Zinc(II) and cadmium(II) N,N'-Bis(2-N-Tosylaminobenzylidene) diaminodipropyliminates: Syntheses, structures, and photoluminescence properties View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2016-11

AUTHORS

T. P. Lysakova, A. S. Burlov, V. G. Vlasenko, Yu. V. Koshchienko, G. G. Aleksandrov, S. I. Levchenkov, Ya. V. Zubavichus, A. S. Cheprasov, D. A. Garnovskii, A. V. Metelitsa

ABSTRACT

Chemical and electrochemical syntheses of the zinc(II) and cadmium(II) complexes with the tetradentate Schiff base (H2L), the condensation product of 2-N-tosylaminobenzaldehyde with diaminodipropylamine, are carried out. The structures, compositions, and properties of the synthesized metal complexes are studied by elemental analyses, IR spectroscopy, 1H NMR, UV spectroscopy, X-ray absorption spectroscopy, and quantum-chemical calculations. The structure of the cadmium(II) complex is determined by X-ray diffraction analysis (CIF file CCDC no. 1446393). The cadmium(II) and zinc(II) complexes exhibit luminescence in a CH2Cl2 solution in the blue spectral range (λPL = 425–428 nm) with the photoluminescence quantum yields ϕ = 0.20 and 0.75, respectively. More... »

PAGES

701-710

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070328416110075

DOI

http://dx.doi.org/10.1134/s1070328416110075

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1018701015


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