Heteroligand complexes of lanthanides with 4-formyl-3-methyl-1-phenylpyrazol-5-one and 1,10-phenanthroline View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2014-01-03

AUTHORS

O. V. Konnik, V. F. Shul’gin, S. V. Abkhairova, S. B. Meshkova, E. B. Rusanov, V. V. Minin

ABSTRACT

Complexes of the general formula LnL3 · Phen (Ln = Nd, Sm, Eu, Gd, Tb, Dy, and Yb; HL = 4-formyl-3-methyl-1-phenylpyrazol-5-one, Phen = 1,10-phenanthroline) were obtained and examined by IR spectroscopy and thermogravimetry. The structure of the complex TbL3 · Phen was studied by X-ray diffraction. The coordination polyhedron of terbium is a distorted square antiprism made up of six O atoms of three 4-formylpyrazol-5-one anions and two N atoms of the 1,10-phenanthroline molecule. Polycrystalline samples of the complexes studied show emission in the spectral ranges characteristic of Ln(III). More... »

PAGES

28-33

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070328414010035

DOI

http://dx.doi.org/10.1134/s1070328414010035

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1014200383


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Inorganic Chemistry", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Taurida National V.I. Vernadsky University, Simferopol, Ukraine", 
          "id": "http://www.grid.ac/institutes/grid.412629.a", 
          "name": [
            "Taurida National V.I. Vernadsky University, Simferopol, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Konnik", 
        "givenName": "O. V.", 
        "id": "sg:person.01045006120.37", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01045006120.37"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Taurida National V.I. Vernadsky University, Simferopol, Ukraine", 
          "id": "http://www.grid.ac/institutes/grid.412629.a", 
          "name": [
            "Taurida National V.I. Vernadsky University, Simferopol, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Shul\u2019gin", 
        "givenName": "V. F.", 
        "id": "sg:person.0616602656.25", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0616602656.25"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Taurida National V.I. Vernadsky University, Simferopol, Ukraine", 
          "id": "http://www.grid.ac/institutes/grid.412629.a", 
          "name": [
            "Taurida National V.I. Vernadsky University, Simferopol, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Abkhairova", 
        "givenName": "S. V.", 
        "id": "sg:person.016351366151.07", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016351366151.07"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Bogatskii Physicochemical Institute, National Academy of Sciences of Ukraine, Odessa, Ukraine", 
          "id": "http://www.grid.ac/institutes/grid.418751.e", 
          "name": [
            "Bogatskii Physicochemical Institute, National Academy of Sciences of Ukraine, Odessa, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Meshkova", 
        "givenName": "S. B.", 
        "id": "sg:person.0664716056.01", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0664716056.01"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Organic Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine", 
          "id": "http://www.grid.ac/institutes/grid.464621.3", 
          "name": [
            "Institute of Organic Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Rusanov", 
        "givenName": "E. B.", 
        "id": "sg:person.01247600537.28", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01247600537.28"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.435216.7", 
          "name": [
            "Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Minin", 
        "givenName": "V. V.", 
        "id": "sg:person.011207441575.56", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011207441575.56"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1134/s0036023607090100", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1020084879", 
          "https://doi.org/10.1134/s0036023607090100"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s0036023612030291", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1034040444", 
          "https://doi.org/10.1134/s0036023612030291"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2014-01-03", 
    "datePublishedReg": "2014-01-03", 
    "description": "Complexes of the general formula LnL3 \u00b7 Phen (Ln = Nd, Sm, Eu, Gd, Tb, Dy, and Yb; HL = 4-formyl-3-methyl-1-phenylpyrazol-5-one, Phen = 1,10-phenanthroline) were obtained and examined by IR spectroscopy and thermogravimetry. The structure of the complex TbL3 \u00b7 Phen was studied by X-ray diffraction. The coordination polyhedron of terbium is a distorted square antiprism made up of six O atoms of three 4-formylpyrazol-5-one anions and two N atoms of the 1,10-phenanthroline molecule. Polycrystalline samples of the complexes studied show emission in the spectral ranges characteristic of Ln(III).", 
    "genre": "article", 
    "id": "sg:pub.10.1134/s1070328414010035", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1294773", 
        "issn": [
          "1070-3284", 
          "1608-3318"
        ], 
        "name": "Russian Journal of Coordination Chemistry", 
        "publisher": "Pleiades Publishing", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "1", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "40"
      }
    ], 
    "keywords": [
      "distorted square antiprism", 
      "X-ray diffraction", 
      "phenanthroline molecules", 
      "heteroligand complexes", 
      "IR spectroscopy", 
      "coordination polyhedron", 
      "square antiprism", 
      "O atoms", 
      "phen", 
      "show emission", 
      "complexes", 
      "atoms", 
      "polycrystalline samples", 
      "LnL3", 
      "anions", 
      "phenanthroline", 
      "lanthanides", 
      "antiprism", 
      "spectroscopy", 
      "thermogravimetry", 
      "diffraction", 
      "spectral range", 
      "TBL3", 
      "molecules", 
      "terbium", 
      "polyhedra", 
      "structure", 
      "emission", 
      "range", 
      "samples"
    ], 
    "name": "Heteroligand complexes of lanthanides with 4-formyl-3-methyl-1-phenylpyrazol-5-one and 1,10-phenanthroline", 
    "pagination": "28-33", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1014200383"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s1070328414010035"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s1070328414010035", 
      "https://app.dimensions.ai/details/publication/pub.1014200383"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-10-01T06:39", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20221001/entities/gbq_results/article/article_618.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1134/s1070328414010035"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s1070328414010035'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s1070328414010035'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s1070328414010035'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s1070328414010035'


