Synthesis and crystal structure of Mo6−xNbxI11 (x = 1–1.5) View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2013-01

AUTHORS

S. B. Artemkina, N. G. Naumov, A. V. Virovets, V. E. Fedorov

ABSTRACT

A solid solution Mo6 − xNbxI11 (x = 1.1–1.5) containing cluster cores {Mo5NbI8} is obtained by the high-temperature reaction of molybdenum, niobium, and iodine (550°C, 70 h, quartz ampule). According to the X-ray diffraction data, heating at 800°C in a molybdenum container results in the decomposition of the solution to Mo6I12 and Nb6I11. According to the X-ray structure analysis data, the compounds are isostructural to the high-spin modification Nb6I11 (space group Pccn). The presence of Nb atoms in the structure changes the structural type from the layered (Mo6I12) to framework structure, noticeably increases the metalmetal distances (2.661–2.716 Å, 2.695 Å) Mo6 octahedron with the retention of the distance from the metal (M) to the μ3-“capped” I atoms, and strongly elongates the M6-I-M6 bridges almost to the value observed in Nb6I11. More... »

PAGES

1-5

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070328413010016

DOI

http://dx.doi.org/10.1134/s1070328413010016

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1044596642


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Inorganic Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Nikolaev Institute of Inorganic Chemistry", 
          "id": "https://www.grid.ac/institutes/grid.425759.8", 
          "name": [
            "Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. akad. Lavrent\u2019eva 3, 630090, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Artemkina", 
        "givenName": "S. B.", 
        "id": "sg:person.010635501003.37", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010635501003.37"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Novosibirsk State University", 
          "id": "https://www.grid.ac/institutes/grid.4605.7", 
          "name": [
            "Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. akad. Lavrent\u2019eva 3, 630090, Novosibirsk, Russia", 
            "Novosibirsk National Research University, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Naumov", 
        "givenName": "N. G.", 
        "id": "sg:person.012635262363.79", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012635262363.79"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Nikolaev Institute of Inorganic Chemistry", 
          "id": "https://www.grid.ac/institutes/grid.425759.8", 
          "name": [
            "Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. akad. Lavrent\u2019eva 3, 630090, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Virovets", 
        "givenName": "A. V.", 
        "id": "sg:person.0642271552.29", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0642271552.29"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Novosibirsk State University", 
          "id": "https://www.grid.ac/institutes/grid.4605.7", 
          "name": [
            "Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. akad. Lavrent\u2019eva 3, 630090, Novosibirsk, Russia", 
            "Novosibirsk National Research University, Novosibirsk, Russia"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Fedorov", 
        "givenName": "V. E.", 
        "id": "sg:person.014112373331.48", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014112373331.48"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1002/zaac.199762301110", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1004561776"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/zaac.19946200730", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1007306542"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/zaac.200900401", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1008870586"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/zaac.200900401", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1008870586"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s0022476611020211", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1013182715", 
          "https://doi.org/10.1134/s0022476611020211"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1134/s1070328412030013", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1015239352", 
          "https://doi.org/10.1134/s1070328412030013"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/zaac.19673550511", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1019962889"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ar800124u", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1025482662"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ar800124u", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1025482662"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0025-5408(78)90001-6", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1030525717"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0025-5408(78)90001-6", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1030525717"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1039/dt9910000057", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041383377"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1016/0022-4596(83)90109-3", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1041596031"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic00131a058", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055543848"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic010867d", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055553884"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic010867d", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055553884"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic50185a034", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055577891"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic9508379", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055585766"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic9508379", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055585766"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2013-01", 
    "datePublishedReg": "2013-01-01", 
    "description": "A solid solution Mo6 \u2212 xNbxI11 (x = 1.1\u20131.5) containing cluster cores {Mo5NbI8} is obtained by the high-temperature reaction of molybdenum, niobium, and iodine (550\u00b0C, 70 h, quartz ampule). According to the X-ray diffraction data, heating at 800\u00b0C in a molybdenum container results in the decomposition of the solution to Mo6I12 and Nb6I11. According to the X-ray structure analysis data, the compounds are isostructural to the high-spin modification Nb6I11 (space group Pccn). The presence of Nb atoms in the structure changes the structural type from the layered (Mo6I12) to framework structure, noticeably increases the metalmetal distances (2.661\u20132.716 \u00c5, 2.695 \u00c5) Mo6 octahedron with the retention of the distance from the metal (M) to the \u03bc3-\u201ccapped\u201d I atoms, and strongly elongates the M6-I-M6 bridges almost to the value observed in Nb6I11.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1134/s1070328413010016", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1294773", 
        "issn": [
          "1070-3284", 
          "1608-3318"
        ], 
        "name": "Russian Journal of Coordination Chemistry", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "1", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "39"
      }
    ], 
    "name": "Synthesis and crystal structure of Mo6\u2212xNbxI11 (x = 1\u20131.5)", 
    "pagination": "1-5", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "d46e29214bc39f3768febf3f1e08602b2bff49d8e14596920748a0ff92a7bdc1"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1134/s1070328413010016"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1044596642"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1134/s1070328413010016", 
      "https://app.dimensions.ai/details/publication/pub.1044596642"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T15:50", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8664_00000507.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1134%2FS1070328413010016"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1134/s1070328413010016'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1134/s1070328413010016'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1134/s1070328413010016'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1134/s1070328413010016'


 

This table displays all metadata directly associated to this object as RDF triples.

