Electrochemical Synthesis, Properties, and Structure of 1,10-Phenanthroline Adducts of Mononuclear Copper, Cobalt, and Nickel Chelates in the N,N,O-Ligand Environment View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2018-10

AUTHORS

D. A. Garnovskii, V. G. Vlasenko, G. G. Aleksandrov, S. I. Levchenkov, N. I. Makarova, Yu. V. Koshchienko, A. I. Uraev, A. S. Burlov

ABSTRACT

1,10-Phenanthroline (Phen) adducts [M(L)Phen] in copper(II), cobalt(II), and zinc(II) chelates based on N,N,O-tridentate tosylamino-functionalized pyrazole-containing Schiff base (H2L), resulting from condensation of 2-tosylaminoaniline with 3-methyl-1-phenyl-4-formylpyrazol-5-ol, were obtained by electrosynthesis. The composition and structure of the mixed-ligand complexes were confirmed by elemental analysis, IR spectroscopy, and magnetochemical measurements. The structures of azomethine H2L and mixed-ligand copper(II) complex were determined by X-ray diffraction. More... »

PAGES

596-603

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070328418100032

DOI

http://dx.doi.org/10.1134/s1070328418100032

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1107430824


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