Tin(IV) complexes with 2-hydroxybenz(2-hydroxynaphth)aldehyde nicotinoylhydrazones (H2Ns, H2Nnf). Molecular and crystal structures of [SnCl3(HNnf)] · 2DMF View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2015-05

AUTHORS

N. V. Shmatkova, I. I. Seifullina, Z. A. Starikova

ABSTRACT

The reaction of SnCl4 with 2-hydroxybenz(2-hydroxynaphth)aldehyde nicotinoylhydrazones (H2Ns, H2Nnf) in CH3OH gave non-electrolyte complexes [SnCl3(HNs)] (I) and [SnCl3(HNnf)] (II), which were recrystallized to give the solvates [SnCl3(HNs)] · DMF (III) and [SnCl3(HNnf)] · 2DMF (IV). It was found by IR spectroscopy that the ligands in I–IV are protonated at the N(Py) and coordinated in the tridentate chelating mode through the azomethine nitrogen atom and oxy and oxyazine oxygen atoms. The thermolysis of I–IV and electron impact-induced fragmentation of I and II are accompanied by the formation of the complexes [SnCl2(Ns)] and [SnCl2(Nnf)]. The molecular and crystal structures of IV were determined by X-ray diffraction (CIF file CCDC no. 816105). More... »

PAGES

293-299

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070328415050073

DOI

http://dx.doi.org/10.1134/s1070328415050073

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1017100586


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Inorganic Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Odessa I. I. Mechnikov National University", 
          "id": "https://www.grid.ac/institutes/grid.440557.7", 
          "name": [
            "Mechnikov National University, ul. Petra Velikogo 2, 270100, Odessa, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Shmatkova", 
        "givenName": "N. V.", 
        "id": "sg:person.013343662007.62", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013343662007.62"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Odessa I. I. Mechnikov National University", 
          "id": "https://www.grid.ac/institutes/grid.440557.7", 
          "name": [
            "Mechnikov National University, ul. Petra Velikogo 2, 270100, Odessa, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Seifullina", 
        "givenName": "I. I.", 
        "id": "sg:person.010267237071.32", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010267237071.32"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, 117813, Moscow, GSP-1, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Starikova", 
        "givenName": "Z. A.", 
        "id": "sg:person.014473641160.05", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014473641160.05"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1134/s0036023607040043", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1015270942", 
          "https://doi.org/10.1134/s0036023607040043"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s0036023613010154", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1017485054", 
          "https://doi.org/10.1134/s0036023613010154"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jorganchem.2005.04.049", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1022533954"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1107/s0108767307043930", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1027786902"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.26634/jme.2.1.1552", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1103969314"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2015-05", 
    "datePublishedReg": "2015-05-01", 
    "description": "The reaction of SnCl4 with 2-hydroxybenz(2-hydroxynaphth)aldehyde nicotinoylhydrazones (H2Ns, H2Nnf) in CH3OH gave non-electrolyte complexes [SnCl3(HNs)] (I) and [SnCl3(HNnf)] (II), which were recrystallized to give the solvates [SnCl3(HNs)] \u00b7 DMF (III) and [SnCl3(HNnf)] \u00b7 2DMF (IV). It was found by IR spectroscopy that the ligands in I\u2013IV are protonated at the N(Py) and coordinated in the tridentate chelating mode through the azomethine nitrogen atom and oxy and oxyazine oxygen atoms. The thermolysis of I\u2013IV and electron impact-induced fragmentation of I and II are accompanied by the formation of the complexes [SnCl2(Ns)] and [SnCl2(Nnf)]. The molecular and crystal structures of IV were determined by X-ray diffraction (CIF file CCDC no. 816105).", 
    "genre": "research_article", 
    "id": "sg:pub.10.1134/s1070328415050073", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1294773", 
        "issn": [
          "1070-3284", 
          "1608-3318"
        ], 
        "name": "Russian Journal of Coordination Chemistry", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "5", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "41"
      }
    ], 
    "name": "Tin(IV) complexes with 2-hydroxybenz(2-hydroxynaphth)aldehyde nicotinoylhydrazones (H2Ns, H2Nnf). Molecular and crystal structures of [SnCl3(HNnf)] \u00b7 2DMF", 
    "pagination": "293-299", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "51797c13b2770a22acbc0c88758d2b9341668d7054a289e1271317f4e76147eb"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s1070328415050073"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1017100586"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s1070328415050073", 
      "https://app.dimensions.ai/details/publication/pub.1017100586"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T21:50", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8687_00000584.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1134%2FS1070328415050073"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s1070328415050073'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s1070328415050073'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s1070328415050073'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s1070328415050073'


 

This table displays all metadata directly associated to this object as RDF triples.

