Tantalum Dimethyldithiocarbamate Complexes View Full Text


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Article Info

DATE

2017-10

AUTHORS

P. A. Petrov, A. V. Rogachev, N. B. Kompan’kov, A. L. Gushchin, M. N. Sokolov

ABSTRACT

The reaction of Ta(NMe2)5 with CS2 gave the tantalum(V) dimethyldithiocarbamate complex [Ta(MeDtc)4](MeDtc) (I). An ionic structure of the complex with a dodecahedral coordination of the tantalum atom was determined for toluene (I · Tol) and THF (I · THF) solvates by X-ray diffraction (CCDC no. 1544283 and no. 1544284, respectively). The reaction of I with CH2Cl2 leads to exchange of the outersphere anion to give the known complex [Ta(MeDtc)4]Cl (II). The cyclic voltammogram of II in CH3CN exhibits a quasi-reversible transition at E1/2 =–0.735 V corresponding to the TaV/TaIV pair. More... »

PAGES

652-656

References to SciGraph publications

  • 1972-03. Some aspects of the stereochemistry of eight-coordinate complexes in JOURNAL OF STRUCTURAL CHEMISTRY
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1134/s1070328417100074

    DOI

    http://dx.doi.org/10.1134/s1070328417100074

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