Complexes {Cp*(Dppe)FeC≡CC2R[Co2L2(CO)4]}n+ (R = H, Si(CH3)3; n = 0, 1, 2; L2 = (CO)2, Dppm): Synthesis, redox properties, and electronic ... View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2015-02-13

AUTHORS

V. A. Koneva, M. G. Ezernitskaya, E. S. Taits, F. M. Dolgushin, B. V. Lokshin, V. V. Krivykh

ABSTRACT

New neutral and cationic complexes containing the mononuclear organoiron Cp*(Dppe)Fe and cluster Co2C2 fragments have been synthesized. It was shown that the redox reactions substantially extend possibilities for the synthesis of the cationic complexes, and the transition metal derivatives with the unoccupied electron shell represent an interesting and promising direction of studies. It has been confirmed by spectroscopy in the near-IR range a substantial intramolecular electron interaction between the cobalt and iron atoms in the cationic complexes. The obtained estimates for the interaction energy suggest that these compounds can be perspective as molecular devices. More... »

PAGES

93-100

References to SciGraph publications

  • 1989. Chemistry and Reactivity of Metal Cluster Carbonyl Radical Anions in PARAMAGNETIC ORGANOMETALLIC SPECIES IN ACTIVATION/SELECTIVITY, CATALYSIS
  • 2010-05-25. Electronic Interactions Between and Through Covalently-Bonded Polymetallic Complexes in JOURNAL OF CLUSTER SCIENCE
  • Identifiers

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    http://scigraph.springernature.com/pub.10.1134/s1070328415020037

    DOI

    http://dx.doi.org/10.1134/s1070328415020037

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