Heteroligand complexes of lanthanides with 4-formyl-3-methyl-1-phenylpyrazol-5-one and 1,10-phenanthroline View Full Text


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Article Info

DATE

2014-01-03

AUTHORS

O. V. Konnik, V. F. Shul’gin, S. V. Abkhairova, S. B. Meshkova, E. B. Rusanov, V. V. Minin

ABSTRACT

Complexes of the general formula LnL3 · Phen (Ln = Nd, Sm, Eu, Gd, Tb, Dy, and Yb; HL = 4-formyl-3-methyl-1-phenylpyrazol-5-one, Phen = 1,10-phenanthroline) were obtained and examined by IR spectroscopy and thermogravimetry. The structure of the complex TbL3 · Phen was studied by X-ray diffraction. The coordination polyhedron of terbium is a distorted square antiprism made up of six O atoms of three 4-formylpyrazol-5-one anions and two N atoms of the 1,10-phenanthroline molecule. Polycrystalline samples of the complexes studied show emission in the spectral ranges characteristic of Ln(III). More... »

PAGES

28-33

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070328414010035

DOI

http://dx.doi.org/10.1134/s1070328414010035

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1014200383


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