Xanthate complexes of {Nb2S4}4+ View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2014-07

AUTHORS

M. N. Sokolov, A. V. Rogachev, A. V. Virovets, V. S. Korenev, M. A. Mikhailov, Yu. A. Laricheva, P. L. Sinkevich, D. A. Mainichev

ABSTRACT

Alkyl xanthate complexes [Nb2S4(S2COR)4] (R = Et (I), iso-Pr (II), n-Bu (III), and iso-Am (IV)) are synthesized by the ligand exchange reaction in solutions from (Et4N)4[Nb2S4(NCS)8] and the corresponding potassium salts in satisfactory yields. The X-ray diffraction analyses are carried out for the isopropyl xanthate (II) and butyl xanthate (III) complexes. From the view point of mutual arrangement of chelate cycles, complexes II and III exist in crystals as ΛΔ isomers. The niobium-niobium distances are 2.8789(4) Å in complex II and 2.8856(3) Å in complex III. The first example for the formation of short S...S contacts between the disulfide ligands of the {Nb2S4}4+ fragments in the crystal structure of III is found (3.146 Å). More... »

PAGES

460-467

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070328414060086

DOI

http://dx.doi.org/10.1134/s1070328414060086

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1012485245


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