Structure and intramolecular hydrogen bonds in Bis(trifluoromethylsulfonylamino)methane and N-[(trifluoromethylsulfonyl)aminomethyl]acetamide View Full Text


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Article Info

DATE

2006-04

AUTHORS

I. V. Sterkhova, V. I. Mescheryakov, N. N. Chipanina, V. A. Kuhareva, T. N. Aksamentova, V. K. Turchaninov, B. A. Shainyan

ABSTRACT

Bis(trifluoromethylsulfonylamino)methane in an inert medium exists as an equilibrium mixture of monomeric forms with various types of intramolecular hydrogen bonds, whose population depends on the polarity of the medium. The energetically most favorable form is a symmetrical form containing two N-H...O=S bonds. Less stable are the isomer with two N-H...F-C bonds and the unsymmetrical isomer with two different hydrogen bonds. N-[(Trifluoromethylsulfonyl)aminomethyl]acetamide contains one intramolecular intramolecular N-H...O=C hydrogen bond and preserves ability for self-association. More... »

PAGES

583-589

References to SciGraph publications

  • 2004-10. Self-association of N-methyltrifluoromethanesulfonamide in the gas phase and in inert solvents in RUSSIAN JOURNAL OF GENERAL CHEMISTRY
  • 2005-06. Self-Association of Trifluoromethanesulfonamide in Inert Solvents in RUSSIAN JOURNAL OF GENERAL CHEMISTRY
  • 2004-04. IR Spectra of Trifluoromethanesulfonamide and Its Self-Associates in the Gas Phase in RUSSIAN JOURNAL OF GENERAL CHEMISTRY
  • 2002-12. Improper, blue-shifting hydrogen bond in THEORETICAL CHEMISTRY ACCOUNTS
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1134/s1070363206040165

    DOI

    http://dx.doi.org/10.1134/s1070363206040165

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