Na4[trans-{Cp*Rh}2Ta6O19] · 24H2O: Synthesis, structure, solution studies View Full Text


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Article Info

DATE

2016-05

AUTHORS

P. A. Abramov, N. B. Kompankov, M. N. Sokolov

ABSTRACT

Reaction of [Cp*RhCl2]2 (Cp* = η5-C5(CH3)5) with Na8[Ta6O19] · 24.5H2O, taken in {Cp*Rh}2+/[Ta6O19]8– 2: 1 molar ratio, in water leads to a new noble-metal-POM complex Na4[trans-{Cp*Rh}2Ta6O19] · 24H2O (I), which was isolated and characterized by XRD (CIF file CCDC no. 1416810), elemental analysis, NMR and IR spectroscopy.

PAGES

311-315

References to SciGraph publications

  • 2011-10. New polyoxotantalate salt Na8[Ta6O19]·24.5H2O and its properties in JOURNAL OF STRUCTURAL CHEMISTRY
  • 2011-10. Cobalt—Sandwiched lindqvist hexaniobate dimer [Co(III)H5(Nb6O19)2]8− 1 in RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
  • Identifiers

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    http://scigraph.springernature.com/pub.10.1134/s1070328416050018

    DOI

    http://dx.doi.org/10.1134/s1070328416050018

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