Tetranuclear Copper(II) Complex with N,N′-bis(2-N-Tosylaminobenzylidene)-1,3-Diaminopropan-2-ol: Crystal structure and magnetic properties View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2013-04-14

AUTHORS

L. D. Popov, S. I. Levchenkov, I. N. Shcherbakov, K. Yu. Suponitskii, A. S. Burlov, S. S. Beloborodov, V. V. Lukov, V. A. Kogan

ABSTRACT

Tetranuclear copper(II) complex, [Cu4L2(OOCCH2COO)], where L is triply deprotonated bis-N,N′-(2-N-tosylaminobenzylidene)-1,3-diaminopropan-2-ol, in which two binuclear fragments are linked by the malonate dianion, is synthesized. The exchange interaction in the binuclear clusters is shown to be antiferromagnetic (2J = −59 cm−1), whereas the intercluster interaction is ferromagnetic (zJ’ = 7.5 cm−1). The structure of the DMSO solvate of the complex is determined by X-ray diffraction analysis. More... »

PAGES

342-346

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070328413040106

DOI

http://dx.doi.org/10.1134/s1070328413040106

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1027305531


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