Synthesis and Crystal Structure of Cobalt(III) Chelate with Tridentate Azomethine Ligand Containing a Benzimidazole Moiety View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2022-01

AUTHORS

L. D. Popov, S. A. Borodkin, M. A. Kiskin, A. A. Pavlov, P. A. Knyazev, V. V. Chernyavina, I. N. Shcherbakov

ABSTRACT

Azomethine HL was synthesized by the reaction of o-aminophenol with 2-acetylbenzimidazole and used to prepare the cobalt(III) complex [CoL2]2(ClO4)2⋅3H2O (I). The structure of complex I was established by NMR spectroscopy in solution and by single crystal X-ray diffraction (CIF file CCDC no. 2051279). The cobalt ion in the +3 oxidation state has an octahedral environment. The crystals are monoclinic, space group C2/c, a = 12.405(7), b = 13.946(11), c = 18.907(13) Å, α = 109.87(3)°, β = 94.534(12)°, γ = 104.564(19)°, V = 2928(3) Å3, ρ(calcd.) = 1.521 g/cm 3, Z = 2. The complex is diamagnetic. Study of the electrochemical behavior of I in acetonitrile showed that it can be reduced to neutral and radical anion forms. More... »

PAGES

9-15

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070328421110038

DOI

http://dx.doi.org/10.1134/s1070328421110038

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1146220560


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Southern Federal University, Rostov-on-Don, Russia", 
          "id": "http://www.grid.ac/institutes/grid.182798.d", 
          "name": [
            "Southern Federal University, Rostov-on-Don, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Popov", 
        "givenName": "L. D.", 
        "id": "sg:person.0721047070.68", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0721047070.68"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Southern Federal University, Rostov-on-Don, Russia", 
          "id": "http://www.grid.ac/institutes/grid.182798.d", 
          "name": [
            "Southern Federal University, Rostov-on-Don, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Borodkin", 
        "givenName": "S. A.", 
        "id": "sg:person.016572312577.19", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016572312577.19"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.435216.7", 
          "name": [
            "Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kiskin", 
        "givenName": "M. A.", 
        "id": "sg:person.01172445335.81", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01172445335.81"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.431939.5", 
          "name": [
            "Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Pavlov", 
        "givenName": "A. A.", 
        "id": "sg:person.013761504372.04", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013761504372.04"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Research Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russia", 
          "id": "http://www.grid.ac/institutes/grid.182798.d", 
          "name": [
            "Research Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Knyazev", 
        "givenName": "P. A.", 
        "id": "sg:person.01031330316.36", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01031330316.36"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Southern Federal University, Rostov-on-Don, Russia", 
          "id": "http://www.grid.ac/institutes/grid.182798.d", 
          "name": [
            "Southern Federal University, Rostov-on-Don, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Chernyavina", 
        "givenName": "V. V.", 
        "id": "sg:person.014721351061.70", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014721351061.70"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Southern Federal University, Rostov-on-Don, Russia", 
          "id": "http://www.grid.ac/institutes/grid.182798.d", 
          "name": [
            "Southern Federal University, Rostov-on-Don, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Shcherbakov", 
        "givenName": "I. N.", 
        "id": "sg:person.011547725721.73", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011547725721.73"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1134/s1070328415010054", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1042508377", 
