Polymeric copper(II) complexes with 4-formyl-3-methyl-1-phenylpyrazol-5-one hetarylhydrazones: Synthesis and crystal structures View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2013-11-27

AUTHORS

L. D. Popov, S. I. Levchenkov, I. N. Shcherbakov, V. V. Minin, G. G. Aleksandrov, E. A. Ugolkova, V. V. Lukov, V. A. Kogan

ABSTRACT

4-Formyl-3-methyl-1-phenylpyrazol-5-one quinolin-2-yl-(H2L1) and benzothiazol-2-ylhydrazones (H2L2) were synthesized and studied. Quantum-chemical modeling of possible tautomers of the hydrazones was performed. Copper(II) complexes of the general formula [Cu(HL)(ROH)]Y (R = CH3, C2H5; Y=NO3, ClO4) were obtained and examined by IR and EPR spectroscopy, magnetochemistry, and X-ray diffraction. Additional coordination through the N atom of the pyrazole ring enables the complex molecules to form zigzag polymer chains linked by intermolecular hydrogen bonds. More... »

PAGES

849-856

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070328413110079

DOI

http://dx.doi.org/10.1134/s1070328413110079

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1032027308


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Inorganic Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0303", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Macromolecular and Materials Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Southern Federal University, Rostov-on-Don, Russia", 
          "id": "http://www.grid.ac/institutes/grid.182798.d", 
          "name": [
            "Southern Federal University, Rostov-on-Don, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Popov", 
        "givenName": "L. D.", 
        "id": "sg:person.0721047070.68", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0721047070.68"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Southern Scientific Center, Russian Academy of Sciences, Rostov-on-Don, Russia", 
          "id": "http://www.grid.ac/institutes/grid.465325.3", 
          "name": [
            "Southern Scientific Center, Russian Academy of Sciences, Rostov-on-Don, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Levchenkov", 
        "givenName": "S. I.", 
        "id": "sg:person.014535627721.66", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014535627721.66"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Southern Federal University, Rostov-on-Don, Russia", 
          "id": "http://www.grid.ac/institutes/grid.182798.d", 
          "name": [
            "Southern Federal University, Rostov-on-Don, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Shcherbakov", 
        "givenName": "I. N.", 
        "id": "sg:person.011547725721.73", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011547725721.73"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.435216.7", 
          "name": [
            "Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Minin", 
        "givenName": "V. V.", 
        "id": "sg:person.011207441575.56", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011207441575.56"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.435216.7", 
          "name": [
            "Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Aleksandrov", 
        "givenName": "G. G.", 
        "id": "sg:person.014422304747.19", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014422304747.19"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia", 
          "id": "http://www.grid.ac/institutes/grid.435216.7", 
          "name": [
            "Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ugolkova", 
        "givenName": "E. A.", 
        "id": "sg:person.015265162315.78", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015265162315.78"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Southern Federal University, Rostov-on-Don, Russia", 
          "id": "http://www.grid.ac/institutes/grid.182798.d", 
          "name": [
            "Southern Federal University, Rostov-on-Don, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Lukov", 
        "givenName": "V. V.", 
        "id": "sg:person.011277251571.08", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011277251571.08"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Southern Federal University, Rostov-on-Don, Russia", 
