Syntheses and structures of complexes {Mo2S2O2}2+ with labile Cl− and DMF ligands View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2015-11

AUTHORS

D. S. Ogienko, A. I. Smolentsev, D. A. Bashirov, M. Yu. Afonin, P. A. Petrov, S. N. Konchenko

ABSTRACT

Complex (Me4N)2[Mo2S2O2Cl4] ((Me4N)2[II]) is synthesized by passing gaseous HCl through a solution of (Me4N)2[Mo2O2S8] ((Me4N)2[I]). The recrystallization of (Me4N)2[II] from N,N-dimethylformamide (DMF) gives compound (Me4N)[Mo2S2O2Cl3(DMF)3] ((Me4N)[III]). The oxidation of (Et4N)2[I] with iodine in DMF affords the earlier described complex [Mo2S2O2(DMF)6]I2 ([IV]I2). However, this complex was not structurally characterized. The structures of the synthesized compounds are determined by X-ray diffraction analyses (CIF files CCDC nos. 1059924–1059926). Thus, several complexes in which the binuclear fragment {Mo2S2O2}2+ has a labile coordination environment were synthesized and characterized. More... »

PAGES

759-764

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070328415110056

DOI

http://dx.doi.org/10.1134/s1070328415110056

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1037166412


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Inorganic Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Nikolaev Institute of Inorganic Chemistry", 
          "id": "https://www.grid.ac/institutes/grid.425759.8", 
          "name": [
            "Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent\u2019eva 3, 630090, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ogienko", 
        "givenName": "D. S.", 
        "id": "sg:person.014434271561.45", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014434271561.45"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Novosibirsk State University", 
          "id": "https://www.grid.ac/institutes/grid.4605.7", 
          "name": [
            "Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent\u2019eva 3, 630090, Novosibirsk, Russia", 
            "Novosibirsk State University, ul. Pirogova 2, 630090, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Smolentsev", 
        "givenName": "A. I.", 
        "id": "sg:person.0643047035.93", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0643047035.93"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Novosibirsk State University", 
          "id": "https://www.grid.ac/institutes/grid.4605.7", 
          "name": [
            "Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent\u2019eva 3, 630090, Novosibirsk, Russia", 
            "Novosibirsk State University, ul. Pirogova 2, 630090, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Bashirov", 
        "givenName": "D. A.", 
        "id": "sg:person.011154723503.70", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011154723503.70"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Nikolaev Institute of Inorganic Chemistry", 
          "id": "https://www.grid.ac/institutes/grid.425759.8", 
          "name": [
            "Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent\u2019eva 3, 630090, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Afonin", 
        "givenName": "M. Yu.", 
        "id": "sg:person.014015352461.03", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014015352461.03"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Novosibirsk State University", 
          "id": "https://www.grid.ac/institutes/grid.4605.7", 
          "name": [
            "Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent\u2019eva 3, 630090, Novosibirsk, Russia", 
            "Novosibirsk State University, ul. Pirogova 2, 630090, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Petrov", 
        "givenName": "P. A.", 
        "id": "sg:person.0662277505.76", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0662277505.76"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Novosibirsk State University", 
          "id": "https://www.grid.ac/institutes/grid.4605.7", 
          "name": [
            "Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent\u2019eva 3, 630090, Novosibirsk, Russia", 
            "Novosibirsk State University, ul. Pirogova 2, 630090, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Konchenko", 
        "givenName": "S. N.", 
        "id": "sg:person.0720422334.76", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0720422334.76"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1002/anie.198109341", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1005430064"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/s0277-5387(00)84930-x", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1007140025"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1107/s0108768102003890", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1012549006"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s1070328414040095", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1014862006", 
          "https://doi.org/10.1134/s1070328414040095"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1107/s0108270196010116", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1016083907"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/c2cs35145e", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1031629169"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr00091a001", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053840470"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic00020a031", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055538385"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic00292a005", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055550785"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja00014a021", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055699095"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2015-11", 
    "datePublishedReg": "2015-11-01", 
    "description": "Complex (Me4N)2[Mo2S2O2Cl4] ((Me4N)2[II]) is synthesized by passing gaseous HCl through a solution of (Me4N)2[Mo2O2S8] ((Me4N)2[I]). The recrystallization of (Me4N)2[II] from N,N-dimethylformamide (DMF) gives compound (Me4N)[Mo2S2O2Cl3(DMF)3] ((Me4N)[III]). The oxidation of (Et4N)2[I] with iodine in DMF affords the earlier described complex [Mo2S2O2(DMF)6]I2 ([IV]I2). However, this complex was not structurally characterized. The structures of the synthesized compounds are determined by X-ray diffraction analyses (CIF files CCDC nos. 1059924\u20131059926). Thus, several complexes in which the binuclear fragment {Mo2S2O2}2+ has a labile coordination environment were synthesized and characterized.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1134/s1070328415110056", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1294773", 
        "issn": [
          "1070-3284", 
          "1608-3318"
        ], 
        "name": "Russian Journal of Coordination Chemistry", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "11", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "41"
      }
    ], 
    "name": "Syntheses and structures of complexes {Mo2S2O2}2+ with labile Cl\u2212 and DMF ligands", 
    "pagination": "759-764", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "b10c2ff47bb807f1ccb537763f1a0a3d121fb3893848c71c1bdb4972f20841e5"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s1070328415110056"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1037166412"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s1070328415110056", 
      "https://app.dimensions.ai/details/publication/pub.1037166412"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T20:45", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8684_00000506.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1134%2FS1070328415110056"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s1070328415110056'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s1070328415110056'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s1070328415110056'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s1070328415110056'