          "https://doi.org/10.1134/s1070328415010054"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10593-017-2037-5", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1084025750", 
          "https://doi.org/10.1007/s10593-017-2037-5"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1186/s13065-019-0516-8", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1111753870", 
          "https://doi.org/10.1186/s13065-019-0516-8"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s1070328410020016", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1042575242", 
          "https://doi.org/10.1134/s1070328410020016"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s1070363210120170", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1011479057", 
          "https://doi.org/10.1134/s1070363210120170"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s13233-013-1008-7", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1051641276", 
          "https://doi.org/10.1007/s13233-013-1008-7"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2022-01", 
    "datePublishedReg": "2022-01-01", 
    "description": "Azomethine HL was synthesized by the reaction of o-aminophenol with 2-acetylbenzimidazole and used to prepare the cobalt(III) complex [CoL2]2(ClO4)2\u22c53H2O (I). The structure of complex I was established by NMR spectroscopy in solution and by single crystal X-ray diffraction (CIF file CCDC no.\u00a02051279). The cobalt ion in the +3 oxidation state has an octahedral environment. The crystals are monoclinic, space group C2/c, a = 12.405(7), b = 13.946(11), c = 18.907(13) \u00c5, \u03b1 = 109.87(3)\u00b0, \u03b2 = 94.534(12)\u00b0, \u03b3 = 104.564(19)\u00b0, V = 2928(3) \u00c53, \u03c1(calcd.) = 1.521 g/cm 3, Z = 2. The complex is diamagnetic. Study of the electrochemical behavior of I in acetonitrile showed that it can be reduced to neutral and radical anion forms.", 
    "genre": "article", 
    "id": "sg:pub.10.1134/s1070328421110038", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1294773", 
        "issn": [
          "1070-3284", 
          "1608-3318"
        ], 
        "name": "Russian Journal of Coordination Chemistry", 
        "publisher": "Pleiades Publishing", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "1", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "48"
      }
    ], 
    "keywords": [
      "single-crystal X-ray diffraction", 
      "crystal X-ray diffraction", 
      "space group C2/c", 
      "tridentate azomethine ligands", 
      "radical anion form", 
      "C2/c", 
      "X-ray diffraction", 
      "azomethine ligands", 
      "electrochemical behavior", 
      "NMR spectroscopy", 
      "octahedral environment", 
      "oxidation state", 
      "anion form", 
      "benzimidazole moiety", 
      "o-aminophenol", 
      "cobalt ions", 
      "crystal structure", 
      "chelates", 
      "moiety", 
      "spectroscopy", 
      "\u00c53", 
      "ligands", 
      "complex I", 
      "diffraction", 
      "ions", 
      "synthesis", 
      "structure", 
      "reaction", 
      "complexes", 
      "crystals", 
      "solution", 
      "HL", 
      "behavior", 
      "state", 
      "form", 
      "environment", 
      "study"
    ], 
    "name": "Synthesis and Crystal Structure of Cobalt(III) Chelate with Tridentate Azomethine Ligand Containing a Benzimidazole Moiety", 
    "pagination": "9-15", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1146220560"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s1070328421110038"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s1070328421110038", 
      "https://app.dimensions.ai/details/publication/pub.1146220560"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-09-02T16:08", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20220902/entities/gbq_results/article/article_950.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1134/s1070328421110038"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s1070328421110038'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s1070328421110038'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s1070328421110038'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s1070328421110038'


 

This table displays all metadata directly associated to this object as RDF triples.