130 TRIPLES      21 PREDICATES      41 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1134/s1070328413010016 schema:about anzsrc-for:03
2 anzsrc-for:0302
3 schema:author N2b979b4b46d54d9e9f88d97594e5abd2
4 schema:citation sg:pub.10.1134/s0022476611020211
5 sg:pub.10.1134/s1070328412030013
6 https://doi.org/10.1002/zaac.19673550511
7 https://doi.org/10.1002/zaac.19946200730
8 https://doi.org/10.1002/zaac.199762301110
9 https://doi.org/10.1002/zaac.200900401
10 https://doi.org/10.1016/0022-4596(83)90109-3
11 https://doi.org/10.1016/0025-5408(78)90001-6
12 https://doi.org/10.1021/ar800124u
13 https://doi.org/10.1021/ic00131a058
14 https://doi.org/10.1021/ic010867d
15 https://doi.org/10.1021/ic50185a034
16 https://doi.org/10.1021/ic9508379
17 https://doi.org/10.1039/dt9910000057
18 schema:datePublished 2013-01
19 schema:datePublishedReg 2013-01-01
20 schema:description A solid solution Mo6 − xNbxI11 (x = 1.1–1.5) containing cluster cores {Mo5NbI8} is obtained by the high-temperature reaction of molybdenum, niobium, and iodine (550°C, 70 h, quartz ampule). According to the X-ray diffraction data, heating at 800°C in a molybdenum container results in the decomposition of the solution to Mo6I12 and Nb6I11. According to the X-ray structure analysis data, the compounds are isostructural to the high-spin modification Nb6I11 (space group Pccn). The presence of Nb atoms in the structure changes the structural type from the layered (Mo6I12) to framework structure, noticeably increases the metalmetal distances (2.661–2.716 Å, 2.695 Å) Mo6 octahedron with the retention of the distance from the metal (M) to the μ3-“capped” I atoms, and strongly elongates the M6-I-M6 bridges almost to the value observed in Nb6I11.
21 schema:genre research_article
22 schema:inLanguage en
23 schema:isAccessibleForFree false
24 schema:isPartOf N1079a1be8a2c47ef82b7d73eb29840f8
25 N6f1874f9a6fa45bc950c0a3d7909a8cb
26 sg:journal.1294773
27 schema:name Synthesis and crystal structure of Mo6−xNbxI11 (x = 1–1.5)
28 schema:pagination 1-5
29 schema:productId N49a85fff038a4ffca0b1fe528f3925c8
30 Nb547b9bcb17f4be88af6b9ad74bcdff6
31 Needb9e7f64c2441592f05ef960e6b7f1
32 schema:sameAs https://app.dimensions.ai/details/publication/pub.1044596642
33 https://doi.org/10.1134/s1070328413010016
34 schema:sdDatePublished 2019-04-10T15:50
35 schema:sdLicense https://scigraph.springernature.com/explorer/license/
36 schema:sdPublisher Nf0cd5e410ccb4333a6917d433e804df7
37 schema:url http://link.springer.com/10.1134%2FS1070328413010016
38 sgo:license sg:explorer/license/
39 sgo:sdDataset articles
40 rdf:type schema:ScholarlyArticle
41 N1079a1be8a2c47ef82b7d73eb29840f8 schema:volumeNumber 39
42 rdf:type schema:PublicationVolume
43 N2b979b4b46d54d9e9f88d97594e5abd2 rdf:first sg:person.010635501003.37
44 rdf:rest N9a0b4a5905a34a69a35f5fee7bab3b7a
45 N49a85fff038a4ffca0b1fe528f3925c8 schema:name dimensions_id
46 schema:value pub.1044596642
47 rdf:type schema:PropertyValue
48 N6f1874f9a6fa45bc950c0a3d7909a8cb schema:issueNumber 1
49 rdf:type schema:PublicationIssue
50 N8fe8ef93690b40c1b1c74d9773639371 rdf:first sg:person.0642271552.29
51 rdf:rest Ndaaf41edbb34444aaf459dcdc6c6299f
52 N9a0b4a5905a34a69a35f5fee7bab3b7a rdf:first sg:person.012635262363.79
53 rdf:rest N8fe8ef93690b40c1b1c74d9773639371
54 Nb547b9bcb17f4be88af6b9ad74bcdff6 schema:name readcube_id
55 schema:value d46e29214bc39f3768febf3f1e08602b2bff49d8e14596920748a0ff92a7bdc1
56 rdf:type schema:PropertyValue
57 Ndaaf41edbb34444aaf459dcdc6c6299f rdf:first sg:person.014112373331.48
58 rdf:rest rdf:nil
59 Needb9e7f64c2441592f05ef960e6b7f1 schema:name doi
60 schema:value 10.1134/s1070328413010016
61 rdf:type schema:PropertyValue
62 Nf0cd5e410ccb4333a6917d433e804df7 schema:name Springer Nature - SN SciGraph project
63 rdf:type schema:Organization
64 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
65 schema:name Chemical Sciences
66 rdf:type schema:DefinedTerm
