Mononuclear pivalates of metals of the first transition series View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2016-09-16

AUTHORS

V. I. Ovcharenko, E. Yu. Fursova, G. V. Romanenko

ABSTRACT

The synthesis and structures of mononuclear Ni(II), Co(II), Mn(II), and Cu(II) pivalates isolated as complex salts NBu4[M(Piv)3] ((NBu4)+ is tetrabutylammonium cation, Piv– is pivalate anion) and polynuclear complexes [Ni6(L)2(HL)2(Piv)6(HPiv)8], (NBu4)2[Co4(Piv)8(AcO)2(H2O)4], NBu4[Co2(Piv)5(H2O)2], and (NBu4)2[Cu4(Piv)8(AcO)2(H2O)2] (L2–, HL–, and AcO– is lactic acid dianion, lactic acid monoanion, and acetate anion, respectively) are discussed. The formation of the compounds is detected during the development of the synthesis of NBu4[M(Piv)3]. More... »

PAGES

584-590

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070328416090049

DOI

http://dx.doi.org/10.1134/s1070328416090049

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1006086119


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Inorganic Chemistry", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "International Tomography Center, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia", 
          "id": "http://www.grid.ac/institutes/grid.415877.8", 
          "name": [
            "International Tomography Center, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ovcharenko", 
        "givenName": "V. I.", 
        "id": "sg:person.0732145436.56", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0732145436.56"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "International Tomography Center, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia", 
          "id": "http://www.grid.ac/institutes/grid.415877.8", 
          "name": [
            "International Tomography Center, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Fursova", 
        "givenName": "E. Yu.", 
        "id": "sg:person.07501453217.49", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07501453217.49"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "International Tomography Center, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia", 
          "id": "http://www.grid.ac/institutes/grid.415877.8", 
          "name": [
            "International Tomography Center, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Romanenko", 
        "givenName": "G. V.", 
        "id": "sg:person.0664032236.40", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0664032236.40"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1023/a:1006988916647", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1021602636", 
          "https://doi.org/10.1023/a:1006988916647"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s0036023606070084", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1047285513", 
          "https://doi.org/10.1134/s0036023606070084"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s1070328415010054", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1042508377", 
          "https://doi.org/10.1134/s1070328415010054"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s11172-009-0002-x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1044625649", 
          "https://doi.org/10.1007/s11172-009-0002-x"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2016-09-16", 
    "datePublishedReg": "2016-09-16", 
    "description": "The synthesis and structures of mononuclear Ni(II), Co(II), Mn(II), and Cu(II) pivalates isolated as complex salts NBu4[M(Piv)3] ((NBu4)+ is tetrabutylammonium cation, Piv\u2013 is pivalate anion) and polynuclear complexes [Ni6(L)2(HL)2(Piv)6(HPiv)8], (NBu4)2[Co4(Piv)8(AcO)2(H2O)4], NBu4[Co2(Piv)5(H2O)2], and (NBu4)2[Cu4(Piv)8(AcO)2(H2O)2] (L2\u2013, HL\u2013, and AcO\u2013 is lactic acid dianion, lactic acid monoanion, and acetate anion, respectively) are discussed. The formation of the compounds is detected during the development of the synthesis of NBu4[M(Piv)3].", 
    "genre": "article", 
    "id": "sg:pub.10.1134/s1070328416090049", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1294773", 
        "issn": [
          "1070-3284", 
          "0132-344X"
        ], 
        "name": "Russian Journal of Coordination Chemistry", 
        "publisher": "Pleiades Publishing", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "9", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "42"
      }
    ], 
    "keywords": [
      "structures of mononuclear", 
      "first transition series", 
      "complex salts", 
      "transition series", 
      "synthesis", 
      "pivalate", 
      "mononuclear", 
      "salt", 
      "compounds", 
      "metals", 
      "complexes", 
      "formation", 
      "structure", 
      "series", 
      "development", 
      "Mononuclear pivalates"
    ], 
    "name": "Mononuclear pivalates of metals of the first transition series", 
    "pagination": "584-590", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1006086119"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s1070328416090049"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s1070328416090049", 
      "https://app.dimensions.ai/details/publication/pub.1006086119"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2021-11-01T18:28", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20211101/entities/gbq_results/article/article_708.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1134/s1070328416090049"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s1070328416090049'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s1070328416090049'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s1070328416090049'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s1070328416090049'


 

This table displays all metadata directly associated to this object as RDF triples.

