Refinement of the Molecular Structure of Ammonium Pentachloroaquaferrate (NH4)2[FeCl5(H2O)] View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2019-07-09

AUTHORS

O. V. Koval’chukova, S. B. Strashnova, A. N. Utenyshev, P. V. Strashnov

ABSTRACT

The crystal structure of ammonium pentachloroaquaferrate (NH4)2[FeCl5(H2O)] is refined (CIF file CCDC no. 1831198). Compounds (А)х[FeCl5(H2O)], where A is an organic or inorganic anion (х = 1, 2), crystallize in the orthorhombic crystal system. The geometry and structural parameters of the [FeCl5(H2O)]2– anion are nearly independent of the counterion nature.

PAGES

512-516

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070328419060022

DOI

http://dx.doi.org/10.1134/s1070328419060022

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1117873623


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Kosygin State University, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/None", 
          "name": [
            "Peoples Friendship University, Moscow, Russia", 
            "Kosygin State University, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Koval\u2019chukova", 
        "givenName": "O. V.", 
        "id": "sg:person.014700054222.28", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014700054222.28"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Peoples Friendship University, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.77642.30", 
          "name": [
            "Peoples Friendship University, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Strashnova", 
        "givenName": "S. B.", 
        "id": "sg:person.01002057636.97", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01002057636.97"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Sechenov State Medical University, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.448878.f", 
          "name": [
            "Sechenov State Medical University, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Utenyshev", 
        "givenName": "A. N.", 
        "id": "sg:person.015236213545.72", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015236213545.72"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.431939.5", 
          "name": [
            "Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Strashnov", 
        "givenName": "P. V.", 
        "id": "sg:person.012361304602.57", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012361304602.57"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1038/nature02018", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1050186763", 
          "https://doi.org/10.1038/nature02018"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nmat1804", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1028942997", 
          "https://doi.org/10.1038/nmat1804"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/978-3-642-70733-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1001407131", 
          "https://doi.org/10.1007/978-3-642-70733-9"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1038/nmat2125", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041639818", 
          "https://doi.org/10.1038/nmat2125"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2019-07-09", 
    "datePublishedReg": "2019-07-09", 
    "description": "The crystal structure of ammonium pentachloroaquaferrate (NH4)2[FeCl5(H2O)] is refined (CIF file CCDC no. 1831198). Compounds (\u0410)\u0445[FeCl5(H2O)], where A is an organic or inorganic anion (\u0445 = 1, 2), crystallize in the orthorhombic crystal system. The geometry and structural parameters of the [FeCl5(H2O)]2\u2013 anion are nearly independent of the counterion nature.", 
    "genre": "article", 
    "id": "sg:pub.10.1134/s1070328419060022", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1294773", 
        "issn": [
          "1070-3284", 
          "1608-3318"
        ], 
        "name": "Russian Journal of Coordination Chemistry", 
        "publisher": "Pleiades Publishing", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "7", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "45"
      }
    ], 
    "keywords": [
      "orthorhombic crystal system", 
      "inorganic anions", 
      "molecular structure", 
      "counterion nature", 
      "crystal system", 
      "crystal structure", 
      "anions", 
      "structural parameters", 
      "compounds", 
      "structure", 
      "geometry", 
      "nature", 
      "refinement", 
      "parameters", 
      "system"
    ], 
    "name": "Refinement of the Molecular Structure of Ammonium Pentachloroaquaferrate (NH4)2[FeCl5(H2O)]", 
    "pagination": "512-516", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1117873623"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s1070328419060022"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s1070328419060022", 
      "https://app.dimensions.ai/details/publication/pub.1117873623"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-10-01T06:45", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20221001/entities/gbq_results/article/article_817.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1134/s1070328419060022"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s1070328419060022'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s1070328419060022'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s1070328419060022'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s1070328419060022'


 

This table displays all metadata directly associated to this object as RDF triples.