 

This table displays all metadata directly associated to this object as RDF triples.

131 TRIPLES      21 PREDICATES      37 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s1070328415110056 schema:about anzsrc-for:03
2 anzsrc-for:0302
3 schema:author Ne45b416fcdfe4b32b89051e5f3efc155
4 schema:citation sg:pub.10.1134/s1070328414040095
5 https://doi.org/10.1002/anie.198109341
6 https://doi.org/10.1016/s0277-5387(00)84930-x
7 https://doi.org/10.1021/cr00091a001
8 https://doi.org/10.1021/ic00020a031
9 https://doi.org/10.1021/ic00292a005
10 https://doi.org/10.1021/ja00014a021
11 https://doi.org/10.1039/c2cs35145e
12 https://doi.org/10.1107/s0108270196010116
13 https://doi.org/10.1107/s0108768102003890
14 schema:datePublished 2015-11
15 schema:datePublishedReg 2015-11-01
16 schema:description Complex (Me4N)2[Mo2S2O2Cl4] ((Me4N)2[II]) is synthesized by passing gaseous HCl through a solution of (Me4N)2[Mo2O2S8] ((Me4N)2[I]). The recrystallization of (Me4N)2[II] from N,N-dimethylformamide (DMF) gives compound (Me4N)[Mo2S2O2Cl3(DMF)3] ((Me4N)[III]). The oxidation of (Et4N)2[I] with iodine in DMF affords the earlier described complex [Mo2S2O2(DMF)6]I2 ([IV]I2). However, this complex was not structurally characterized. The structures of the synthesized compounds are determined by X-ray diffraction analyses (CIF files CCDC nos. 1059924–1059926). Thus, several complexes in which the binuclear fragment {Mo2S2O2}2+ has a labile coordination environment were synthesized and characterized.
17 schema:genre research_article
18 schema:inLanguage en
19 schema:isAccessibleForFree false
20 schema:isPartOf Nd258b2806233415abe9f27504c3ac68e
21 Nf98a24cafb234c19a07d90b3ad93b266
22 sg:journal.1294773
23 schema:name Syntheses and structures of complexes {Mo2S2O2}2+ with labile Cl− and DMF ligands
24 schema:pagination 759-764
25 schema:productId N090a1f00fd7d4e0d9d4988ac8d48a2ca
26 N43a4c8c0f9e945febf6ae2c72c0d1d18
27 N8f19a8f2f3e742148b01532176ebf08c
28 schema:sameAs https://app.dimensions.ai/details/publication/pub.1037166412
29 https://doi.org/10.1134/s1070328415110056
30 schema:sdDatePublished 2019-04-10T20:45
31 schema:sdLicense https://scigraph.springernature.com/explorer/license/
32 schema:sdPublisher N79525532c61740cb9cf893afaf5d8a6f
33 schema:url http://link.springer.com/10.1134%2FS1070328415110056
34 sgo:license sg:explorer/license/
35 sgo:sdDataset articles
36 rdf:type schema:ScholarlyArticle
37 N00c4f30c8f754be0b67eb75a078e9997 rdf:first sg:person.0720422334.76
38 rdf:rest rdf:nil
39 N090a1f00fd7d4e0d9d4988ac8d48a2ca schema:name dimensions_id
40 schema:value pub.1037166412
41 rdf:type schema:PropertyValue
42 N1303d26ebbb6479e879a9cde601c8935 rdf:first sg:person.0662277505.76
43 rdf:rest N00c4f30c8f754be0b67eb75a078e9997
44 N43a4c8c0f9e945febf6ae2c72c0d1d18 schema:name readcube_id
45 schema:value b10c2ff47bb807f1ccb537763f1a0a3d121fb3893848c71c1bdb4972f20841e5
46 rdf:type schema:PropertyValue
47 N4a319677911d4f158293f71fe1aad5e9 rdf:first sg:person.0643047035.93
48 rdf:rest Nff468c8585dd4320a76efeb2292d053a
49 N64138b94341f44cb903848d1a75832e8 rdf:first sg:person.014015352461.03
50 rdf:rest N1303d26ebbb6479e879a9cde601c8935
51 N79525532c61740cb9cf893afaf5d8a6f schema:name Springer Nature - SN SciGraph project
52 rdf:type schema:Organization
53 N8f19a8f2f3e742148b01532176ebf08c schema:name doi
54 schema:value 10.1134/s1070328415110056
55 rdf:type schema:PropertyValue
56 Nd258b2806233415abe9f27504c3ac68e schema:volumeNumber 41
57 rdf:type schema:PublicationVolume
58 Ne45b416fcdfe4b32b89051e5f3efc155 rdf:first sg:person.014434271561.45
59 rdf:rest N4a319677911d4f158293f71fe1aad5e9
60 Nf98a24cafb234c19a07d90b3ad93b266 schema:issueNumber 11
61 rdf:type schema:PublicationIssue
62 Nff468c8585dd4320a76efeb2292d053a rdf:first sg:person.011154723503.70
63 rdf:rest N64138b94341f44cb903848d1a75832e8
64 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
