Cesium tetrakis(1-(1,5-dimethyl-1H-pyrazol-4-yl)-4,4,4-trifluorobutane-1,3-diono)europiate(III): Synthesis, crystal structure, and luminescence properties View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2013-09

AUTHORS

I. V. Taidakov, S. S. Krasnosel’skii, A. N. Lobanov, A. G. Vitukhnovskii, Z. A. Starikova

ABSTRACT

Anionic complex Cs+[EuL4]− (I) is synthesized by the reaction of Eu(NO3)3 · 6H2O with 1-(1,5-dimethyl-1H-pyrazol-4-yl)-4,4,4-trifluorobutane-1,3-dione (HL) and CsOH in an aqueous-alcohol medium. Unstable adduct Cs+[EuL4]− · 2CH2Cl2 (Ia) is obtained from a solution in CH2Cl2. The structure of complex Ia is determined by X-ray diffraction analysis. The crystals of complex Ia at 100 K are monoclinic, a = 10.8435(5), b = 20.1353(9), c = 23.355(1) Å, β = 92.548(1)°, V = 5094.3(4) Å3, space group P21/n, Z = 4, and R = 0.0294. The coordination number of the Cs+ ion is 9. The Cs+ ion forms shortened (up to 3.3 Å) contacts with the O, N, and F atoms of four diketonate fragments joining the molecules into a three-dimensional structure. More... »

PAGES

680-684

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s107032841309008x

DOI

http://dx.doi.org/10.1134/s107032841309008x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1020957462


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Peoples Friendship University, ul. Miklukho-Maklaya 6, Moscow, Russia", 
            "Lebedev Physical Institute, Russian Academy of Sciences, Leninskii pr. 53, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Taidakov", 
        "givenName": "I. V.", 
        "id": "sg:person.011400547653.12", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011400547653.12"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Peoples' Friendship University of Russia", 
          "id": "https://www.grid.ac/institutes/grid.77642.30", 
          "name": [
            "Peoples Friendship University, ul. Miklukho-Maklaya 6, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Krasnosel\u2019skii", 
        "givenName": "S. S.", 
        "id": "sg:person.015451106073.59", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015451106073.59"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Lebedev Physical Institute, Russian Academy of Sciences, Leninskii pr. 53, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Lobanov", 
        "givenName": "A. N.", 
        "id": "sg:person.014526534265.23", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014526534265.23"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Lebedev Physical Institute, Russian Academy of Sciences, Leninskii pr. 53, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Vitukhnovskii", 
        "givenName": "A. G.", 
        "id": "sg:person.07657576104.07", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07657576104.07"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Starikova", 
        "givenName": "Z. A.", 
        "id": "sg:person.014473641160.05", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014473641160.05"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "sg:pub.10.1134/s0036023611030211", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1000085611", 
          "https://doi.org/10.1134/s0036023611030211"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jphotochem.2012.10.003", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1020869040"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/j.jlumin.2012.02.027", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041795199"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr010448y", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043646392"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr010448y", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1043646392"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.3184/003685005783238435", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1071111114"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.3184/003685005783238435", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1071111114"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.3184/003685005783238435", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1071111114"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2013-09", 
    "datePublishedReg": "2013-09-01", 
    "description": "Anionic complex Cs+[EuL4]\u2212 (I) is synthesized by the reaction of Eu(NO3)3 \u00b7 6H2O with 1-(1,5-dimethyl-1H-pyrazol-4-yl)-4,4,4-trifluorobutane-1,3-dione (HL) and CsOH in an aqueous-alcohol medium. Unstable adduct Cs+[EuL4]\u2212 \u00b7 2CH2Cl2 (Ia) is obtained from a solution in CH2Cl2. The structure of complex Ia is determined by X-ray diffraction analysis. The crystals of complex Ia at 100 K are monoclinic, a = 10.8435(5), b = 20.1353(9), c = 23.355(1) \u00c5, \u03b2 = 92.548(1)\u00b0, V = 5094.3(4) \u00c53, space group P21/n, Z = 4, and R = 0.0294. The coordination number of the Cs+ ion is 9. The Cs+ ion forms shortened (up to 3.3 \u00c5) contacts with the O, N, and F atoms of four diketonate fragments joining the molecules into a three-dimensional structure.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1134/s107032841309008x", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1294773", 
        "issn": [
          "1070-3284", 
          "1608-3318"
        ], 
        "name": "Russian Journal of Coordination Chemistry", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "9", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "39"
      }
    ], 
    "name": "Cesium tetrakis(1-(1,5-dimethyl-1H-pyrazol-4-yl)-4,4,4-trifluorobutane-1,3-diono)europiate(III): Synthesis, crystal structure, and luminescence properties", 
    "pagination": "680-684", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "63da6d62e148318204dd10705f90b6c89a2acee63bdd8931c6093fac6c6b9371"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s107032841309008x"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1020957462"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s107032841309008x", 
      "https://app.dimensions.ai/details/publication/pub.1020957462"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T01:58", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8700_00000505.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1134%2FS107032841309008X"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s107032841309008x'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s107032841309008x'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s107032841309008x'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s107032841309008x'