67 anzsrc-for:0302 schema:inDefinedTermSet anzsrc-for:
68 schema:name Inorganic Chemistry
69 rdf:type schema:DefinedTerm
70 sg:journal.1294773 schema:issn 1070-3284
71 1608-3318
72 schema:name Russian Journal of Coordination Chemistry
73 rdf:type schema:Periodical
74 sg:person.010635501003.37 schema:affiliation https://www.grid.ac/institutes/grid.425759.8
75 schema:familyName Artemkina
76 schema:givenName S. B.
77 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010635501003.37
78 rdf:type schema:Person
79 sg:person.012635262363.79 schema:affiliation https://www.grid.ac/institutes/grid.4605.7
80 schema:familyName Naumov
81 schema:givenName N. G.
82 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012635262363.79
83 rdf:type schema:Person
84 sg:person.014112373331.48 schema:affiliation https://www.grid.ac/institutes/grid.4605.7
85 schema:familyName Fedorov
86 schema:givenName V. E.
87 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014112373331.48
88 rdf:type schema:Person
89 sg:person.0642271552.29 schema:affiliation https://www.grid.ac/institutes/grid.425759.8
90 schema:familyName Virovets
91 schema:givenName A. V.
92 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0642271552.29
93 rdf:type schema:Person
94 sg:pub.10.1134/s0022476611020211 schema:sameAs https://app.dimensions.ai/details/publication/pub.1013182715
95 https://doi.org/10.1134/s0022476611020211
96 rdf:type schema:CreativeWork
97 sg:pub.10.1134/s1070328412030013 schema:sameAs https://app.dimensions.ai/details/publication/pub.1015239352
98 https://doi.org/10.1134/s1070328412030013
99 rdf:type schema:CreativeWork
100 https://doi.org/10.1002/zaac.19673550511 schema:sameAs https://app.dimensions.ai/details/publication/pub.1019962889
101 rdf:type schema:CreativeWork
102 https://doi.org/10.1002/zaac.19946200730 schema:sameAs https://app.dimensions.ai/details/publication/pub.1007306542
103 rdf:type schema:CreativeWork
104 https://doi.org/10.1002/zaac.199762301110 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004561776
105 rdf:type schema:CreativeWork
106 https://doi.org/10.1002/zaac.200900401 schema:sameAs https://app.dimensions.ai/details/publication/pub.1008870586
107 rdf:type schema:CreativeWork
108 https://doi.org/10.1016/0022-4596(83)90109-3 schema:sameAs https://app.dimensions.ai/details/publication/pub.1041596031
109 rdf:type schema:CreativeWork
110 https://doi.org/10.1016/0025-5408(78)90001-6 schema:sameAs https://app.dimensions.ai/details/publication/pub.1030525717
111 rdf:type schema:CreativeWork
112 https://doi.org/10.1021/ar800124u schema:sameAs https://app.dimensions.ai/details/publication/pub.1025482662
113 rdf:type schema:CreativeWork
114 https://doi.org/10.1021/ic00131a058 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055543848
115 rdf:type schema:CreativeWork
116 https://doi.org/10.1021/ic010867d schema:sameAs https://app.dimensions.ai/details/publication/pub.1055553884
117 rdf:type schema:CreativeWork
118 https://doi.org/10.1021/ic50185a034 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055577891
119 rdf:type schema:CreativeWork
120 https://doi.org/10.1021/ic9508379 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055585766
121 rdf:type schema:CreativeWork
122 https://doi.org/10.1039/dt9910000057 schema:sameAs https://app.dimensions.ai/details/publication/pub.1041383377
123 rdf:type schema:CreativeWork
124 https://www.grid.ac/institutes/grid.425759.8 schema:alternateName Nikolaev Institute of Inorganic Chemistry
125 schema:name Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. akad. Lavrent’eva 3, 630090, Novosibirsk, Russia
126 rdf:type schema:Organization
127 https://www.grid.ac/institutes/grid.4605.7 schema:alternateName Novosibirsk State University
128 schema:name Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. akad. Lavrent’eva 3, 630090, Novosibirsk, Russia
129 Novosibirsk National Research University, Novosibirsk, Russia
130 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...