65 schema:name Chemical Sciences
66 rdf:type schema:DefinedTerm
67 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
68 schema:name Inorganic Chemistry
69 rdf:type schema:DefinedTerm
70 sg:journal.1294773 schema:issn 1070-3284
71 1608-3318
72 schema:name Russian Journal of Coordination Chemistry
73 rdf:type schema:Periodical
74 sg:person.011154723503.70 schema:affiliation https://www.grid.ac/institutes/grid.4605.7
75 schema:familyName Bashirov
76 schema:givenName D. A.
77 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011154723503.70
78 rdf:type schema:Person
79 sg:person.014015352461.03 schema:affiliation https://www.grid.ac/institutes/grid.425759.8
80 schema:familyName Afonin
81 schema:givenName M. Yu.
82 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014015352461.03
83 rdf:type schema:Person
84 sg:person.014434271561.45 schema:affiliation https://www.grid.ac/institutes/grid.425759.8
85 schema:familyName Ogienko
86 schema:givenName D. S.
87 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014434271561.45
88 rdf:type schema:Person
89 sg:person.0643047035.93 schema:affiliation https://www.grid.ac/institutes/grid.4605.7
90 schema:familyName Smolentsev
91 schema:givenName A. I.
92 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0643047035.93
93 rdf:type schema:Person
94 sg:person.0662277505.76 schema:affiliation https://www.grid.ac/institutes/grid.4605.7
95 schema:familyName Petrov
96 schema:givenName P. A.
97 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0662277505.76
98 rdf:type schema:Person
99 sg:person.0720422334.76 schema:affiliation https://www.grid.ac/institutes/grid.4605.7
100 schema:familyName Konchenko
101 schema:givenName S. N.
102 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0720422334.76
103 rdf:type schema:Person
104 sg:pub.10.1134/s1070328414040095 schema:sameAs https://app.dimensions.ai/details/publication/pub.1014862006
105 https://doi.org/10.1134/s1070328414040095
106 rdf:type schema:CreativeWork
107 https://doi.org/10.1002/anie.198109341 schema:sameAs https://app.dimensions.ai/details/publication/pub.1005430064
108 rdf:type schema:CreativeWork
109 https://doi.org/10.1016/s0277-5387(00)84930-x schema:sameAs https://app.dimensions.ai/details/publication/pub.1007140025
110 rdf:type schema:CreativeWork
111 https://doi.org/10.1021/cr00091a001 schema:sameAs https://app.dimensions.ai/details/publication/pub.1053840470
112 rdf:type schema:CreativeWork
113 https://doi.org/10.1021/ic00020a031 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055538385
114 rdf:type schema:CreativeWork
115 https://doi.org/10.1021/ic00292a005 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055550785
116 rdf:type schema:CreativeWork
117 https://doi.org/10.1021/ja00014a021 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055699095
118 rdf:type schema:CreativeWork
119 https://doi.org/10.1039/c2cs35145e schema:sameAs https://app.dimensions.ai/details/publication/pub.1031629169
120 rdf:type schema:CreativeWork
121 https://doi.org/10.1107/s0108270196010116 schema:sameAs https://app.dimensions.ai/details/publication/pub.1016083907
122 rdf:type schema:CreativeWork
123 https://doi.org/10.1107/s0108768102003890 schema:sameAs https://app.dimensions.ai/details/publication/pub.1012549006
124 rdf:type schema:CreativeWork
125 https://www.grid.ac/institutes/grid.425759.8 schema:alternateName Nikolaev Institute of Inorganic Chemistry
126 schema:name Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, 630090, Novosibirsk, Russia
127 rdf:type schema:Organization
128 https://www.grid.ac/institutes/grid.4605.7 schema:alternateName Novosibirsk State University
129 schema:name Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, 630090, Novosibirsk, Russia
130 Novosibirsk State University, ul. Pirogova 2, 630090, Novosibirsk, Russia
131 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...