Polymeric copper(II) complexes with 4-formyl-3-methyl-1-phenylpyrazol-5-one hetarylhydrazones: Synthesis and crystal structures View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2013-11-27

AUTHORS

L. D. Popov, S. I. Levchenkov, I. N. Shcherbakov, V. V. Minin, G. G. Aleksandrov, E. A. Ugolkova, V. V. Lukov, V. A. Kogan

ABSTRACT

4-Formyl-3-methyl-1-phenylpyrazol-5-one quinolin-2-yl-(H2L1) and benzothiazol-2-ylhydrazones (H2L2) were synthesized and studied. Quantum-chemical modeling of possible tautomers of the hydrazones was performed. Copper(II) complexes of the general formula [Cu(HL)(ROH)]Y (R = CH3, C2H5; Y=NO3, ClO4) were obtained and examined by IR and EPR spectroscopy, magnetochemistry, and X-ray diffraction. Additional coordination through the N atom of the pyrazole ring enables the complex molecules to form zigzag polymer chains linked by intermolecular hydrogen bonds. More... »

PAGES

849-856

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070328413110079

DOI

http://dx.doi.org/10.1134/s1070328413110079

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1032027308


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