 

This table displays all metadata directly associated to this object as RDF triples.

139 TRIPLES      21 PREDICATES      56 URIs      46 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s1070328414010035 schema:about anzsrc-for:03
2 anzsrc-for:0302
3 schema:author Naa1a87618af94cefb7a3d3c6a9bff07c
4 schema:citation sg:pub.10.1134/s0036023607090100
5 sg:pub.10.1134/s0036023612030291
6 schema:datePublished 2014-01-03
7 schema:datePublishedReg 2014-01-03
8 schema:description Complexes of the general formula LnL3 · Phen (Ln = Nd, Sm, Eu, Gd, Tb, Dy, and Yb; HL = 4-formyl-3-methyl-1-phenylpyrazol-5-one, Phen = 1,10-phenanthroline) were obtained and examined by IR spectroscopy and thermogravimetry. The structure of the complex TbL3 · Phen was studied by X-ray diffraction. The coordination polyhedron of terbium is a distorted square antiprism made up of six O atoms of three 4-formylpyrazol-5-one anions and two N atoms of the 1,10-phenanthroline molecule. Polycrystalline samples of the complexes studied show emission in the spectral ranges characteristic of Ln(III).
9 schema:genre article
10 schema:isAccessibleForFree false
11 schema:isPartOf N211c000d210a4c2faf2b967b071dc634
12 N2921cf58e7cd48b0ba5b862d33ccf22c
13 sg:journal.1294773
14 schema:keywords IR spectroscopy
15 LnL3
16 O atoms
17 TBL3
18 X-ray diffraction
19 anions
20 antiprism
21 atoms
22 complexes
23 coordination polyhedron
24 diffraction
25 distorted square antiprism
26 emission
27 heteroligand complexes
28 lanthanides
29 molecules
30 phen
31 phenanthroline
32 phenanthroline molecules
33 polycrystalline samples
34 polyhedra
35 range
36 samples
37 show emission
38 spectral range
39 spectroscopy
40 square antiprism
41 structure
42 terbium
43 thermogravimetry
44 schema:name Heteroligand complexes of lanthanides with 4-formyl-3-methyl-1-phenylpyrazol-5-one and 1,10-phenanthroline
45 schema:pagination 28-33
46 schema:productId N21cd46dd634c4d158452e5b10d6f3fb2
47 Nc992bc6f1d314bf18ccb0b97f999dcac
48 schema:sameAs https://app.dimensions.ai/details/publication/pub.1014200383
49 https://doi.org/10.1134/s1070328414010035
50 schema:sdDatePublished 2022-10-01T06:39
51 schema:sdLicense https://scigraph.springernature.com/explorer/license/
52 schema:sdPublisher Nb231a30452014bd8badfa709f5092c44
53 schema:url https://doi.org/10.1134/s1070328414010035
54 sgo:license sg:explorer/license/
55 sgo:sdDataset articles
56 rdf:type schema:ScholarlyArticle
57 N211c000d210a4c2faf2b967b071dc634 schema:issueNumber 1
58 rdf:type schema:PublicationIssue
59 N21cd46dd634c4d158452e5b10d6f3fb2 schema:name dimensions_id
60 schema:value pub.1014200383
61 rdf:type schema:PropertyValue
62 N2921cf58e7cd48b0ba5b862d33ccf22c schema:volumeNumber 40
63 rdf:type schema:PublicationVolume
64 N55c409d1fe1c41e2963a2eb9355b18f0 rdf:first sg:person.016351366151.07
65 rdf:rest Nbc16778244b64d63a057818a0f331b50
66 N6c8f09e1a4dc49028f275739443ca394 rdf:first sg:person.011207441575.56
67 rdf:rest rdf:nil
68 N9643999fcad1493e90ca91881a5b8b61 rdf:first sg:person.01247600537.28
69 rdf:rest N6c8f09e1a4dc49028f275739443ca394
70 Na1c76ecd75054a2e83a6a5adcbcd251d rdf:first sg:person.0616602656.25
71 rdf:rest N55c409d1fe1c41e2963a2eb9355b18f0
72 Naa1a87618af94cefb7a3d3c6a9bff07c rdf:first sg:person.01045006120.37
73 rdf:rest Na1c76ecd75054a2e83a6a5adcbcd251d
74 Nb231a30452014bd8badfa709f5092c44 schema:name Springer Nature - SN SciGraph project
75 rdf:type schema:Organization
