Binuclear metallochelates of 2-(N-tosylamino)benzal-2’-(hydroxymethyl)aniline: Syntheses, structures, and magnetic properties View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2016-04

AUTHORS

A. S. Burlov, V. G. Vlasenko, Yu. V. Koshchienko, S. I. Levchenkov, I. V. Pankov, Ya. V. Zubavichus, A. L. Trigub, G. S. Borodkin, T. A. Mazepina, D. A. Garnovskii, A. I. Uraev

ABSTRACT

Binuclear complexes of Co(II), Сu(II), and Pd(II) with 2-(N-tosylamino)benzal-2’-(hydroxymethyl)aniline are synthesized. The compositions and structures of the ligand and complexes are determined from the data of elemental analysis, IR spectroscopy, 1Н, 13С, and 15N NMR spectroscopy, X-ray absorption spectroscopy, and magnetochemical measurements in a temperature range of 294–77.4 K. All complexes are dimeric. The Cu…Cu and Cо…Cо distances equal to 3.03 and 2.99 Å, respectively, are obtained for the Cu(II) and Co(II) complexes. These complexes are characterized by the antiferromagnetic exchange interaction with 2J = –630 and –42 cm–1, respectively. More... »

PAGES

267-273

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URI

http://scigraph.springernature.com/pub.10.1134/s1070328416030027

DOI

http://dx.doi.org/10.1134/s1070328416030027

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https://app.dimensions.ai/details/publication/pub.1049052078


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