 

This table displays all metadata directly associated to this object as RDF triples.

110 TRIPLES      21 PREDICATES      32 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s107032841309008x schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N4444ffe800434164a20565325902347f
4 schema:citation sg:pub.10.1134/s0036023611030211
5 https://doi.org/10.1016/j.jlumin.2012.02.027
6 https://doi.org/10.1016/j.jphotochem.2012.10.003
7 https://doi.org/10.1021/cr010448y
8 https://doi.org/10.3184/003685005783238435
9 schema:datePublished 2013-09
10 schema:datePublishedReg 2013-09-01
11 schema:description Anionic complex Cs+[EuL4]− (I) is synthesized by the reaction of Eu(NO3)3 · 6H2O with 1-(1,5-dimethyl-1H-pyrazol-4-yl)-4,4,4-trifluorobutane-1,3-dione (HL) and CsOH in an aqueous-alcohol medium. Unstable adduct Cs+[EuL4]− · 2CH2Cl2 (Ia) is obtained from a solution in CH2Cl2. The structure of complex Ia is determined by X-ray diffraction analysis. The crystals of complex Ia at 100 K are monoclinic, a = 10.8435(5), b = 20.1353(9), c = 23.355(1) Å, β = 92.548(1)°, V = 5094.3(4) Å3, space group P21/n, Z = 4, and R = 0.0294. The coordination number of the Cs+ ion is 9. The Cs+ ion forms shortened (up to 3.3 Å) contacts with the O, N, and F atoms of four diketonate fragments joining the molecules into a three-dimensional structure.
12 schema:genre research_article
13 schema:inLanguage en
14 schema:isAccessibleForFree false
15 schema:isPartOf N3ee5e266b6f544659a958b355fb7e018
16 N4ebb798931454db9ab6a8cd35268d58c
17 sg:journal.1294773
18 schema:name Cesium tetrakis(1-(1,5-dimethyl-1H-pyrazol-4-yl)-4,4,4-trifluorobutane-1,3-diono)europiate(III): Synthesis, crystal structure, and luminescence properties
19 schema:pagination 680-684
20 schema:productId Nb816af8c6a504fe6be4efc618c7350f0
21 Ndbefce43d9eb4cc4a74e4ddab7dc609d
22 Nf1d9e44e335f434e821fe2d5003b524b
23 schema:sameAs https://app.dimensions.ai/details/publication/pub.1020957462
24 https://doi.org/10.1134/s107032841309008x
25 schema:sdDatePublished 2019-04-11T01:58
26 schema:sdLicense https://scigraph.springernature.com/explorer/license/
27 schema:sdPublisher Nbc996bb0195449d2ada66a0ae1c2aaff
28 schema:url http://link.springer.com/10.1134%2FS107032841309008X
29 sgo:license sg:explorer/license/
30 sgo:sdDataset articles
31 rdf:type schema:ScholarlyArticle
32 N03ac889cd238492884c54b0489e911ff rdf:first sg:person.07657576104.07
33 rdf:rest Nfa628ee7e94e4e338642b2bb2635c9c3
34 N3d5add5d09d64948a63fc41b6b427055 rdf:first sg:person.014526534265.23
35 rdf:rest N03ac889cd238492884c54b0489e911ff
36 N3ee5e266b6f544659a958b355fb7e018 schema:issueNumber 9
37 rdf:type schema:PublicationIssue
38 N4444ffe800434164a20565325902347f rdf:first sg:person.011400547653.12
39 rdf:rest Nd8f521301b2d47eeb63ead9373b2ff86
40 N4ebb798931454db9ab6a8cd35268d58c schema:volumeNumber 39
41 rdf:type schema:PublicationVolume
42 Nb816af8c6a504fe6be4efc618c7350f0 schema:name doi
43 schema:value 10.1134/s107032841309008x
44 rdf:type schema:PropertyValue
45 Nbc996bb0195449d2ada66a0ae1c2aaff schema:name Springer Nature - SN SciGraph project
46 rdf:type schema:Organization
47 Nd8f521301b2d47eeb63ead9373b2ff86 rdf:first sg:person.015451106073.59
48 rdf:rest N3d5add5d09d64948a63fc41b6b427055
49 Ndbefce43d9eb4cc4a74e4ddab7dc609d schema:name readcube_id
50 schema:value 63da6d62e148318204dd10705f90b6c89a2acee63bdd8931c6093fac6c6b9371