          "id": "http://www.grid.ac/institutes/grid.182798.d", 
          "name": [
            "Southern Federal University, Rostov-on-Don, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kogan", 
        "givenName": "V. A.", 
        "id": "sg:person.01147254073.80", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01147254073.80"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1023/b:rugc.0000007624.57825.22", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1026885662", 
          "https://doi.org/10.1023/b:rugc.0000007624.57825.22"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s00044-011-9749-3", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1029438672", 
          "https://doi.org/10.1007/s00044-011-9749-3"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s0036023609080099", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1009274149", 
          "https://doi.org/10.1134/s0036023609080099"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s0036023610050165", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1040901559", 
          "https://doi.org/10.1134/s0036023610050165"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s0036023612020234", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1034366985", 
          "https://doi.org/10.1134/s0036023612020234"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2013-11-27", 
    "datePublishedReg": "2013-11-27", 
    "description": "Abstract4-Formyl-3-methyl-1-phenylpyrazol-5-one quinolin-2-yl-(H2L1) and benzothiazol-2-ylhydrazones (H2L2) were synthesized and studied. Quantum-chemical modeling of possible tautomers of the hydrazones was performed. Copper(II) complexes of the general formula [Cu(HL)(ROH)]Y (R = CH3, C2H5; Y=NO3, ClO4) were obtained and examined by IR and EPR spectroscopy, magnetochemistry, and X-ray diffraction. Additional coordination through the N atom of the pyrazole ring enables the complex molecules to form zigzag polymer chains linked by intermolecular hydrogen bonds.", 
    "genre": "article", 
    "id": "sg:pub.10.1134/s1070328413110079", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1294773", 
        "issn": [
          "1070-3284", 
          "1608-3318"
        ], 
        "name": "Russian Journal of Coordination Chemistry", 
        "publisher": "Pleiades Publishing", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "12", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "39"
      }
    ], 
    "keywords": [
      "zigzag polymer chains", 
      "quantum chemical modeling", 
      "intermolecular hydrogen bonds", 
      "X-ray diffraction", 
      "polymer chains", 
      "EPR spectroscopy", 
      "possible tautomers", 
      "additional coordination", 
      "hydrogen bonds", 
      "phenylpyrazol-5", 
      "complex molecules", 
      "crystal structure", 
      "N atoms", 
      "general formula", 
      "pyrazole ring", 
      "complexes", 
      "hetarylhydrazones", 
      "magnetochemistry", 
      "tautomers", 
      "hydrazones", 
      "IR", 
      "spectroscopy", 
      "bonds", 
      "Abstract4", 
      "diffraction", 
      "synthesis", 
      "molecules", 
      "atoms", 
      "ring", 
      "chain", 
      "coordination", 
      "structure", 
      "formula", 
      "modeling"
    ], 
    "name": "Polymeric copper(II) complexes with 4-formyl-3-methyl-1-phenylpyrazol-5-one hetarylhydrazones: Synthesis and crystal structures", 
    "pagination": "849-856", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1032027308"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s1070328413110079"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s1070328413110079", 
      "https://app.dimensions.ai/details/publication/pub.1032027308"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-12-01T06:31", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20221201/entities/gbq_results/article/article_606.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1134/s1070328413110079"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s1070328413110079'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s1070328413110079'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s1070328413110079'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s1070328413110079'


