Trinuclear iodobismuthate complex [Na3(Me2CO)12][Bi3I12]: Synthesis and crystal structure View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2014-12

AUTHORS

S. A. Adonin, E. V. Peresypkina, M. N. Sokolov, V. P. Fedin

ABSTRACT

The reaction of BiI3 and NaI in acetone gives a trinuclear iodobismuthate complex, [Na3(Me2CO)12][Bi3I12] (I), which was studied by X-ray diffraction (CIF file CCDC no. 996330). The centrosymmetric [Bi3III I12]3− anions are groups of three distorted {BiI6} octahedra coupled at the faces. The sodium cations combine six Me2CO molecules in the bidentate bridging mode to give linear trimers in which the side sodium ions coordinate six terminal acetone molecules. More... »

PAGES

867-870

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URI

http://scigraph.springernature.com/pub.10.1134/s107032841412001x

DOI

http://dx.doi.org/10.1134/s107032841412001x

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