51 rdf:type schema:PropertyValue
52 Nf1d9e44e335f434e821fe2d5003b524b schema:name dimensions_id
53 schema:value pub.1020957462
54 rdf:type schema:PropertyValue
55 Nfa628ee7e94e4e338642b2bb2635c9c3 rdf:first sg:person.014473641160.05
56 rdf:rest rdf:nil
57 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
58 schema:name Chemical Sciences
59 rdf:type schema:DefinedTerm
60 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
61 schema:name Physical Chemistry (incl. Structural)
62 rdf:type schema:DefinedTerm
63 sg:journal.1294773 schema:issn 1070-3284
64 1608-3318
65 schema:name Russian Journal of Coordination Chemistry
66 rdf:type schema:Periodical
67 sg:person.011400547653.12 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
68 schema:familyName Taidakov
69 schema:givenName I. V.
70 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011400547653.12
71 rdf:type schema:Person
72 sg:person.014473641160.05 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
73 schema:familyName Starikova
74 schema:givenName Z. A.
75 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014473641160.05
76 rdf:type schema:Person
77 sg:person.014526534265.23 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
78 schema:familyName Lobanov
79 schema:givenName A. N.
80 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014526534265.23
81 rdf:type schema:Person
82 sg:person.015451106073.59 schema:affiliation https://www.grid.ac/institutes/grid.77642.30
83 schema:familyName Krasnosel’skii
84 schema:givenName S. S.
85 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015451106073.59
86 rdf:type schema:Person
87 sg:person.07657576104.07 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
88 schema:familyName Vitukhnovskii
89 schema:givenName A. G.
90 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07657576104.07
91 rdf:type schema:Person
92 sg:pub.10.1134/s0036023611030211 schema:sameAs https://app.dimensions.ai/details/publication/pub.1000085611
93 https://doi.org/10.1134/s0036023611030211
94 rdf:type schema:CreativeWork
95 https://doi.org/10.1016/j.jlumin.2012.02.027 schema:sameAs https://app.dimensions.ai/details/publication/pub.1041795199
96 rdf:type schema:CreativeWork
97 https://doi.org/10.1016/j.jphotochem.2012.10.003 schema:sameAs https://app.dimensions.ai/details/publication/pub.1020869040
98 rdf:type schema:CreativeWork
99 https://doi.org/10.1021/cr010448y schema:sameAs https://app.dimensions.ai/details/publication/pub.1043646392
100 rdf:type schema:CreativeWork
101 https://doi.org/10.3184/003685005783238435 schema:sameAs https://app.dimensions.ai/details/publication/pub.1071111114
102 rdf:type schema:CreativeWork
103 https://www.grid.ac/institutes/grid.4886.2 schema:alternateName Russian Academy of Sciences
104 schema:name Lebedev Physical Institute, Russian Academy of Sciences, Leninskii pr. 53, 119991, Moscow, Russia
105 Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, 119991, Moscow, Russia
106 Peoples Friendship University, ul. Miklukho-Maklaya 6, Moscow, Russia
107 rdf:type schema:Organization
108 https://www.grid.ac/institutes/grid.77642.30 schema:alternateName Peoples' Friendship University of Russia
109 schema:name Peoples Friendship University, ul. Miklukho-Maklaya 6, Moscow, Russia
110 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...