Binuclear bismuth halide complexes (N-Me(2,2'-BipyH))2[Bi2X10] (X = Cl, Br): Syntheses, crystal structures, and optical properties View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2016-11

AUTHORS

S. A. Adonin, I. D. Gorokh, D. G. Samsonenko, I. V. Yushina, M. N. Sokolov, V. P. Fedin

ABSTRACT

Binuclear halide complexes (N-Me(2,2'-BipyH)2[Bi2X10] (X = Cl (I), Br (II); 2,2'-Bipy = 2,2'-bipyridine) are synthesized by the reaction of solutions of [BiX6]3– and (N-Me(2,2'-BipyH)(NO3)2 in 2 M HX. The structure of [Bi2X10]4– anions consists of octahedral fragments {BiX6} linked by two μ2-bridging halide ligands. The structures of the compounds are determined by X-ray diffraction analysis (CIF files CCDC 1455987 (I) and 1455988 (II)). The forbidden gap width Eg is determined for complex II from the diffuse reflectance spectrum. More... »

PAGES

695-700

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070328416110014

DOI

http://dx.doi.org/10.1134/s1070328416110014

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1023572705


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