www.grid.ac/institutes/grid.415877.8", 
              "name": [
                "Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Trofimova", 
            "givenName": "O. M.", 
            "id": "sg:person.010446355057.52", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010446355057.52"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia", 
              "id": "http://www.grid.ac/institutes/grid.415877.8", 
              "name": [
                "Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Albanov", 
            "givenName": "A. I.", 
            "id": "sg:person.0754654523.04", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0754654523.04"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia", 
              "id": "http://www.grid.ac/institutes/grid.415877.8", 
              "name": [
                "Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Chernov", 
            "givenName": "N. F.", 
            "id": "sg:person.012621274514.60", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012621274514.60"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia", 
              "id": "http://www.grid.ac/institutes/grid.415877.8", 
              "name": [
                "Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Chipanina", 
            "givenName": "N. N.", 
            "id": "sg:person.0640426123.25", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0640426123.25"
            ], 
            "type": "Person"
          }
        ], 
        "citation": [
          {
            "id": "sg:pub.10.1007/bf01168916", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1028143939", 
              "https://doi.org/10.1007/bf01168916"
            ], 
            "type": "CreativeWork"
          }
        ], 
        "datePublished": "2006-12", 
        "datePublishedReg": "2006-12-01", 
        "description": "Reaction of tetrafluorosilane with tris(2-hydroxyethyl)-and tris(2-trimethylsiloxyethyl)amine results in formation of 1-fluorosilatrane and fluorosilatrane in 75 and 53% yield, respectively. Reaction of tetrafluorosilane with bis(2-trimethylsiloxyethyl)amine and its N-methyl derivative leads to the hitherto unknown 1,1-difluoroquasisilatranes (N \u2192 Si) F2Si(OCH2CH2)2NR (R = H, Me) containing donor-acceptor bond N \u2192 Si and pentacoordinate silicon atom. The structure of the synthesized compounds was proved by 1H, 13C, 15N, 19F, 29Si NMR and IR spectroscopy.", 
        "genre": "article", 
        "id": "sg:pub.10.1134/s1070363206120012", 
        "inLanguage": "en", 
        "isAccessibleForFree": false, 
        "isPartOf": [
          {
            "id": "sg:journal.1109093", 
            "issn": [
              "1070-3632", 
              "1608-3350"
            ], 
            "name": "Russian Journal of General Chemistry", 
            "publisher": "Pleiades Publishing", 
            "type": "Periodical"
          }, 
          {
            "issueNumber": "12", 
            "type": "PublicationIssue"
          }, 
          {
            "type": "PublicationVolume", 
            "volumeNumber": "76"
          }
        ], 
        "keywords": [
          "methyl derivatives", 
          "IR spectroscopy", 
          "bond N", 
          "silicon atoms", 
          "tetrafluorosilane", 
          "reaction", 
          "derivatives", 
          "NMR", 
          "spectroscopy", 
          "atoms", 
          "compounds", 
          "yield", 
          "formation", 
          "Si", 
          "structure", 
          "results", 
          "Reaction of tetrafluorosilane", 
          "fluorosilatrane", 
          "donor-acceptor bond N"
        ], 
        "name": "Reaction of tetrafluorosilane with tris(2-hydroxyethyl)amine, tris(2-trimethylsiloxyethyl)amine and bis(2-trimethylsiloxyethyl)amine and its N-methyl derivative. 1,1-difluoroquasisilatranes", 
        "pagination": "1851-1853", 
        "productId": [
          {
            "name": "dimensions_id", 
            "type": "PropertyValue", 
            "value": [
              "pub.1029333622"
            ]
          }, 
          {
            "name": "doi", 
            "type": "PropertyValue", 
            "value": [
              "10.1134/s1070363206120012"
            ]
          }
        ], 
        "sameAs": [
          "https://doi.org/10.1134/s1070363206120012", 
          "https://app.dimensions.ai/details/publication/pub.1029333622"
        ], 
        "sdDataset": "articles", 
        "sdDatePublished": "2022-01-01T18:16", 
        "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
        "sdPublisher": {
          "name": "Springer Nature - SN SciGraph project", 
          "type": "Organization"
        }, 
        "sdSource": "s3://com-springernature-scigraph/baseset/20220101/entities/gbq_results/article/article_428.jsonl", 
        "type": "ScholarlyArticle", 
        "url": "https://doi.org/10.1134/s1070363206120012"
      }
    ]
     