76 Nbc16778244b64d63a057818a0f331b50 rdf:first sg:person.0664716056.01
77 rdf:rest N9643999fcad1493e90ca91881a5b8b61
78 Nc992bc6f1d314bf18ccb0b97f999dcac schema:name doi
79 schema:value 10.1134/s1070328414010035
80 rdf:type schema:PropertyValue
81 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
82 schema:name Chemical Sciences
83 rdf:type schema:DefinedTerm
84 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
85 schema:name Inorganic Chemistry
86 rdf:type schema:DefinedTerm
87 sg:journal.1294773 schema:issn 1070-3284
88 1608-3318
89 schema:name Russian Journal of Coordination Chemistry
90 schema:publisher Pleiades Publishing
91 rdf:type schema:Periodical
92 sg:person.01045006120.37 schema:affiliation grid-institutes:grid.412629.a
93 schema:familyName Konnik
94 schema:givenName O. V.
95 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01045006120.37
96 rdf:type schema:Person
97 sg:person.011207441575.56 schema:affiliation grid-institutes:grid.435216.7
98 schema:familyName Minin
99 schema:givenName V. V.
100 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011207441575.56
101 rdf:type schema:Person
102 sg:person.01247600537.28 schema:affiliation grid-institutes:grid.464621.3
103 schema:familyName Rusanov
104 schema:givenName E. B.
105 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01247600537.28
106 rdf:type schema:Person
107 sg:person.016351366151.07 schema:affiliation grid-institutes:grid.412629.a
108 schema:familyName Abkhairova
109 schema:givenName S. V.
110 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016351366151.07
111 rdf:type schema:Person
112 sg:person.0616602656.25 schema:affiliation grid-institutes:grid.412629.a
113 schema:familyName Shul’gin
114 schema:givenName V. F.
115 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0616602656.25
116 rdf:type schema:Person
117 sg:person.0664716056.01 schema:affiliation grid-institutes:grid.418751.e
118 schema:familyName Meshkova
119 schema:givenName S. B.
120 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0664716056.01
121 rdf:type schema:Person
122 sg:pub.10.1134/s0036023607090100 schema:sameAs https://app.dimensions.ai/details/publication/pub.1020084879
123 https://doi.org/10.1134/s0036023607090100
124 rdf:type schema:CreativeWork
125 sg:pub.10.1134/s0036023612030291 schema:sameAs https://app.dimensions.ai/details/publication/pub.1034040444
126 https://doi.org/10.1134/s0036023612030291
127 rdf:type schema:CreativeWork
128 grid-institutes:grid.412629.a schema:alternateName Taurida National V.I. Vernadsky University, Simferopol, Ukraine
129 schema:name Taurida National V.I. Vernadsky University, Simferopol, Ukraine
130 rdf:type schema:Organization
131 grid-institutes:grid.418751.e schema:alternateName Bogatskii Physicochemical Institute, National Academy of Sciences of Ukraine, Odessa, Ukraine
132 schema:name Bogatskii Physicochemical Institute, National Academy of Sciences of Ukraine, Odessa, Ukraine
133 rdf:type schema:Organization
134 grid-institutes:grid.435216.7 schema:alternateName Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia
135 schema:name Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia
136 rdf:type schema:Organization
137 grid-institutes:grid.464621.3 schema:alternateName Institute of Organic Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine
138 schema:name Institute of Organic Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine
139 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...