95 TRIPLES      21 PREDICATES      32 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s1070328415050073 schema:about anzsrc-for:03
2 anzsrc-for:0302
3 schema:author Nc5a673ecf764487e92ebdd79a76f19fe
4 schema:citation sg:pub.10.1134/s0036023607040043
5 sg:pub.10.1134/s0036023613010154
6 https://doi.org/10.1016/j.jorganchem.2005.04.049
7 https://doi.org/10.1107/s0108767307043930
8 https://doi.org/10.26634/jme.2.1.1552
9 schema:datePublished 2015-05
10 schema:datePublishedReg 2015-05-01
11 schema:description The reaction of SnCl4 with 2-hydroxybenz(2-hydroxynaphth)aldehyde nicotinoylhydrazones (H2Ns, H2Nnf) in CH3OH gave non-electrolyte complexes [SnCl3(HNs)] (I) and [SnCl3(HNnf)] (II), which were recrystallized to give the solvates [SnCl3(HNs)] · DMF (III) and [SnCl3(HNnf)] · 2DMF (IV). It was found by IR spectroscopy that the ligands in I–IV are protonated at the N(Py) and coordinated in the tridentate chelating mode through the azomethine nitrogen atom and oxy and oxyazine oxygen atoms. The thermolysis of I–IV and electron impact-induced fragmentation of I and II are accompanied by the formation of the complexes [SnCl2(Ns)] and [SnCl2(Nnf)]. The molecular and crystal structures of IV were determined by X-ray diffraction (CIF file CCDC no. 816105).
12 schema:genre research_article
13 schema:inLanguage en
14 schema:isAccessibleForFree false
15 schema:isPartOf N7fd61d8b9f524e29bfa050b196becc14
16 Naa826e235f9942f9bd3a9428a29fb00a
17 sg:journal.1294773
18 schema:name Tin(IV) complexes with 2-hydroxybenz(2-hydroxynaphth)aldehyde nicotinoylhydrazones (H2Ns, H2Nnf). Molecular and crystal structures of [SnCl3(HNnf)] · 2DMF
19 schema:pagination 293-299
20 schema:productId N628afaceb5b04dce98609ce133357aee
21 N78efd79147864b5ab9263e6bfa7d1847
22 Nbbeb88757dc94a919a37909e99a3e70e
23 schema:sameAs https://app.dimensions.ai/details/publication/pub.1017100586
24 https://doi.org/10.1134/s1070328415050073
25 schema:sdDatePublished 2019-04-10T21:50
26 schema:sdLicense https://scigraph.springernature.com/explorer/license/
27 schema:sdPublisher Nc8237c0702364363bc46ce2cc290a422
28 schema:url http://link.springer.com/10.1134%2FS1070328415050073
29 sgo:license sg:explorer/license/
30 sgo:sdDataset articles
31 rdf:type schema:ScholarlyArticle
32 N16137d2dd4b94bfc9a4bf2798bb2381e rdf:first sg:person.014473641160.05
33 rdf:rest rdf:nil
34 N628afaceb5b04dce98609ce133357aee schema:name dimensions_id
35 schema:value pub.1017100586
36 rdf:type schema:PropertyValue
37 N78efd79147864b5ab9263e6bfa7d1847 schema:name readcube_id
38 schema:value 51797c13b2770a22acbc0c88758d2b9341668d7054a289e1271317f4e76147eb
39 rdf:type schema:PropertyValue
40 N7fd61d8b9f524e29bfa050b196becc14 schema:volumeNumber 41
41 rdf:type schema:PublicationVolume
42 Na52d214d42794a0ba80b019d180202e1 rdf:first sg:person.010267237071.32
43 rdf:rest N16137d2dd4b94bfc9a4bf2798bb2381e
44 Naa826e235f9942f9bd3a9428a29fb00a schema:issueNumber 5
45 rdf:type schema:PublicationIssue
46 Nbbeb88757dc94a919a37909e99a3e70e schema:name doi
47 schema:value 10.1134/s1070328415050073
48 rdf:type schema:PropertyValue
49 Nc5a673ecf764487e92ebdd79a76f19fe rdf:first sg:person.013343662007.62
50 rdf:rest Na52d214d42794a0ba80b019d180202e1
51 Nc8237c0702364363bc46ce2cc290a422 schema:name Springer Nature - SN SciGraph project
52 rdf:type schema:Organization
53 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
54 schema:name Chemical Sciences
55 rdf:type schema:DefinedTerm
56 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
57 schema:name Inorganic Chemistry
58 rdf:type schema:DefinedTerm
59 sg:journal.1294773 schema:issn 1070-3284
60 1608-3318
61 schema:name Russian Journal of Coordination Chemistry
62 rdf:type schema:Periodical
63 sg:person.010267237071.32 schema:affiliation https://www.grid.ac/institutes/grid.440557.7
64 schema:familyName Seifullina
65 schema:givenName I. I.
66 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010267237071.32
67 rdf:type schema:Person
68 sg:person.013343662007.62 schema:affiliation https://www.grid.ac/institutes/grid.440557.7
69 schema:familyName Shmatkova
70 schema:givenName N. V.
71 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013343662007.62
72 rdf:type schema:Person
73 sg:person.014473641160.05 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
74 schema:familyName Starikova
75 schema:givenName Z. A.
76 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014473641160.05
77 rdf:type schema:Person
78 sg:pub.10.1134/s0036023607040043 schema:sameAs https://app.dimensions.ai/details/publication/pub.1015270942
79 https://doi.org/10.1134/s0036023607040043
80 rdf:type schema:CreativeWork
81 sg:pub.10.1134/s0036023613010154 schema:sameAs https://app.dimensions.ai/details/publication/pub.1017485054
82 https://doi.org/10.1134/s0036023613010154
83 rdf:type schema:CreativeWork
84 https://doi.org/10.1016/j.jorganchem.2005.04.049 schema:sameAs https://app.dimensions.ai/details/publication/pub.1022533954
85 rdf:type schema:CreativeWork
86 https://doi.org/10.1107/s0108767307043930 schema:sameAs https://app.dimensions.ai/details/publication/pub.1027786902
87 rdf:type schema:CreativeWork
88 https://doi.org/10.26634/jme.2.1.1552 schema:sameAs https://app.dimensions.ai/details/publication/pub.1103969314
89 rdf:type schema:CreativeWork
90 https://www.grid.ac/institutes/grid.440557.7 schema:alternateName Odessa I. I. Mechnikov National University
91 schema:name Mechnikov National University, ul. Petra Velikogo 2, 270100, Odessa, Ukraine
92 rdf:type schema:Organization
93 https://www.grid.ac/institutes/grid.4886.2 schema:alternateName Russian Academy of Sciences
94 schema:name Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, 117813, Moscow, GSP-1, Russia
95 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...