Coordination Compounds of Cobalt(II), Nickel(II), and Copper(II) Halides with 2-Methyl-1,2,4-Triazolo[1,5-a]benzimidazole View Full Text


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Article Info

DATE

2018-12

AUTHORS

I. I. Dyukova, T. A. Kuz’menko, V. Yu. Komarov, T. S. Sukhikh, E. V. Vorontsova, L. G. Lavrenova

ABSTRACT

New coordination compounds of Co(II), Ni(II), and Cu(II) halides with 2-methyl-1,2,4-triazolo[1,5-a]benzimidazole (L), [Co(L)2Cl2] (Ia), [Ni(L)2(H2O)4]Cl2 · 4H2O (II), and [Сu2(L)4(µ-Br)2Br2] (IIIa), are synthesized. The complexes are studied by X-ray structure analysis (СIF files CCDC nos. 1825006–1825008), electronic (diffuse reflectance) spectroscopy, and IR spectroscopy. In compounds Ia, II, and IIIa, ligand L is coordinated to the metal by the N4 atom of the triazole fragment. The study of the cytotoxic effect of the ligand and synthesized complexes on the Hep-2 line (laryngeal cancer cells) shows a considerably higher activity of the copper(II) complex than that of the ligand. More... »

PAGES

755-764

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s107032841812014x

DOI

http://dx.doi.org/10.1134/s107032841812014x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1111502303


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