High-spin adducts of redox active 2,4,6,8-tetrakis(tert-butyl)phenoxazin-1-one with tetrahedral cobalt(II) complexes View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2016-08

AUTHORS

E. P. Ivakhnenko, Yu. V. Koshchienko, P. A. Knyazev, K. A. Lysenko, A. S. Bogomyakov, V. I. Minkin

ABSTRACT

The complex formation between redox active 2,4,6,8-tetrakis(tert-butyl)phenoxazin-1-one (L) and four-coordinate Co(II) complexes, resulting in six-coordinate adducts (I) (C77H82N12O5Co) and (II) (C38H41NO6F12Co) was studied. High-spin structure of the formed cobalt adducts I and II (hs-CoII–BQ) was established by X-ray diffraction analysis and magnetochemistry methods. Adducts I and II are stable over a wide temperature range (5–300 K) and are not involved in the redox process giving low-spin adducts (ls-CoIII–SQ) studied previously. More... »

PAGES

509-515

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070328416080017

DOI

http://dx.doi.org/10.1134/s1070328416080017

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1019667146


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