Copper(I) complexes with 1-(2-carboxyphenyl)-5-heterylhydrazidinyl-6-celluloses as reversible redox indicators View Full Text


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Article Info

DATE

2012-11

AUTHORS

V. M. Ostrovskaya, V. V. Minin, G. A. Zvereva, A. V. Tsygankov, N. N. Efimov, D. A. Man’shev

ABSTRACT

A number of reagent test papers were designed on the basis of redox indicators: copper(I) complexes with sheet polydentate 1-(2-carboxyphenyl)-5-heterylhydrazidinyl-6-celluloses (I–IV) (heteryl = 6-methoxy-4-methylpyrimidin-2-yl, 4,6-dimethylpyrimidin-2-yl, benzoxazol-2-yl, and benzothiazol-2-yl). Complexes I–IV were transformed under the action of H2O2 into copper(II) complexes with 1-(2-carboxyphenyl)-5-heterylformazanyl-6-celluloses (V–VIII), respectively. When treated with Na2S, complexes V–VIII were reversibly reduced to the starting copper(I) complexes I–IV. The reactions were accompanied by bathochromic shifts from the central region of the visible spectrum to the higher wavelengths. Complex I was used to develop visual and reflectometric test methods for checking the peroxide content of pharmaceuticals and cosmetics at a level of 0.01% and above. More... »

PAGES

703-708

References to SciGraph publications

  • 2006-01. Copper complexes with polydentate hetarylformazanylcelluloses in RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
  • Identifiers

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    http://scigraph.springernature.com/pub.10.1134/s107032841211005x

    DOI

    http://dx.doi.org/10.1134/s107032841211005x

    DIMENSIONS

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