168 TRIPLES      21 PREDICATES      68 URIs      54 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s1070328421110038 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N697dd11735a84bd9b18d99fbe1118627
4 schema:citation sg:pub.10.1007/s10593-017-2037-5
5 sg:pub.10.1007/s13233-013-1008-7
6 sg:pub.10.1134/s1070328410020016
7 sg:pub.10.1134/s1070328415010054
8 sg:pub.10.1134/s1070363210120170
9 sg:pub.10.1186/s13065-019-0516-8
10 schema:datePublished 2022-01
11 schema:datePublishedReg 2022-01-01
12 schema:description Azomethine HL was synthesized by the reaction of o-aminophenol with 2-acetylbenzimidazole and used to prepare the cobalt(III) complex [CoL2]2(ClO4)2⋅3H2O (I). The structure of complex I was established by NMR spectroscopy in solution and by single crystal X-ray diffraction (CIF file CCDC no. 2051279). The cobalt ion in the +3 oxidation state has an octahedral environment. The crystals are monoclinic, space group C2/c, a = 12.405(7), b = 13.946(11), c = 18.907(13) Å, α = 109.87(3)°, β = 94.534(12)°, γ = 104.564(19)°, V = 2928(3) Å3, ρ(calcd.) = 1.521 g/cm 3, Z = 2. The complex is diamagnetic. Study of the electrochemical behavior of I in acetonitrile showed that it can be reduced to neutral and radical anion forms.
13 schema:genre article
14 schema:isAccessibleForFree false
15 schema:isPartOf N73c1a5d4eac94569ac324cde51de878d
16 Nca8d5a95a17444bfa63dabbee24caf5f
17 sg:journal.1294773
18 schema:keywords C2/c
19 HL
20 NMR spectroscopy
21 X-ray diffraction
22 anion form
23 azomethine ligands
24 behavior
25 benzimidazole moiety
26 chelates
27 cobalt ions
28 complex I
29 complexes
30 crystal X-ray diffraction
31 crystal structure
32 crystals
33 diffraction
34 electrochemical behavior
35 environment
36 form
37 ions
38 ligands
39 moiety
40 o-aminophenol
41 octahedral environment
42 oxidation state
43 radical anion form
44 reaction
45 single-crystal X-ray diffraction
46 solution
47 space group C2/c
48 spectroscopy
49 state
50 structure
51 study
52 synthesis
53 tridentate azomethine ligands
54 Å3
55 schema:name Synthesis and Crystal Structure of Cobalt(III) Chelate with Tridentate Azomethine Ligand Containing a Benzimidazole Moiety
56 schema:pagination 9-15
57 schema:productId N6117ae68672d400ea2f42deead132e6e
58 Nbdefa1da685c4e209b013f35727217a7
59 schema:sameAs https://app.dimensions.ai/details/publication/pub.1146220560
60 https://doi.org/10.1134/s1070328421110038
61 schema:sdDatePublished 2022-09-02T16:08
62 schema:sdLicense https://scigraph.springernature.com/explorer/license/
63 schema:sdPublisher Nb85593aa11ff4b8780b1ab0adbe78be0
64 schema:url https://doi.org/10.1134/s1070328421110038
65 sgo:license sg:explorer/license/
66 sgo:sdDataset articles
67 rdf:type schema:ScholarlyArticle
68 N43301628f0484030838accd5bdf83201 rdf:first sg:person.011547725721.73
69 rdf:rest rdf:nil
70 N4c4497dcb23b46698b7dc1eadd71d54d rdf:first sg:person.01172445335.81
71 rdf:rest Ncac69326d6f04f69a3de211123e2f95e
72 N4e724cc2507b46939f5623226c5be1d7 rdf:first sg:person.014721351061.70
73 rdf:rest N43301628f0484030838accd5bdf83201
74 N6117ae68672d400ea2f42deead132e6e schema:name doi
75 schema:value 10.1134/s1070328421110038
76 rdf:type schema:PropertyValue
77 N697dd11735a84bd9b18d99fbe1118627 rdf:first sg:person.0721047070.68
78 rdf:rest Nb12a7817b0c64cbbb67a20dbc6ab88c0
79 N73c1a5d4eac94569ac324cde51de878d schema:issueNumber 1
80 rdf:type schema:PublicationIssue
81 N9deb6d18c6b84bcd96156575130eccbf rdf:first sg:person.01031330316.36
82 rdf:rest N4e724cc2507b46939f5623226c5be1d7
83 Nb12a7817b0c64cbbb67a20dbc6ab88c0 rdf:first sg:person.016572312577.19
84 rdf:rest N4c4497dcb23b46698b7dc1eadd71d54d
85 Nb85593aa11ff4b8780b1ab0adbe78be0 schema:name Springer Nature - SN SciGraph project
86 rdf:type schema:Organization
87 Nbdefa1da685c4e209b013f35727217a7 schema:name dimensions_id
88 schema:value pub.1146220560
89 rdf:type schema:PropertyValue
90 Nca8d5a95a17444bfa63dabbee24caf5f schema:volumeNumber 48
91 rdf:type schema:PublicationVolume
92 Ncac69326d6f04f69a3de211123e2f95e rdf:first sg:person.013761504372.04
93 rdf:rest N9deb6d18c6b84bcd96156575130eccbf
