Cluster complexes [Mo3O2S2(Acac)3(Amine)3]PF6 View Full Text


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Article Info

DATE

2014-03

AUTHORS

P. A. Abramov, J. A. Laricheva, E. V. Peresypkina, M. N. Sokolov

ABSTRACT

New mixed-ligand cluster complexes [Mo3O2S2(Acac)3(Amine)3]PF6 (Amine = morpholine (Mor), 4-cyanopyridine (PyCN), pyrazine (Pz)) have been synthesized. The compounds were characterized by IR spectroscopy and mass spectrometry (ESI-MS). The crystal structure of the Mor complex, which was isolated as [Mo3(μ3-S)(μ2-O)2(μ2-S)(Acac)3(Mor)3]PF6 · 0.5Mor · 0.3(CH3)2CO was determined. The stability of the complexes in methanolic solutions decreases in a row: Mor > PyCN > Pz. More... »

PAGES

171-178

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070328414030014

DOI

http://dx.doi.org/10.1134/s1070328414030014

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1040132132


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