119 TRIPLES      21 PREDICATES      43 URIs      31 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s1070328419060022 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N7c6c3956d6c74862af554605aa46f54e
4 schema:citation sg:pub.10.1007/978-3-642-70733-9
5 sg:pub.10.1038/nature02018
6 sg:pub.10.1038/nmat1804
7 sg:pub.10.1038/nmat2125
8 schema:datePublished 2019-07-09
9 schema:datePublishedReg 2019-07-09
10 schema:description The crystal structure of ammonium pentachloroaquaferrate (NH4)2[FeCl5(H2O)] is refined (CIF file CCDC no. 1831198). Compounds (А)х[FeCl5(H2O)], where A is an organic or inorganic anion (х = 1, 2), crystallize in the orthorhombic crystal system. The geometry and structural parameters of the [FeCl5(H2O)]2– anion are nearly independent of the counterion nature.
11 schema:genre article
12 schema:isAccessibleForFree false
13 schema:isPartOf N158d0687dd8b48f094765a3ec30810c4
14 N8bb1a69e9930455594f5591c98850e10
15 sg:journal.1294773
16 schema:keywords anions
17 compounds
18 counterion nature
19 crystal structure
20 crystal system
21 geometry
22 inorganic anions
23 molecular structure
24 nature
25 orthorhombic crystal system
26 parameters
27 refinement
28 structural parameters
29 structure
30 system
31 schema:name Refinement of the Molecular Structure of Ammonium Pentachloroaquaferrate (NH4)2[FeCl5(H2O)]
32 schema:pagination 512-516
33 schema:productId Nf19c4c2433a347e9b6638547f233ba1a
34 Nf42df765686d4885a93e025b3620477b
35 schema:sameAs https://app.dimensions.ai/details/publication/pub.1117873623
36 https://doi.org/10.1134/s1070328419060022
37 schema:sdDatePublished 2022-10-01T06:45
38 schema:sdLicense https://scigraph.springernature.com/explorer/license/
39 schema:sdPublisher N8142d12ad7e942fea690d2b06ee1baa6
40 schema:url https://doi.org/10.1134/s1070328419060022
41 sgo:license sg:explorer/license/
42 sgo:sdDataset articles
43 rdf:type schema:ScholarlyArticle
44 N158d0687dd8b48f094765a3ec30810c4 schema:issueNumber 7
45 rdf:type schema:PublicationIssue
46 N4cff0af5b9df4304abadfbb1d48f7de4 rdf:first sg:person.015236213545.72
47 rdf:rest Ne211e92239ff4f209692f543d92ed4b5
48 N5e9572f608f740feaef514d7d28b5146 rdf:first sg:person.01002057636.97
49 rdf:rest N4cff0af5b9df4304abadfbb1d48f7de4
50 N7c6c3956d6c74862af554605aa46f54e rdf:first sg:person.014700054222.28
51 rdf:rest N5e9572f608f740feaef514d7d28b5146
52 N8142d12ad7e942fea690d2b06ee1baa6 schema:name Springer Nature - SN SciGraph project
53 rdf:type schema:Organization
54 N8bb1a69e9930455594f5591c98850e10 schema:volumeNumber 45
55 rdf:type schema:PublicationVolume
56 Ne211e92239ff4f209692f543d92ed4b5 rdf:first sg:person.012361304602.57
57 rdf:rest rdf:nil
58 Nf19c4c2433a347e9b6638547f233ba1a schema:name doi
59 schema:value 10.1134/s1070328419060022
60 rdf:type schema:PropertyValue
61 Nf42df765686d4885a93e025b3620477b schema:name dimensions_id
62 schema:value pub.1117873623
63 rdf:type schema:PropertyValue
64 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
65 schema:name Chemical Sciences
66 rdf:type schema:DefinedTerm
67 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
68 schema:name Physical Chemistry (incl. Structural)
69 rdf:type schema:DefinedTerm
70 sg:journal.1294773 schema:issn 1070-3284
71 1608-3318
72 schema:name Russian Journal of Coordination Chemistry
73 schema:publisher Pleiades Publishing
74 rdf:type schema:Periodical
75 sg:person.01002057636.97 schema:affiliation grid-institutes:grid.77642.30
76 schema:familyName Strashnova
77 schema:givenName S. B.
78 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01002057636.97
79 rdf:type schema:Person
80 sg:person.012361304602.57 schema:affiliation grid-institutes:grid.431939.5
81 schema:familyName Strashnov
82 schema:givenName P. V.
83 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012361304602.57
84 rdf:type schema:Person
85 sg:person.014700054222.28 schema:affiliation grid-institutes:None
86 schema:familyName Koval’chukova
87 schema:givenName O. V.
88 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014700054222.28
89 rdf:type schema:Person
90 sg:person.015236213545.72 schema:affiliation grid-institutes:grid.448878.f
91 schema:familyName Utenyshev
92 schema:givenName A. N.
93 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015236213545.72
94 rdf:type schema:Person
95 sg:pub.10.1007/978-3-642-70733-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1001407131
96 https://doi.org/10.1007/978-3-642-70733-9
97 rdf:type schema:CreativeWork
98 sg:pub.10.1038/nature02018 schema:sameAs https://app.dimensions.ai/details/publication/pub.1050186763
99 https://doi.org/10.1038/nature02018
100 rdf:type schema:CreativeWork
101 sg:pub.10.1038/nmat1804 schema:sameAs https://app.dimensions.ai/details/publication/pub.1028942997
102 https://doi.org/10.1038/nmat1804
103 rdf:type schema:CreativeWork
104 sg:pub.10.1038/nmat2125 schema:sameAs https://app.dimensions.ai/details/publication/pub.1041639818
105 https://doi.org/10.1038/nmat2125
106 rdf:type schema:CreativeWork
107 grid-institutes:None schema:alternateName Kosygin State University, Moscow, Russia
108 schema:name Kosygin State University, Moscow, Russia
109 Peoples Friendship University, Moscow, Russia
110 rdf:type schema:Organization
111 grid-institutes:grid.431939.5 schema:alternateName Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia
112 schema:name Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119991, Moscow, Russia
113 rdf:type schema:Organization
114 grid-institutes:grid.448878.f schema:alternateName Sechenov State Medical University, Moscow, Russia
115 schema:name Sechenov State Medical University, Moscow, Russia
116 rdf:type schema:Organization
117 grid-institutes:grid.77642.30 schema:alternateName Peoples Friendship University, Moscow, Russia
118 schema:name Peoples Friendship University, Moscow, Russia
119 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...