    Download the RDF metadata as:  json-ld nt turtle xml License info

    HOW TO GET THIS DATA PROGRAMMATICALLY:

    JSON-LD is a popular format for linked data which is fully compatible with JSON.

    curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s1070363206120012'

    N-Triples is a line-based linked data format ideal for batch operations.

    curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s1070363206120012'

    Turtle is a human-readable linked data format.

    curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s1070363206120012'

    RDF/XML is a standard XML format for linked data.

    curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s1070363206120012'


     

    This table displays all metadata directly associated to this object as RDF triples.

    116 TRIPLES      22 PREDICATES      46 URIs      37 LITERALS      6 BLANK NODES

    Subject Predicate Object
    1 sg:pub.10.1134/s1070363206120012 schema:about anzsrc-for:03
    2 anzsrc-for:0306
    3 schema:author N8f37f9a7a1a24a818f96308fc8ffb567
    4 schema:citation sg:pub.10.1007/bf01168916
    5 schema:datePublished 2006-12
    6 schema:datePublishedReg 2006-12-01
    7 schema:description Reaction of tetrafluorosilane with tris(2-hydroxyethyl)-and tris(2-trimethylsiloxyethyl)amine results in formation of 1-fluorosilatrane and fluorosilatrane in 75 and 53% yield, respectively. Reaction of tetrafluorosilane with bis(2-trimethylsiloxyethyl)amine and its N-methyl derivative leads to the hitherto unknown 1,1-difluoroquasisilatranes (N → Si) F2Si(OCH2CH2)2NR (R = H, Me) containing donor-acceptor bond N → Si and pentacoordinate silicon atom. The structure of the synthesized compounds was proved by 1H, 13C, 15N, 19F, 29Si NMR and IR spectroscopy.
    8 schema:genre article
    9 schema:inLanguage en
    10 schema:isAccessibleForFree false
    11 schema:isPartOf N923905c2d5264dddb159ee9e4c111e72
    12 Nbe851aa092524fb5ad000538caf83a1c
    13 sg:journal.1109093
    14 schema:keywords IR spectroscopy
    15 NMR
    16 Reaction of tetrafluorosilane
    17 Si
    18 atoms
    19 bond N
    20 compounds
    21 derivatives
    22 donor-acceptor bond N
    23 fluorosilatrane
    24 formation
    25 methyl derivatives
    26 reaction
    27 results
    28 silicon atoms
    29 spectroscopy
    30 structure
    31 tetrafluorosilane
    32 yield
    33 schema:name Reaction of tetrafluorosilane with tris(2-hydroxyethyl)amine, tris(2-trimethylsiloxyethyl)amine and bis(2-trimethylsiloxyethyl)amine and its N-methyl derivative. 1,1-difluoroquasisilatranes
    34 schema:pagination 1851-1853
    35 schema:productId N4cd0168261cb4b27ba3f913f64fdde41
    36 N6a72e140d3e44aefb9fdbc6a80ed8808
    37 schema:sameAs https://app.dimensions.ai/details/publication/pub.1029333622
    38 https://doi.org/10.1134/s1070363206120012
    39 schema:sdDatePublished 2022-01-01T18:16
    40 schema:sdLicense https://scigraph.springernature.com/explorer/license/
    41 schema:sdPublisher Nb4213389908348f9811953320e5607d3
    42 schema:url https://doi.org/10.1134/s1070363206120012
    43 sgo:license sg:explorer/license/
    44 sgo:sdDataset articles
    45 rdf:type schema:ScholarlyArticle
    46 N10d4fbd8b8df485e9c2816af82645ab8 rdf:first sg:person.0754654523.04
    47 rdf:rest N694f5eb276254fab9b89575c2e3f3d4a
    48 N4cd0168261cb4b27ba3f913f64fdde41 schema:name dimensions_id
    49 schema:value pub.1029333622
    50 rdf:type schema:PropertyValue
    51 N694f5eb276254fab9b89575c2e3f3d4a rdf:first sg:person.012621274514.60
