Polymer chlorobismuthate complex catena-{((Me,Me)Bpe)[BiCl5]}n: Synthesis and crystal structure View Full Text


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Article Info

DATE

2016-01

AUTHORS

S. A. Adonin, D. G. Samsonenko, M. N. Sokolov, V. P. Fedin

ABSTRACT

The reaction of BiCl3 and N,N-dimethyl-1,2-bis(pyridyl)ethane chloride (Me,Me-Bpe) in 2 M HCl affords a polymer chlorobismuthate complex {((Me,Me)Bpe)[BiCl5]}n (I). The structure of complex I is determined by X-ray diffraction analysis (CIF file CCDC 1058842). The anionic moiety of the complex is presented by a 1D coordination polymer ([BiCl5]2n–)n consisting of octahedral blocks {Cl6} linked by µ2- bridging chloride ligands into infinite zigzag chains. More... »

PAGES

27-31

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070328416010012

DOI

http://dx.doi.org/10.1134/s1070328416010012

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1016003144


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