Cyclometallated Ni(II) and Pd(II) Complexes of the Azomethine Compounds: Synthesis and Structures View Full Text


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Article Info

DATE

2019-11-01

AUTHORS

A. S. Burlov, S. A. Mashchenko, V. G. Vlasenko, M. A. Kiskin, S. A. Nikolaevskii, E. V. Korshunova

ABSTRACT

New Ni(II) and Pd(II) complexes (Ia and Ib) are synthesized on the basis of the azomethine compound 2-[(E)-[4-methyl-2-[(Z)-p-tolylazo]phenyl]iminomethyl]phenol. The structures and properties of the complexes are characterized by IR spectroscopy, 1Н NMR spectroscopy, and X-ray diffraction analysis (СIF files CCDC nos. 1899223 (Ia) and 1899224 (Ib)). The complex formation affords cyclometallated chelates. According to the X-ray diffraction data, the crystals of the Ni(II) and Pd(II) complexes are isostructural with the square geometry of the coordination mode (MCN2O, M = Ni, Pd) and formation of two five-membered and one six-membered metallocycles. More... »

PAGES

782-787

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070328419110010

DOI

http://dx.doi.org/10.1134/s1070328419110010

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1122264249


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