 

This table displays all metadata directly associated to this object as RDF triples.

174 TRIPLES      21 PREDICATES      65 URIs      50 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s1070328413110079 schema:about anzsrc-for:03
2 anzsrc-for:0302
3 anzsrc-for:0303
4 anzsrc-for:0306
5 schema:author N91d9619cc0f946f2a075b733abf78e0e
6 schema:citation sg:pub.10.1007/s00044-011-9749-3
7 sg:pub.10.1023/b:rugc.0000007624.57825.22
8 sg:pub.10.1134/s0036023609080099
9 sg:pub.10.1134/s0036023610050165
10 sg:pub.10.1134/s0036023612020234
11 schema:datePublished 2013-11-27
12 schema:datePublishedReg 2013-11-27
13 schema:description Abstract4-Formyl-3-methyl-1-phenylpyrazol-5-one quinolin-2-yl-(H2L1) and benzothiazol-2-ylhydrazones (H2L2) were synthesized and studied. Quantum-chemical modeling of possible tautomers of the hydrazones was performed. Copper(II) complexes of the general formula [Cu(HL)(ROH)]Y (R = CH3, C2H5; Y=NO3, ClO4) were obtained and examined by IR and EPR spectroscopy, magnetochemistry, and X-ray diffraction. Additional coordination through the N atom of the pyrazole ring enables the complex molecules to form zigzag polymer chains linked by intermolecular hydrogen bonds.
14 schema:genre article
15 schema:isAccessibleForFree false
16 schema:isPartOf N7f4aa961623249069d7f17a0e5bb96b4
17 Ndd20287087874e0eb69133b41bbe19a9
18 sg:journal.1294773
19 schema:keywords Abstract4
20 EPR spectroscopy
21 IR
22 N atoms
23 X-ray diffraction
24 additional coordination
25 atoms
26 bonds
27 chain
28 complex molecules
29 complexes
30 coordination
31 crystal structure
32 diffraction
33 formula
34 general formula
35 hetarylhydrazones
36 hydrazones
37 hydrogen bonds
38 intermolecular hydrogen bonds
39 magnetochemistry
40 modeling
41 molecules
42 phenylpyrazol-5
43 polymer chains
44 possible tautomers
45 pyrazole ring
46 quantum chemical modeling
47 ring
48 spectroscopy
49 structure
50 synthesis
51 tautomers
52 zigzag polymer chains
53 schema:name Polymeric copper(II) complexes with 4-formyl-3-methyl-1-phenylpyrazol-5-one hetarylhydrazones: Synthesis and crystal structures
54 schema:pagination 849-856
55 schema:productId N81435d386b3240668453118755ee58a2
56 Nb299706535d44c19a1f390f1433c93fd
57 schema:sameAs https://app.dimensions.ai/details/publication/pub.1032027308
58 https://doi.org/10.1134/s1070328413110079
59 schema:sdDatePublished 2022-12-01T06:31
60 schema:sdLicense https://scigraph.springernature.com/explorer/license/
61 schema:sdPublisher N4b4d2235b9c44db79c8f0328eec71462
62 schema:url https://doi.org/10.1134/s1070328413110079
63 sgo:license sg:explorer/license/
64 sgo:sdDataset articles
65 rdf:type schema:ScholarlyArticle
66 N4b4d2235b9c44db79c8f0328eec71462 schema:name Springer Nature - SN SciGraph project
67 rdf:type schema:Organization
68 N5fb480a22de8410d9d00e068d2aff210 rdf:first sg:person.014535627721.66
69 rdf:rest N99a81a3bc561423a87262eb576a17f8e
70 N7f4aa961623249069d7f17a0e5bb96b4 schema:volumeNumber 39
71 rdf:type schema:PublicationVolume
72 N81435d386b3240668453118755ee58a2 schema:name doi
73 schema:value 10.1134/s1070328413110079
74 rdf:type schema:PropertyValue
75 N91d9619cc0f946f2a075b733abf78e0e rdf:first sg:person.0721047070.68
76 rdf:rest N5fb480a22de8410d9d00e068d2aff210
77 N99a81a3bc561423a87262eb576a17f8e rdf:first sg:person.011547725721.73
78 rdf:rest N9a0349a97d5242068c03c502059f6f4d
79 N9a0349a97d5242068c03c502059f6f4d rdf:first sg:person.011207441575.56
80 rdf:rest Ncaba6119b9794f33b7584e73477d723a
81 Nb299706535d44c19a1f390f1433c93fd schema:name dimensions_id
82 schema:value pub.1032027308
83 rdf:type schema:PropertyValue
84 Nc98c21d903884ccb8f12cd97336f0387 rdf:first sg:person.01147254073.80
85 rdf:rest rdf:nil
86 Ncaba6119b9794f33b7584e73477d723a rdf:first sg:person.014422304747.19
87 rdf:rest Nd3338cbf33444efba2daa86fc751327b
88 Nd3338cbf33444efba2daa86fc751327b rdf:first sg:person.015265162315.78
89 rdf:rest Nf308db9540544adfac8271fba65950ee
90 Ndd20287087874e0eb69133b41bbe19a9 schema:issueNumber 12
91 rdf:type schema:PublicationIssue
92 Nf308db9540544adfac8271fba65950ee rdf:first sg:person.011277251571.08
93 rdf:rest Nc98c21d903884ccb8f12cd97336f0387
94 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
95 schema:name Chemical Sciences