    52 rdf:rest Nd0f19533c79545299f402c0266dc2265
    53 N6a72e140d3e44aefb9fdbc6a80ed8808 schema:name doi
    54 schema:value 10.1134/s1070363206120012
    55 rdf:type schema:PropertyValue
    56 N8f37f9a7a1a24a818f96308fc8ffb567 rdf:first sg:person.016410733065.70
    57 rdf:rest Nc2f8c742fbb34d6cab4dcecf904a0e2c
    58 N923905c2d5264dddb159ee9e4c111e72 schema:issueNumber 12
    59 rdf:type schema:PublicationIssue
    60 Nb4213389908348f9811953320e5607d3 schema:name Springer Nature - SN SciGraph project
    61 rdf:type schema:Organization
    62 Nbe851aa092524fb5ad000538caf83a1c schema:volumeNumber 76
    63 rdf:type schema:PublicationVolume
    64 Nc2f8c742fbb34d6cab4dcecf904a0e2c rdf:first sg:person.010114234171.52
    65 rdf:rest Nf8d9473b2f054250bec1cc527de66924
    66 Nd0f19533c79545299f402c0266dc2265 rdf:first sg:person.0640426123.25
    67 rdf:rest rdf:nil
    68 Nf8d9473b2f054250bec1cc527de66924 rdf:first sg:person.010446355057.52
    69 rdf:rest N10d4fbd8b8df485e9c2816af82645ab8
    70 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
    71 schema:name Chemical Sciences
    72 rdf:type schema:DefinedTerm
    73 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
    74 schema:name Physical Chemistry (incl. Structural)
    75 rdf:type schema:DefinedTerm
    76 sg:journal.1109093 schema:issn 1070-3632
    77 1608-3350
    78 schema:name Russian Journal of General Chemistry
    79 schema:publisher Pleiades Publishing
    80 rdf:type schema:Periodical
    81 sg:person.010114234171.52 schema:affiliation grid-institutes:grid.415877.8
    82 schema:familyName Grebneva
    83 schema:givenName E. A.
    84 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010114234171.52
    85 rdf:type schema:Person
    86 sg:person.010446355057.52 schema:affiliation grid-institutes:grid.415877.8
    87 schema:familyName Trofimova
    88 schema:givenName O. M.
    89 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010446355057.52
    90 rdf:type schema:Person
    91 sg:person.012621274514.60 schema:affiliation grid-institutes:grid.415877.8
    92 schema:familyName Chernov
    93 schema:givenName N. F.
    94 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012621274514.60
    95 rdf:type schema:Person
    96 sg:person.016410733065.70 schema:affiliation grid-institutes:grid.415877.8
    97 schema:familyName Voronkov
    98 schema:givenName M. G.
    99 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016410733065.70
    100 rdf:type schema:Person
    101 sg:person.0640426123.25 schema:affiliation grid-institutes:grid.415877.8
    102 schema:familyName Chipanina
    103 schema:givenName N. N.
    104 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0640426123.25
    105 rdf:type schema:Person
    106 sg:person.0754654523.04 schema:affiliation grid-institutes:grid.415877.8
    107 schema:familyName Albanov
    108 schema:givenName A. I.
    109 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0754654523.04
    110 rdf:type schema:Person
    111 sg:pub.10.1007/bf01168916 schema:sameAs https://app.dimensions.ai/details/publication/pub.1028143939
    112 https://doi.org/10.1007/bf01168916
    113 rdf:type schema:CreativeWork
    114 grid-institutes:grid.415877.8 schema:alternateName Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia
    115 schema:name Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, 664033, Irkutsk, Russia
    116 rdf:type schema:Organization
     




    Preview window. Press ESC to close (or click here)


    ...