Unusual Bridging Coordination Modes of THF and Piv Anions in the Hexanuclear Nickel(II) Carboxylate Complex View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2018-10

AUTHORS

N. V. Gogoleva, G. G. Aleksandrov, M. A. Kiskin, A. A. Sidorov, I. L. Eremenko

ABSTRACT

The recrystallization of complex [Ni9(OH)6(Piv)12(HPiv)4] (Piv– is anion of trimethylacetic acid) from a THF–MeCN (6 : 1) mixture gives a new hexanuclear compound of nickel(II): [Ni6(µ3-OH)2(Piv)10(THF)4]. Its structure (CIF file CCDC no. 1579976) exhibits rare examples of coordination of the µ2-THF and µ4-Piv ligands.

PAGES

585-588

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070328418100044

DOI

http://dx.doi.org/10.1134/s1070328418100044

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1107428777


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