96 rdf:type schema:DefinedTerm
97 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
98 schema:name Inorganic Chemistry
99 rdf:type schema:DefinedTerm
100 anzsrc-for:0303 schema:inDefinedTermSet anzsrc-for:
101 schema:name Macromolecular and Materials Chemistry
102 rdf:type schema:DefinedTerm
103 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
104 schema:name Physical Chemistry (incl. Structural)
105 rdf:type schema:DefinedTerm
106 sg:journal.1294773 schema:issn 1070-3284
107 1608-3318
108 schema:name Russian Journal of Coordination Chemistry
109 schema:publisher Pleiades Publishing
110 rdf:type schema:Periodical
111 sg:person.011207441575.56 schema:affiliation grid-institutes:grid.435216.7
112 schema:familyName Minin
113 schema:givenName V. V.
114 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011207441575.56
115 rdf:type schema:Person
116 sg:person.011277251571.08 schema:affiliation grid-institutes:grid.182798.d
117 schema:familyName Lukov
118 schema:givenName V. V.
119 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011277251571.08
120 rdf:type schema:Person
121 sg:person.01147254073.80 schema:affiliation grid-institutes:grid.182798.d
122 schema:familyName Kogan
123 schema:givenName V. A.
124 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01147254073.80
125 rdf:type schema:Person
126 sg:person.011547725721.73 schema:affiliation grid-institutes:grid.182798.d
127 schema:familyName Shcherbakov
128 schema:givenName I. N.
129 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011547725721.73
130 rdf:type schema:Person
131 sg:person.014422304747.19 schema:affiliation grid-institutes:grid.435216.7
132 schema:familyName Aleksandrov
133 schema:givenName G. G.
134 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014422304747.19
135 rdf:type schema:Person
136 sg:person.014535627721.66 schema:affiliation grid-institutes:grid.465325.3
137 schema:familyName Levchenkov
138 schema:givenName S. I.
139 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014535627721.66
140 rdf:type schema:Person
141 sg:person.015265162315.78 schema:affiliation grid-institutes:grid.435216.7
142 schema:familyName Ugolkova
143 schema:givenName E. A.
144 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015265162315.78
145 rdf:type schema:Person
146 sg:person.0721047070.68 schema:affiliation grid-institutes:grid.182798.d
147 schema:familyName Popov
148 schema:givenName L. D.
149 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0721047070.68
150 rdf:type schema:Person
151 sg:pub.10.1007/s00044-011-9749-3 schema:sameAs https://app.dimensions.ai/details/publication/pub.1029438672
152 https://doi.org/10.1007/s00044-011-9749-3
153 rdf:type schema:CreativeWork
154 sg:pub.10.1023/b:rugc.0000007624.57825.22 schema:sameAs https://app.dimensions.ai/details/publication/pub.1026885662
155 https://doi.org/10.1023/b:rugc.0000007624.57825.22
156 rdf:type schema:CreativeWork
157 sg:pub.10.1134/s0036023609080099 schema:sameAs https://app.dimensions.ai/details/publication/pub.1009274149
158 https://doi.org/10.1134/s0036023609080099
159 rdf:type schema:CreativeWork
160 sg:pub.10.1134/s0036023610050165 schema:sameAs https://app.dimensions.ai/details/publication/pub.1040901559
161 https://doi.org/10.1134/s0036023610050165
162 rdf:type schema:CreativeWork
163 sg:pub.10.1134/s0036023612020234 schema:sameAs https://app.dimensions.ai/details/publication/pub.1034366985
164 https://doi.org/10.1134/s0036023612020234
165 rdf:type schema:CreativeWork
166 grid-institutes:grid.182798.d schema:alternateName Southern Federal University, Rostov-on-Don, Russia
167 schema:name Southern Federal University, Rostov-on-Don, Russia
168 rdf:type schema:Organization
169 grid-institutes:grid.435216.7 schema:alternateName Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia
170 schema:name Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, 119991, Moscow, Russia
171 rdf:type schema:Organization
172 grid-institutes:grid.465325.3 schema:alternateName Southern Scientific Center, Russian Academy of Sciences, Rostov-on-Don, Russia
173 schema:name Southern Scientific Center, Russian Academy of Sciences, Rostov-on-Don, Russia
174 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...