Synthesis and study of cobalt(II), nickel(II), and copper(II) complexes with 4-(4-hydroxyphenyl)-1,2,4-triazole View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2012-05

AUTHORS

E. V. Lider, E. V. Peresypkina, L. G. Lavrenova, L. A. Sheludyakova, A. I. Smolentsev, T. I. Yaroshenko, V. N. Elokhina

ABSTRACT

New complexes of Co(II), Ni(II), and Cu(II) nitrates, chlorides, and perchlorates with 4-(4-hydroxyphenyl)-1,2,4-triazole (L) were obtained and examined by single-crystal X-ray diffraction, X-ray powder diffraction, and electronic absorption and IR spectroscopy. The cations of all the complexes have linear trinuclear structures. Ligand L is coordinated to the metal ions in a bidentate bridging fashion through the N(1) and N(2) atoms of the heterocycle. The coordination polyhedron of the metal atoms is a distorted octahedron. The molecular and crystal structures of the complexes [Co3L6(H2O)6](ClO4)6 · 3C2H5OH · 3.75H2O and [M3L6(H2O)6](ClO4)6 · 6H2O (M = Cu2+ and Ni2+) were determined. More... »

PAGES

353-362

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070328412050065

DOI

http://dx.doi.org/10.1134/s1070328412050065

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1025494756


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