104 TRIPLES      22 PREDICATES      45 URIs      33 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s1070328416090049 schema:about anzsrc-for:03
2 anzsrc-for:0302
3 schema:author N3cadd4bad1c2458a9346f55e176368ec
4 schema:citation sg:pub.10.1007/s11172-009-0002-x
5 sg:pub.10.1023/a:1006988916647
6 sg:pub.10.1134/s0036023606070084
7 sg:pub.10.1134/s1070328415010054
8 schema:datePublished 2016-09-16
9 schema:datePublishedReg 2016-09-16
10 schema:description The synthesis and structures of mononuclear Ni(II), Co(II), Mn(II), and Cu(II) pivalates isolated as complex salts NBu4[M(Piv)3] ((NBu4)+ is tetrabutylammonium cation, Piv– is pivalate anion) and polynuclear complexes [Ni6(L)2(HL)2(Piv)6(HPiv)8], (NBu4)2[Co4(Piv)8(AcO)2(H2O)4], NBu4[Co2(Piv)5(H2O)2], and (NBu4)2[Cu4(Piv)8(AcO)2(H2O)2] (L2–, HL–, and AcO– is lactic acid dianion, lactic acid monoanion, and acetate anion, respectively) are discussed. The formation of the compounds is detected during the development of the synthesis of NBu4[M(Piv)3].
11 schema:genre article
12 schema:inLanguage en
13 schema:isAccessibleForFree false
14 schema:isPartOf N5a2d0da738c1486fb204026a188701a8
15 N7c126679078248adb4bca1c443d9aedb
16 sg:journal.1294773
17 schema:keywords Mononuclear pivalates
18 complex salts
19 complexes
20 compounds
21 development
22 first transition series
23 formation
24 metals
25 mononuclear
26 pivalate
27 salt
28 series
29 structure
30 structures of mononuclear
31 synthesis
32 transition series
33 schema:name Mononuclear pivalates of metals of the first transition series
34 schema:pagination 584-590
35 schema:productId N4621c37799314894a6b67cbe86fbb7fe
36 N63abaaa68f2e4d058416873df9886ee4
37 schema:sameAs https://app.dimensions.ai/details/publication/pub.1006086119
38 https://doi.org/10.1134/s1070328416090049
39 schema:sdDatePublished 2021-11-01T18:28
40 schema:sdLicense https://scigraph.springernature.com/explorer/license/
41 schema:sdPublisher N080d71e6a6b440cc840f624f06b14f56
42 schema:url https://doi.org/10.1134/s1070328416090049
43 sgo:license sg:explorer/license/
44 sgo:sdDataset articles
45 rdf:type schema:ScholarlyArticle
46 N080d71e6a6b440cc840f624f06b14f56 schema:name Springer Nature - SN SciGraph project
47 rdf:type schema:Organization
48 N3cadd4bad1c2458a9346f55e176368ec rdf:first sg:person.0732145436.56
49 rdf:rest N45f7ef5189f54454b8e6c6bc1cd1a13f
50 N45f7ef5189f54454b8e6c6bc1cd1a13f rdf:first sg:person.07501453217.49
51 rdf:rest Na934761b82924844b7b521f64d6491a5
52 N4621c37799314894a6b67cbe86fbb7fe schema:name doi
53 schema:value 10.1134/s1070328416090049
54 rdf:type schema:PropertyValue
55 N5a2d0da738c1486fb204026a188701a8 schema:volumeNumber 42
56 rdf:type schema:PublicationVolume
57 N63abaaa68f2e4d058416873df9886ee4 schema:name dimensions_id
58 schema:value pub.1006086119
59 rdf:type schema:PropertyValue
60 N7c126679078248adb4bca1c443d9aedb schema:issueNumber 9
61 rdf:type schema:PublicationIssue
62 Na934761b82924844b7b521f64d6491a5 rdf:first sg:person.0664032236.40
63 rdf:rest rdf:nil
64 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
65 schema:name Chemical Sciences
66 rdf:type schema:DefinedTerm
67 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
68 schema:name Inorganic Chemistry
69 rdf:type schema:DefinedTerm
70 sg:journal.1294773 schema:issn 0132-344X
71 1070-3284
72 schema:name Russian Journal of Coordination Chemistry
73 schema:publisher Pleiades Publishing
74 rdf:type schema:Periodical
75 sg:person.0664032236.40 schema:affiliation grid-institutes:grid.415877.8
76 schema:familyName Romanenko
77 schema:givenName G. V.
78 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0664032236.40
79 rdf:type schema:Person
80 sg:person.0732145436.56 schema:affiliation grid-institutes:grid.415877.8
81 schema:familyName Ovcharenko
82 schema:givenName V. I.
83 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0732145436.56
84 rdf:type schema:Person
85 sg:person.07501453217.49 schema:affiliation grid-institutes:grid.415877.8
86 schema:familyName Fursova
87 schema:givenName E. Yu.
88 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07501453217.49
89 rdf:type schema:Person
90 sg:pub.10.1007/s11172-009-0002-x schema:sameAs https://app.dimensions.ai/details/publication/pub.1044625649
91 https://doi.org/10.1007/s11172-009-0002-x
92 rdf:type schema:CreativeWork
93 sg:pub.10.1023/a:1006988916647 schema:sameAs https://app.dimensions.ai/details/publication/pub.1021602636
94 https://doi.org/10.1023/a:1006988916647
95 rdf:type schema:CreativeWork
96 sg:pub.10.1134/s0036023606070084 schema:sameAs https://app.dimensions.ai/details/publication/pub.1047285513
97 https://doi.org/10.1134/s0036023606070084
98 rdf:type schema:CreativeWork
99 sg:pub.10.1134/s1070328415010054 schema:sameAs https://app.dimensions.ai/details/publication/pub.1042508377
100 https://doi.org/10.1134/s1070328415010054
101 rdf:type schema:CreativeWork
102 grid-institutes:grid.415877.8 schema:alternateName International Tomography Center, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia
103 schema:name International Tomography Center, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia
104 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...