Nickel(I) complex as the final product of the sequence of spontaneous transformations in the system Ni(allyl)2-(2,6-diisopropylphenyl)diazabutadiene View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2012-06-07

AUTHORS

P. B. Kraikivskii, V. V. Saraev, V. V. Bocharova, G. V. Romanenko, D. A. Matveev, S. K. Petrovskii, A. S. Kuzakov

ABSTRACT

A reaction of Ni(Allyl)2 with bis(2,6-diisopropylphenyl)diazabutadiene gave an imino amide allyl nickel(II) complex (I). Complicated rearrangements of the imino amide ligand in the coordination sphere of complex I spontaneously yielded a paramagnetic Ni(I) π-allyl complex as a final reaction product. The nickel complexes produced in this system were studied by EPR, IR, and 2D NMR spectroscopy and mass spectrometry. Structure I was examined by X-ray diffraction. More... »

PAGES

416-425

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1134/s1070328412050053

DOI

http://dx.doi.org/10.1134/s1070328412050053

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1048890220


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