94 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
95 schema:name Chemical Sciences
96 rdf:type schema:DefinedTerm
97 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
98 schema:name Physical Chemistry (incl. Structural)
99 rdf:type schema:DefinedTerm
100 sg:journal.1294773 schema:issn 1070-3284
101 1608-3318
102 schema:name Russian Journal of Coordination Chemistry
103 schema:publisher Pleiades Publishing
104 rdf:type schema:Periodical
105 sg:person.01031330316.36 schema:affiliation grid-institutes:grid.182798.d
106 schema:familyName Knyazev
107 schema:givenName P. A.
108 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01031330316.36
109 rdf:type schema:Person
110 sg:person.011547725721.73 schema:affiliation grid-institutes:grid.182798.d
111 schema:familyName Shcherbakov
112 schema:givenName I. N.
113 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011547725721.73
114 rdf:type schema:Person
115 sg:person.01172445335.81 schema:affiliation grid-institutes:grid.435216.7
116 schema:familyName Kiskin
117 schema:givenName M. A.
118 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01172445335.81
119 rdf:type schema:Person
120 sg:person.013761504372.04 schema:affiliation grid-institutes:grid.431939.5
121 schema:familyName Pavlov
122 schema:givenName A. A.
123 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013761504372.04
124 rdf:type schema:Person
125 sg:person.014721351061.70 schema:affiliation grid-institutes:grid.182798.d
126 schema:familyName Chernyavina
127 schema:givenName V. V.
128 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014721351061.70
129 rdf:type schema:Person
130 sg:person.016572312577.19 schema:affiliation grid-institutes:grid.182798.d
131 schema:familyName Borodkin
132 schema:givenName S. A.
133 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016572312577.19
134 rdf:type schema:Person
135 sg:person.0721047070.68 schema:affiliation grid-institutes:grid.182798.d
136 schema:familyName Popov
137 schema:givenName L. D.
138 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0721047070.68
139 rdf:type schema:Person
140 sg:pub.10.1007/s10593-017-2037-5 schema:sameAs https://app.dimensions.ai/details/publication/pub.1084025750
141 https://doi.org/10.1007/s10593-017-2037-5
142 rdf:type schema:CreativeWork
143 sg:pub.10.1007/s13233-013-1008-7 schema:sameAs https://app.dimensions.ai/details/publication/pub.1051641276
144 https://doi.org/10.1007/s13233-013-1008-7
145 rdf:type schema:CreativeWork
146 sg:pub.10.1134/s1070328410020016 schema:sameAs https://app.dimensions.ai/details/publication/pub.1042575242
147 https://doi.org/10.1134/s1070328410020016
148 rdf:type schema:CreativeWork
149 sg:pub.10.1134/s1070328415010054 schema:sameAs https://app.dimensions.ai/details/publication/pub.1042508377
150 https://doi.org/10.1134/s1070328415010054
151 rdf:type schema:CreativeWork
152 sg:pub.10.1134/s1070363210120170 schema:sameAs https://app.dimensions.ai/details/publication/pub.1011479057
153 https://doi.org/10.1134/s1070363210120170
154 rdf:type schema:CreativeWork
155 sg:pub.10.1186/s13065-019-0516-8 schema:sameAs https://app.dimensions.ai/details/publication/pub.1111753870
156 https://doi.org/10.1186/s13065-019-0516-8
157 rdf:type schema:CreativeWork
158 grid-institutes:grid.182798.d schema:alternateName Research Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russia
159 Southern Federal University, Rostov-on-Don, Russia
160 schema:name Research Institute of Physical and Organic Chemistry, Southern Federal University, Rostov-on-Don, Russia
161 Southern Federal University, Rostov-on-Don, Russia
162 rdf:type schema:Organization
163 grid-institutes:grid.431939.5 schema:alternateName Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia
164 schema:name Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia
165 rdf:type schema:Organization
166 grid-institutes:grid.435216.7 schema:alternateName Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
167 schema:name Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
168 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...